Hysteresis and scanning behavior of mesoporous molecular sieves

Sorption hysteresis is a widely studied phenomenon whose predicted behavior is well documented and researched. On the other hand, there is much less known about the region that lies between sorption isotherms, believed to be a metastable region. Scanning curves are a way of understanding the mechanism of hysteresis and a tool for hysteresis model validation. Scanning curves were produced for mesoporous materials: SBA-15 and MCM-41 for N(2) sorption at 77 K and Ar sorption at 87 K. A limited set of different scanning behaviors is identified. Like most hysteresis theories, it was found that a single model for scanning behavior cannot be extended to all materials under the same or different experimental conditions. Two behaviors are consistent with recent theories and simulations; however, several are not. The implications as to the characterization of pore dimensions and structure are discussed.     

Electronic structure,electrical and magnetic properties of RMo(8)O(14) compounds (R = La,Ce, Pr,Nd, Sm) containing bicapped Mo(8) clusters

Magnetic and electrical resistivity properties of RMo(8)O(14) (R = La, Ce, Pr, Nd, Sm) compounds containing different bicapped-octahedral Mo(8) clusters are discussed. Extended Hückel (EH) molecular calculations were carried out in order to study the influence of the position of metal capping atoms on the electronic structure of different Mo(8) isomers. Different optimal metal electron counts are possible for these clusters. Periodic density functional calculations confirm the molecular character of these compounds and allow the understanding of their semiconducting and magnetic properties.     

α-zirconium hydrogenphosphate,monohydrate. preparation,chemical properties and ac conductivity

The preparation of zirconium hydrogenphosphate, monohydrate (αZrP) was performed by two methods giving materials with slightly different properties. It is shown that the particle size of αZrP depend upon the method of preparation and the washing procedures, and that the ac conductivity decreases with increasing particle size (5 x 10^-6 to 5 x 10^-5 Ω^-1 cm^-1 at 20°C). The activation energy has been determined to 0.25 eV/mol (between 20°C and about 100°C) independent of the particle size, showing αZrP to be a surface ion conductor.     

Strange particle production and charmed particle search in the gargamelle neutrino experiment

Data is given for single and multiple strange particle production in neutrino reactions in both charged and neutral current channels. A total of 15000 neutrino and antineutrino events has been examined for possible evidence of semi-leptonic decay of a charmed particle. One candidate has been observed. Upper limits on charmed particle production cross-sections are given as a function of the neutrino energy and the invariant mass of the final state hadrons.     

High-pressure Raman and infrared study of ZrV 2O7

The room-temperature Raman and infrared spectra of zirconium vanadate (ZrV ₂O₇) were observed up to pressures of 12 GPa and 5.7 GPa, respectively. The frequencies of the optically active modes at ambient pressure were calculated using direct methods and compared with experimental values. Average mode Grüneisen parameters were calculated for the Raman and infrared active modes. Changes in the spectra under pressure indicate a phase transition at ∼1.6 GPa, which is consistent with the previously observed α (cubic) to β (pseudo-tetragonal) phase transition, and changes in the spectra at ∼4 GPa are consistent with an irreversible transformation to an amorphous structure.     

Bidding in sequential electricity markets: The Nordic case

For electricity market participants trading in sequential markets with differences in price levels and risk exposure, it is relevant to analyze the potential of coordinated bidding. We consider a Nordic power producer who engages in the day-ahead spot market and the hour-ahead balancing market. In both markets, clearing prices and dispatched volumes are unknown at the time of bidding. However, in the balancing market, the market participant faces an additional risk of not being dispatched. Taking into account the sequential clearing of these markets and the gradual realization of market prices, we formulate the bidding problem as a multi-stage stochastic program. We investigate whether higher risk exposure may cause hesitation to bid into the balancing market. Furthermore, we quantify the gain from coordinated bidding, and by deriving bounds on this gain, assess the performance of alternative bidding strategies used in practice.     

Untersuchung von Wasser und Abwasser

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