首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   524篇
  免费   17篇
  国内免费   6篇
化学   353篇
晶体学   1篇
力学   23篇
数学   81篇
物理学   89篇
  2023年   9篇
  2022年   6篇
  2021年   23篇
  2020年   11篇
  2019年   4篇
  2018年   12篇
  2017年   5篇
  2016年   19篇
  2015年   12篇
  2014年   17篇
  2013年   29篇
  2012年   39篇
  2011年   45篇
  2010年   26篇
  2009年   31篇
  2008年   40篇
  2007年   26篇
  2006年   32篇
  2005年   28篇
  2004年   25篇
  2003年   17篇
  2002年   11篇
  2001年   7篇
  2000年   6篇
  1999年   11篇
  1998年   5篇
  1997年   7篇
  1996年   2篇
  1995年   9篇
  1994年   4篇
  1993年   1篇
  1992年   6篇
  1991年   1篇
  1990年   2篇
  1989年   2篇
  1988年   1篇
  1987年   3篇
  1986年   1篇
  1985年   3篇
  1981年   1篇
  1978年   4篇
  1976年   1篇
  1974年   1篇
  1968年   1篇
  1967年   1篇
排序方式: 共有547条查询结果,搜索用时 15 毫秒
21.
A data-processing technique is proposed for use with conventional frequency-chirped absorption spectroscopy to ensure accurate mapping of spectral features into time-domain signatures with arbitrarily fast readout chirp rates. This technique recovers the spectrum from a signal that is distorted owing to the fast chirp rate and therefore facilitates fast measurement of the spectral features over a broad spectral range with high resolution. Both numerical simulations and experimental results are presented.  相似文献   
22.
Crystalline ternary inclusion monolayers consisting of a two-dimensional hydrogen-bonded host network of guanidinium (G) ions and organosulfonate (S) amphiphiles, and biphenylalkane guests, can be generated at the air-water interface through synergistic structural enforcement by hydrogen bonding and host-guest packing. Surface pressure-area isotherms of the 4'-hexadecylbiphenyl-4-sulfonate (C16BPS) amphiphile in the presence of G, with or without guest, are characterized by lift-off molecular areas expected for the GS sheet based on single-crystal X-ray structures of homologous bulk crystals. Intercalation of biphenylalkane guests (4-C(n)()H(2)(n)()(+1)-C(6)H(4)-C(6)H(5), n = 1, 4, 6, 10, 16; denoted CnBP) between organosulfonate hydrophobes, which define pocketlike cavities in the GS monolayer host, afford ternary inclusion monolayers with a 1:1 host-guest stoichiometry. These inclusion monolayers are less compressible than the guest-free host, consistent with dense packing of the biphenylalkane moieties of the host and the biphenylalkane guests. The inclusion monolayers are distinguished from the amorphous guest-free host and from selected guanidinium-free mixed monolayers by structural characterization with grazing-angle incidence X-ray diffraction (GIXD). The GIXD data for the ternary (G)C16BPS:C16BP and (G)C16BPS:C6BP inclusion monolayers obtained upon compression are consistent with a rectangular unit cell. The dimensions of these unit cells and refinement of the GIXD data suggest a "rotated shifted ribbon" GS hydrogen-bonding motif similar to that observed in some bulk GS crystals, including (G)(ethylbiphenylsulfonate). GIXD reveals that (G)C16BPS:C16BP and (G)C16BPS:C6BP are more crystalline than the corresponding guanidinium-free mixed monolayers. The (G)C16BPS:C6BP inclusion monolayer is stable upon compression, even though the alkyl-alkyl host-guest interactions are reduced due to the shorter hexyl substituents of the guest, demonstrating an important reinforcing role for the hydrogen-bonded GS sheet. The structure of a C16BPS:tetracosane (C24) mixed monolayer is independent of G; the unit cell symmetry and dimensions suggest a structure governed by alkyl-alkane interactions that prohibit formation of a GS network. These results illustrate that the existence of ternary inclusion monolayers with an intact GS network requires guest molecules that are structurally homologous with the hydrophobes of the host, in this case biphenylalkanes. The observation of these inclusion compounds suggests an approach for introducing functional nonamphiphilic molecules to an air-water interface through inclusion in a well-defined host.  相似文献   
23.
We introduce a local version of the Shannon entropy in order to describe information transport in spatially extended dynamical systems, and to explore to what extent information can be viewed as a local quantity. Using an appropriately defined information current, this quantity is shown to obey a local conservation law in the case of one-dimensional reversible cellular automata with arbitrary initial measures. The result is also shown to apply to one-dimensional surjective cellular automata in the case of shift-invariant measures. Bounds on the information flow are also shown.  相似文献   
24.
A new hybrid magnetic bead separator that combines an external magnetic field with 175 μm thick current lines buried in the back side of a silicon wafer is presented. A microfluidic channel was etched into the front side of the wafer. The large cross-section of the current lines makes it possible to use larger currents and obtain forces of longer range than from thin current lines at a given power limit. Guiding of magnetic beads in the hybrid magnetic separator and the construction of a programmable microarray of magnetic beads in the microfluidic channel by hydrodynamic focusing is presented.  相似文献   
25.
26.
27.
Naphthalene‐2,3‐dicarbaldehyde (NDA), a reagent used for the fluorescent detection of amino acids in the presence of cyanide, self‐condenses in the presence of cyanide ion and methanol at room temperature to yield a unique crystalline product 2, 15‐hydroxybenzo[g]benzo[6,7]isochromeno[4,3‐c]isochromen‐7(15H)‐one. The product is proposed to result from facile air oxidation of NDA to a methyl ester in combination with benzoin condensation. Product 2 does not to form in the absence of air. The gHMBC spectrum of 2 distinguishes it from a possible alternative isomeric condensation product.  相似文献   
28.
A convergence theorem for the continuous weak approximation of the solution of stochastic differential equations (SDEs) by general one-step methods is proved, which is an extension of a theorem due to Milstein. As an application, uniform second order conditions for a class of continuous stochastic Runge–Kutta methods containing the continuous extension of the second order stochastic Runge–Kutta scheme due to Platen are derived. Further, some coefficients for optimal continuous schemes applicable to Itô SDEs with respect to a multi–dimensional Wiener process are presented.  相似文献   
29.
This article describes the synthesis and characterization of a variety of new poly(2‐oxazoline)s. With regard to functional polymers, 2‐oxazolines represent an interesting class of monomers because of the easy variation of the substituent in 2‐position. Starting from the corresponding nitriles, different 2‐oxazolines were obtained containing a diverse set of 2‐substituents, including thioether bonds ( M11 ), trifluoromethyl groups ( M8 , M10 ), and alkyl‐ or aryl groups ( M1 – M7 ). The subsequent polymerization of the majority of these monomers proceeded in a living manner, which was demonstrated by linear first‐order kinetics, a linear increase of molar mass with conversion, and relatively narrow molar mass distributions. In addition, selected thermal and surface properties of the polymers were studied utilizing DSC and contact‐angle measurements to determine the effects of different 2‐substituents on the macroscopic properties. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 3829–3838, 2009  相似文献   
30.
JPC – Journal of Planar Chromatography – Modern TLC -  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号