Evaluation of thermophysical characteristics on shape-stabilized paraffin as a solid-liquid phase change material

This report deals with thermophysical properties and measuring methods of shape-stabilized paraffin as a new type of latent heat storage material, which keeps the same shape in a solid state when the paraffin melts. Therefore, this type paraffin can be used in a latent heat storage system without encapsulation. A transient hot wire method, a differential scanning calorimeter (DSC), a water calorimeter and a volume expansion meter, which were developed in the present study, were used to measure effective thermal conductivity, latent heat, specific heat and density of the shape-stabilized paraffin, respectively. From the obtained data, useful correlation equations of the above-mentioned thermophysical properties of the shape-stabilized paraffin were expressed as functions of physical property and mass fraction of each constituent of the shape-stabilized paraffin.     

Free convection from horizontal screened plates

Experimental investigations of laminar free convection from horizontal isothermal surfaces screened by cylindrical vertical walls are presented. Screen diameters (D) were equal to the diameter of a heating plate while their heights (H) were varied. Results obtained for several heating fluxes and two different liquids indicate that depending on the (H/D) ratio of cylindrical screens, the heat flux transferred from the heating plate to the liquid varies. Three subranges of screening effect have been distinguished: primary inhibition, intensification and secondary inhibition. For primary inhibition, a theoretical model has been proposed and critical ratio of (H/D) has been predicted. The results of flow visualization are also discussed.

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Freie Konvektion von horizontalen, seitlich abgeschirmten Platten

Zusammenfassung Es werden experimentelle Untersuchungen der laminaren freien Konvektion an horizontalen, isothermen Flächen mit vertikalen zylindrischen Abschirmflächen beschrieben. Die Schirmdurchmesser (D) waren gleich dem einer Heizplatte, während die Schirmhöhen (H) variiert wurden. Die Resultate, welche für mehrere Wärmeflüsse und mit zwei verschiedenen Flüssigkeiten gewonnen wurden, zeigen, daß — abhängig von VerhältnisH/D der zylindrischen Schirme — der von der Heizplatte an das Fluid übergehende Wärmestrom stark variiert. Drei Bereiche konnten bezüglich des Abschirmeffektes unterschieden werden: erste Hemmung, Verstärkung und zweite Hemmung. Für den Fall der ersten Hemmung wird ein theoretisches Modell vorgeschlagen und das kritischeH/D-Verhältnis vorausberechnet. Abschließend erfolgt die Diskussion von Ergebnissen, welche aus der sichtbaren Darstellung des Strömungsfeldes gewonnen wurde.

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Nomenclature a thermal diffusivity [m²/s] - D external diameter of the plate, internal diameter of screens [m] - g gravitational acceleration [m/s²] - H height of screen [m] - Nu= D/ Nusselt number - Nu _(H/D)=0 Nusselt number for plate without screens - Nu _H/D Nusselt number for plate with screen of heightH - Ra=g (T _w1–T _F)D ³/( a) Rayleigh number - Ra _H=g (T _w–T _w1)H ³/( a) Rayleigh number inside screen - q heat flux density [W/m²] - T _w surface temperature of the heating plate [°C] - T _w1 boundary temperature of the motionless liquid [°C] - T _F bulk temperature of the liquid [°C] - heat transfer coefficient [W/(m²·K)] - coefficient of volumetric expansion [1/K] - kinematic viscosity - thermal conductivity [W/(m·K)]     

On using non-Gaussian distributions to perform statistical linearization

In statistical linearization non-linear elements are approximated by equivalent linear elements according to recipes proposed by the pioneers of the procedure. The recipes require the evaluation of certain statistics which, ideally, should be evaluated using the exact probability distribution of the non-linear response. Because the exact non-linear response distribution is unknown it has become traditional to use a Gaussian distribution as an approximation to the exact distribution. With the modern computing tools now available it is easy to use non-Gaussian distributions which can provide better approximations in cases where Gaussian distributions are not appropriate. Examples are displayed for power-law oscillators with stiffening and softening springs, and for the Duffing oscillator, and for a double-well oscillator. Two families of probability distributions with varying shape are studied.     

Liquid-structure-foundation interaction of slender water towers

Summary The dynamic behaviour of a slender water tower based on a (deep) foundation is studied by a lumped model in which the parameters have been derived analytically from continuous models. The effects of the liquid and foundation on the structural dynamics can be studied analytically using this model, sensitivity analyses are easily performed. Ring baffles in the liquid tank and the local yielding of the pile-soil interaction along the shaft of the foundation piles may reduce the dynamic response.

