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61.
Yuanbin Zhang Jianbo Hu Rajamani Krishna Lingyao Wang Lifeng Yang Xili Cui Simon Duttwyler Huabin Xing 《Angewandte Chemie (International ed. in English)》2020,59(40):17664-17669
Separation of acetylene (C2H2) from carbon dioxide (CO2) or ethylene (C2H4) is important in industry but limited by the low capacity and selectivity owing to their similar molecular sizes and physical properties. Herein, we report two novel dodecaborate‐hybrid metal–organic frameworks, MB12H12(dpb)2 (termed as BSF‐3 and BSF‐3‐Co for M=Cu and Co), for highly selective capture of C2H2. The high C2H2 capacity and remarkable C2H2/CO2 selectivity resulted from the unique anionic boron cluster functionality as well as the suitable pore size with cooperative proton‐hydride dihydrogen bonding sites (B?Hδ????Hδ+?C≡C?Hδ+???Hδ??B). This new type of C2H2‐specific functional sites represents a fresh paradigm distinct from those in previous leading materials based on open metal sites, strong electrostatics, or hydrogen bonding. 相似文献
62.
Ramajayam Govindan Mohamed El-Sherbiny Khalid Mohamed Morsy Ibraheem Srinivasan Narasimhan Mohamed EL-Dosoky Mohamed Salama Fazil Ahmad Selvaraj Jayaraman Vishnu Priya Veeraraghavan Srinivasan Vengadassalapathy Surapaneni Krishna Mohan Vidhya Rekha Umapathy Gayathri Rengasamy Shazia Fathima Jaffer Hussain Maheshkumar Poomarimuthu Senthilkumar Kalimuthu 《Molecules (Basel, Switzerland)》2022,27(3)
63.
64.
Monisha Prasad Selvaraj Jayaraman Mohamed Ahmed Eladl Mohamed El-Sherbiny Mosaab Abdella Ebrahim Abdelrahman Vishnu Priya Veeraraghavan Srinivasan Vengadassalapathy Vidhya Rekha Umapathy Shazia Fathima Jaffer Hussain Kalaiselvi Krishnamoorthy Durairaj Sekar Chella Perumal Palanisamy Surapaneni Krishna Mohan Ponnulakshmi Rajagopal 《Molecules (Basel, Switzerland)》2022,27(5)
Natural products in the form of functional foods have become increasingly popular due to their protective effects against life-threatening diseases, low risk of adverse effects, affordability, and accessibility. Plant components such as phytosterol, in particular, have drawn a lot of press recently due to a link between their consumption and a modest incidence of global problems, such as Type 2 Diabetes mellitus (T2DM), cancer, and cardiovascular disease. In the management of diet-related metabolic diseases, such as T2DM and cardiovascular disorders, these plant-based functional foods and nutritional supplements have unquestionably led the market in terms of cost-effectiveness, therapeutic efficacy, and safety. Diabetes mellitus is a metabolic disorder categoriszed by high blood sugar and insulin resistance, which influence major metabolic organs, such as the liver, adipose tissue, and skeletal muscle. These chronic hyperglycemia fallouts result in decreased glucose consumption by body cells, increased fat mobilisation from fat storage cells, and protein depletion in human tissues, keeping the tissues in a state of crisis. In addition, functional foods such as phytosterols improve the body’s healing process from these crises by promoting a proper physiological metabolism and cellular activities. They are plant-derived steroid molecules having structure and function similar to cholesterol, which is found in vegetables, grains, nuts, olive oil, wood pulp, legumes, cereals, and leaves, and are abundant in nature, along with phytosterol derivatives. The most copious phytosterols seen in the human diet are sitosterol, stigmasterol, and campesterol, which can be found in free form, as fatty acid/cinnamic acid esters or as glycosides processed by pancreatic enzymes. Accumulating evidence reveals that phytosterols and diets enriched with them can control glucose and lipid metabolism, as well as insulin resistance. Despite this, few studies on the advantages of sterol control in diabetes care have been published. As a basis, the primary objective of this review is to convey extensive updated information on the possibility of managing diabetes and associated complications with sterol-rich foods in molecular aspects. 相似文献
65.
Y. C. Venudhar Leela Iyengar K. V. Krishna Rao 《Crystal Research and Technology》1985,20(10):1393-1398
The precision lattice parameters of osmium dioxide have been determined at different temperatures, in the temperature range 30–444 °C, using a Unicam high temperature powder camera 19 cm in diameter and CuKα radiation. The data have been used to evaluate the coefficients of thermal expansion at various temperatures by a graphical method. The ‘a’ parameter increases non-linearly with increasing temperature while the ‘c’ parameter remains constant throughout the range of temperature studied indicating a zero coefficient of expansion along the c-direction. The abnormal thermal behaviour of this compound is explained in terms of the electronic configuration of the d-shell of the cation. 相似文献
66.
D. Bharathi B. Siddlingeshwar R. Hari Krishna Vikram Singh Nagaraju Kottam Darshan Devang Divakar Abdulaziz Abdullah Alkheraif 《Journal of fluorescence》2018,28(2):573-579
Carbon quantum dots (CQDs) due to its high fluorescent output is evolving as novel sensing material and is considered as future building blocks for nano sensing devices. Hence, in this investigation we report microwave assisted preparation and multi sensing application of CQDs. The microwave derived CQDs are characterized by Dynamic Light Scattering (DLS) experiment and Fourier Infrared spectra (FTIR) to investigate the size distribution and chemical purity respectively. Fluorescent emission spectra recorded at varying pH shows varying fluorescence emission intensities. Further, emission spectra recorded at different temperatures shows that fluorescence emission of CQDs greatly depends on temperature. Therefore, we demonstrate the pH and temperature sensing characteristics of CQDs by fluorescence quenching behaviour. In addition, the interaction and sensing behaviour of CQDs for dopamine is also presented in this work with a detection limit of 0.2 mM. The steady state and time-resolved methods have been employed in fluorescence quenching methods for sensing dopamine through CQDs at room temperature. The bimolecular quenching rate constants for different concentration have been measured. The interaction between CQDs and dopamine indicates fluorescence quenching method is an elegant process for detecting dopamine through CQDs. 相似文献
67.
