BEEM-π calculations for a series of pyridines and their 14N N.Q.R.

The ⁵⁷Fe Mössbauer spectrum of a powdered sample of phthalocyanine-iron(II) in an applied magnetic field of 3·0 teslas has been measured as a function of temperature in the range 4·2 K to 100 K. Measurements have also been made at 4·2 K with 6·0 teslas applied, and on a single crystal specimen at 4·2 K with 3·0 teslas applied. Independent computer fits to the three measurements taken at 4·2 K were found to be consistent with one another, and showed that detailed information concerning magnetic anisotropy can be obtained even from powdered samples of paramagnets by Mössbauer spectroscopy. Although the asymmetry parameter in the electric field gradient tensor was found to be small, there was a significant departure from tetragonal symmetry in the magnetic properties of the molecule. The magnetic hyperfine field at the ⁵⁷Fe nucleus was found to be positive in all directions, indicating that all three electronic g values are significantly greater than 2·0.     

The Synthesis and Mechanistic Considerations of a Series of Ammonium Monosubstituted H-Phosphonate Salts

A series of ammonium monosubstituted H-phosphonate salts were synthesized by combining H-phosphonate diesters with amines in the absence of solvent at 80 °C. Variation of the ester substituent and amine produced a range of ionic liquids with low melting points. The products and by-products were analyzed by spectroscopic and spectrometric techniques in order to get a better mechanistic picture of the dealkylation and formal dearylation observed. For dialkyl H-phosphonate diesters, (RO)₂P(O)H (R=alkyl), the reaction proceeds via direct dealkylation with the reactivity increasing in the order R=iPr<Et<Me corresponding to DFT calculated activation enthalpies of 22.6, 20.8, and 17.9 kcal mol⁻¹. For the diphenyl H-phosphonate diesters, (PhO)₂P(O)H, the dearylation was found to proceed via phenol-assisted formation of a 5-coordinate intermediate, (PhO)₃PH(OH), from which P(OPh)₃ and water were eliminated. The presence of an equivalent of water then facilitated the formation of P(OH)₂OPh and the amine, R'NH₂, subsequently abstracted a proton from it to yield [(PhO)PH(O)O]^-[R'NH₃]⁺.     

Ueber die Entwickelung der doppelt periodischen Functionen zweiter und dritter Art in trigonometrische Reihen

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Ueber einige Differentialbeziehungen im Gebiete der Thetafunctionen zweier Veränderlichen

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Ueber die Transformation fünften Grades des hyperelliptischen Functionen erster Ordnung

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Die Modulargleichungen der hyperelliptischen Functionen erster Ordnung für die Transformation dritten Grades

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Über Valyl-Leucinanhydrid

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Die Deformation keramischer Massen beim Trocknen

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