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Wechselwirkung von Flüssigkeitsfüllung, Bauwerk und Fundament von schlanken Wassertürmen

Übersicht Das dynamische Verhalten eines auf ein tiefes Fundament gegründeten schlanken Wasserturms wird anhand eines diskreten Modells analysiert, in dem die Parameter analytisch aus kontinuierlichen Modellen hergeleitet wurden. Mit Hilfe des Modells kann der Einfluß des Wassers und des Fundamentes auf das dynamische Konstruktionsverhalten analytisch studiert werden. Empfindlichkeitsanalysen lassen sich somit leicht durchführen.Zwischenringe im Flüssigkeitsbehälter und lokales Fließen in den Kontaktflächen zwischen Gründungspfählen und Boden können die Strukturschwingungen mindern.

     

Mixed convection of an incompressible viscous fluid in a porous medium past a hot vertical plate

This paper analyses steady two-dimensional mixed convection of an imcompressible viscous fluid in a porous medium past a hot vertical plate. Assuming Darcy-Brinkman model for the flow in a porous medium, the boundary layer equations are integrated numerically to obtain the non-similar solution for the velocity and temperature distribution for several values of the permeability and viscous dissipation parameters. It is shown that for a fixed value of Prandtl number Pr and dissipation parameter E, the skin-friction at the plate decreases with increase in the permeability parameter K₁. However for the same value or Pr and E, the heat transfer rate at the plate increases with increasing K₁. The dimensionlcss velocity and temperature functions in the flow are plotted for several values of E and K₁ with Pr = 0.73. It is also shown that for fixed values of K₁, and KPr, the skin-friction increases with increase in the dissipation parameter E.     

Strain-gage-stability measurements for years at 75°C in air

The authors have evaluated the performance of three types of metal-foil strain gages for two and a half years at a constant temperature of 75°C in air. The studies included polyimide-backed and phenolic-glass-backed gages with copper-nickel foil (constantan) and glass-fiber-rein-forced epoxy-phenolic-resin-backed gages with nickel-chromium foil (modified Karma). All gages were tested in a three-wire-lead, single-active-gage Wheatstone bridge system at nominal mechanical-strain levels of 0, +1000 and ?1000 μm/m. The polyimide-backed constantan gages used in Installation No. 1 typically zero-shifted more than +200 μm/m after 30 days' testing at 75°C. The phenolic-glass-backed constantan gages used in Installation No. 2 zero-shifted ?40 to +20 μm/m after 30 days and +270 to +350 μm/m after 900 days. The glass-fiber-reinforced, epoxyphenolic-resin-backed Karma gages used in Installation No. 3 zero-shifted about +5 μm/m after 30 days, and +20 to +45 μm/m after 900 days. The Karma gages used in Installation No. 3 performed better than the other two types of gages. The measured results for the Karma gages appeared to be independent of the adhesives, test-part material, and mechanical-strain levels that we tested. The high stability and low zero drifts of this gage at 75°C allowed us to reliably correct the measured static-strain data on actual test parts.     

Intramolecular Oxidative Coupling of the Bis Enolate Derived from Dimethyl β,β-Dimethylglutarate: A Facile Stereoselective Route to a Versatile Synthon for Preparation of Insecticidal Pyrethroids

Treatment of the bis enolate derived from dimethyl β,β-dimethylglutarate with silver chloride afforded dimethyl cis-3,3-dimethyl-1,2-cyclopropanedicarboxylate, a versatile synthon for the preparation of the acid component of cis-pyrethroids. A similar experiment utilizing iodine as the oxidant led to the isolation of the corresponding trans diester with good stereo-selectivity.     

Mechanism of and Products from the Oxidation of Phenols by Hypervalent Iodine Compounds

Iodobenzene dichloride or diacetate initiates the polymerization of 2,6-dimethylphenolate anion to poly [oxy(2,5-dimethyl)-l, 4-phenylene]. Electron spin resonance spectroscopy was used to identify the polymeric radical that is the growing chain. Infrared and NMR spectroscopy identified the final polymer. The mechanism proposed is probably applicable also to other phenol oxidation processes yielding substituted poly(oxyphenylenes).

The anomalous chemistry of those compounds of xenon, iodine, and tellurium in which the number of bonding electrons exceeds that given by Lewis valence theory has been considered in general terms by Musher [1] who coined the term “hypervalent” to describe these substances. The oxidizing properties of these compounds is in a general way similar to that of peroxides and other strong oxidizing agents, but has not been characterized in any exact fashion. We have observed [2] that the iodobenzene esters have polymeric analogs of the formula, [-I(R)OOCXCOO-], and these compounds are stable oxidizing agents (R = aryl; X = alkylene or arylene). We have been interested in determining if -I(R)OXO- compounds can be formed.

The first question to consider is the stability of bonds in -OI(R)O- compounds. Only acyl derivatives are known [3]. However, the possibility