Weerasekara A Rinzan M Matsik S Perera AG Buchanan M Liu HC von Winckel G Stintz A Krishna S 《Optics letters》2007,32(10):1335-1337
Terahertz detection using the free-carrier absorption requires a small internal work function of the order of a few millielectron volts. A threshold frequency of 3.2 THz (93 microm or approximately 13 meV work function) is demonstrated by using a 1 x 10(18) cm(-3) Si-doped GaAs emitter and an undoped Al(0.04)Ga(0.96)As barrier structure. The peak responsivity of 6.5 A/W, detectivity of 5.5 x 10(8) Jones, and quantum efficiency of 19% were obtained at 7.1 THz under a bias field of 0.7 kV/cm at 6 K, while the detector spectral response range spans from 3.2 to 30 THz. 相似文献
68.
T. Raghavendra RaoCh. Rama Krishna U.S. Udayachandran ThampyCh. Venkata Reddy Y.P. ReddyP. Sambasiva Rao R.V.S.S.N. Ravikumar 《Physica B: Condensed Matter》2011,406(11):2132-2137
The effect of Li2O content in vanadyl doped 20ZnO+xLi2O+(30−x)Na2O+50B2O3 (5≤x≥25) glasses has been studied with respect to their physical and structural properties. The absence of sharp peaks in XRD spectra of these glass samples confirms the amorphous nature. The physical parameters like density, refractive index, ionic concentration and electronic polarizability vary non-linearly with x mol% depending on the diffusivities of alkali ions. EPR and optical absorption spectra reveal that the resonance signals are characteristics of VO2+ ions in tetragonally compressed octahedral site. Spin-Hamiltonian, crystal field, tetragonal field and bonding parameters are found to be in good agreement with the other reported glass systems. The tetragonal distortion (g⊥-g∥) and Dt reveals that their values vary non-linearly with Li2O content and reaches a minimum at x=10 mol%. An anomaly of character has been observed in all the properties of vanadyl doped glass systems, which gives a clear indication of mixed alkali effect. 相似文献
69.
J. -E. Augustin G. Cosme F. Couchot B. Dudelzak F. Fulda B. Grelaud G. Grosdidier B. Jean-Marie S. Jullian D. Lalanne V. Lepeltier B. Louis F. Mané C. Paulot R. Riskalla Ph. Roy F. Rumpf G. Szklarz Z. Ajaltouni A. Falvard J. Jousset B. Michel J. C. Montret R. Baldini S. Calcaterra G. Capon D. Bisello G. Busetto S. Limentani M. Nigro L. Pescara M. Posocco P. Sartori L. Stanco DM Collaboration 《Zeitschrift fur Physik C Particles and Fields》1987,36(3):369-376
The radiative decayJ/ψ → γ π+ π? has been studied using the 8.6 millionJ/ψ produced in the DM2 experiment at the DCIe +e? storage rings at Orsay. The π+ π? mass spectrum shows a cleanf 2 (1270) signal, and the possible presence of two other states at thef 2 (1720) andf 4 (2030) masses. For thef 2 (1270), the branching ratio BR(J/ψ →γf)xBR(f→π+ π?) is measured to be (7.50±0.30±1.12)×10?4, and the spin analysis prefers theJ=2 assignment, with helicity parametersx=0.83±0.06 andy=0.01±0.06. The existence of higher mass states is discussed. 相似文献
70.
Dr. T. Krishna Kumar 《Mathematical Methods of Operations Research》1966,10(4):224-236
Summary In dealing with dynamic economic policy models one encounters optimization problems whose objective function is an integral of a linear function of a finite number of continuous variables and whose constraints are linear integral inequalities. A set of intertemporal efficiency conditions (equilibrium conditions) yielding the optimal policy are given. By approximating the continuous problem by a set of discrete problems and appealing to a well known convergence theorem in functional analysis a continuous analog of the duality theorem is proved.
The author is indebted to Mr.Arnold Faden for helpful suggestions and to ProfessorKarl A. Fox andGerhard Tintner for encouragement during the preparation of the paper. This research has been partially supported by a grant from the Ford Foundation to the School of Business Administration administered by the Center for Research in Management Science, University of California, Berkeley.
Vorgel. v.:G. Tintner. 相似文献
Zusammenfassung Bei der Beschäftigung mit dynamischen Modellen der ökonomischen Politik stößt man auf Optimierungsprobleme, deren Zielfunktion ein Integral einer linearen Funktion von einer endlichen Anzahl stetiger Variablen ist und deren Beschränkungen lineare Integral-Ungleichungen sind. Eine Menge intertemporaler Effizienz-Bedingungen (Gleichgewichtsbedingungen), die zur optimalen Politik führen, sind gegeben. Durch Approximation des kontinuierlichen Problems mittels einer Menge von diskreten Problemen und Berufung auf einen wohlbekannten Konvergenzsatz aus der Funktionalanalysis wird ein stetiges Analogon des Dualitätstheorems bewiesen.
The author is indebted to Mr.Arnold Faden for helpful suggestions and to ProfessorKarl A. Fox andGerhard Tintner for encouragement during the preparation of the paper. This research has been partially supported by a grant from the Ford Foundation to the School of Business Administration administered by the Center for Research in Management Science, University of California, Berkeley.
Vorgel. v.:G. Tintner. 相似文献