排序方式: 共有147条查询结果,搜索用时 46 毫秒
41.
Berestovitskaya V. M. Artemova O. V. Vasil’eva O. S. Litvinov I. A. Gubaidullin A. T. Krivolapov D. B. Ostroglyadov E. S. Berkova G. A. 《Russian Journal of General Chemistry》2009,79(4):808-819
3-Methoxycarbonyl-4-phenyl-2-pyrrolidone reacts with benzalmalonate and related compounds as an N-nucleophile affording adducts as an easily resolvable diastereoisomeric mixture. Structure of the synthesized compounds is studied by IR and 1H, 13C NMR spectroscopy. Structural parameters and configurations of the stereoisomers of one among the series of synthesized compounds was determined by X-ray structural analysis. The pyrrolidone ring of these compounds is shown to be present in an envelope conformation. The supramolecular structures in crystal are formed mainly on account of intermolecular hydrogen bonds of C-H?O type and π?π interactions.
相似文献42.
Yu. V. Bakhtiyarova R. I. Sagdieva I. V. Galkina V. I. Galkin R. A. Cherkasov D. B. Krivolapov A. T. Gubaidullin I. A. Litvinov 《Russian Journal of Organic Chemistry》2007,43(2):207-213
By reaction of triorganylphosphines with unsaturated dicarboxylic acids adducts of betaine structure were synthesized whose stability depended on the character of substituents at phosphorus and on the structure of acid. The betaine obtained from phosphines and maleic and fumaric acids redily underwent decarboxylation into the corresponding monoacyl phosphonium derivatives. The structure of the latter was established by means of X-ray crystallography. The adduct prepared from phosphines and itaconic acid was stabilized by intramolecular hydrogen bond between the acylate anionic center and the “second” carboxy group. 相似文献
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Felix D. Sokolov Damir A. Safin Maria G. Babashkina Nail G. Zabirov Vasiliy V. Brusko Nikolay A. Mironov Dmitry B. Krivolapov Igor A. Litvinov Rafael A. Cherkasov Boris N. Solomonov 《Polyhedron》2007
For N-(thio)phosphorylthioureas of the common formula RC(S)NHP(X)(OiPr)2HLI (R = N-(4′-aminobenzo-15-crown-5), X = S), HLII (R = N-(4′-aminobenzo-15-crown-5), X = O), HLIII (R = PhNH, X = S), HLIV (R = PhNH, X = O), and (N,N′-bis-[C(S)NHP(S)(OiPr)2]2-1,10-diaza-18-crown-6) H2LV, salts LiLI,III,IV, NaLI–IV, KLI–IVM2LV (M = Li+, Na+, K+), Ba(LI,III,IV)2, and BaLV have been synthesized and investigated. Compounds NaLI,II quantitatively drop out as a deposit in ethanol medium, allowing the separation of Na+ and K+ cations. This effect is not displayed for the other compounds. The crystal structures of HLIII and the solvate of the composition [K(Me2CO)LIII] have been investigated by X-ray crystallography. 相似文献
44.
M. S. Dzyurkevich D. B. Krivolapov O. A. Lodochnikova I. A. Litvinov V. V. Plemenkov 《Russian Journal of General Chemistry》2011,81(6):1181-1184
Reactions of alloocimene with maleic and citraconic anhydrides gave the corresponding Diels-Alder cycloaddition products which
may be regarded as new synthetic sesquiterpenoids. The molecular structures of the adducts, determined by X-ray analysis,
indicated endo addition of the dienophiles at the most sterically accessible diene system and syn-boat conformation of the bicyclic skeleton. 相似文献
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V. V. Bakharev A. A. Gidaspov E. V. Selezneva I. V. Ul’yankina D. B. Krivolapov I. A. Litvinov O. S. Eltsov 《Chemistry of Heterocyclic Compounds》2011,46(11):1386-1392
The reaction of 6-R-4-methoxy-1,3,5-triazin-2-ylnitroformaldoximes with dimethyl malonate gives the zwitterionic 4-methoxycarbonyl-3-(4-R-6-methoxy-1,3,5-triazin-2-yl)-4,5-dihydroisoxazol-5-ones.
X-ray structural analysis has been carried out on the zwitterionic 4-methoxycarbonyl-3-(4-methoxy-6-piperidino-1,3,5-triazin-2-yl)-4,5-dihydroisoxazol-5-one. 相似文献
47.
E. V. Mironova O. A. Lodochnikova D. B. Krivolapov Ya. V. Veremeichik V. V. Plemenkov I. A. Litvinov 《Journal of Structural Chemistry》2014,55(3):539-547
An X-ray crystallographic study of a new compound is performed and the structure of five sulfin- and sulfonamides of the thiazine series is discussed. The conformation of the thiazine ring in all structures (a distorted boat) is stabilized by the intramolecular interaction of the C-H…N type. The nitrogen atom of the thiazine ring has a pyramidal configuration. The geometry of isolated molecules is calculated at density functional theory level (PBE1PBE, 6-31G(d,p)) and compared to that observed in the crystals. In the crystal structures different packing motifs are implemented with the formation of supramolecular associates of different types due to classical hydrogen bonds such as N-H…O. 相似文献
48.
New Functional Cyclic Aminomethylphosphine Ligands for the Construction of Catalysts for Electrochemical Hydrogen Transformations 下载免费PDF全文
Dr. Elvira I. Musina Vera V. Khrizanforova Igor D. Strelnik Murad I. Valitov Yulia S. Spiridonova Dr. Dmitry B. Krivolapov Dr. Igor A. Litvinov Dr. Marsil K. Kadirov Dr. Peter Lönnecke Prof. Dr. Evamarie Hey‐Hawkins Prof. Dr. Yulia H. Budnikova Prof. Dr. Andrey A. Karasik Prof. Dr. Oleg G. Sinyashin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(11):3169-3182
Eight‐membered cyclic functional bisphosphines, namely 1,5‐di‐aryl‐3,7‐di(2‐pyridyl)‐1,5‐diaza‐3,7‐diphosphacyclooctanes (aryl=2‐pyridyl, m‐tolyl, p‐tolyl, diphenylmethyl, benzyl, (R)‐(+)‐(α‐methyl)benzyl), with 2‐pyridyl substituents on the phosphorus atoms have been synthesized by condensation of 2‐pyridylphosphine, formaldehyde, and the corresponding primary amine. The structures of some of these bisphosphines have been investigated by X‐ray crystallography. The bisphosphines readily form neutral P,P‐chelate complexes [(κ2‐P,P‐L)MCl2], cationic bis‐P,P‐chelate complexes [(κ2‐P,P‐L)2M]2+, or a five‐coordinate complex [(κ2‐P,P‐L)2NiBr]Br. The electrochemical behavior of two of the nickel complexes, and their catalytic activities in electrochemical hydrogen evolution and hydrogen oxidation, including the fuel‐cell test, have been studied. 相似文献
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