全文获取类型
收费全文 | 511篇 |
免费 | 20篇 |
国内免费 | 4篇 |
专业分类
化学 | 436篇 |
晶体学 | 7篇 |
力学 | 7篇 |
数学 | 9篇 |
物理学 | 76篇 |
出版年
2022年 | 3篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2016年 | 9篇 |
2015年 | 7篇 |
2014年 | 17篇 |
2013年 | 26篇 |
2012年 | 29篇 |
2011年 | 38篇 |
2010年 | 19篇 |
2009年 | 14篇 |
2008年 | 39篇 |
2007年 | 26篇 |
2006年 | 21篇 |
2005年 | 25篇 |
2004年 | 26篇 |
2003年 | 11篇 |
2002年 | 18篇 |
2001年 | 13篇 |
2000年 | 5篇 |
1999年 | 6篇 |
1998年 | 6篇 |
1997年 | 4篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1990年 | 8篇 |
1989年 | 2篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 14篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 11篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1978年 | 9篇 |
1977年 | 6篇 |
1976年 | 6篇 |
1975年 | 6篇 |
1974年 | 9篇 |
1973年 | 12篇 |
1972年 | 6篇 |
1971年 | 4篇 |
1970年 | 2篇 |
1967年 | 3篇 |
1965年 | 1篇 |
排序方式: 共有535条查询结果,搜索用时 250 毫秒
431.
Yukiko Inoue Kozo Matsumoto Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2015,53(9):1076-1081
Polyaddition of bis(five‐membered cyclic dithiocarbonate), 2,2‐bis[4‐(1,3‐thioxolane‐2‐one‐4‐yl‐methoxy)phenyl]propane ( 1 ), with diamines having soft oligoether segments and property of the obtained poly(thiourethane)s were examined. Treatment of 1 with equivalent diamines in tetrahydrofuran at room temperature gave poly(thiourethane)s having a mercapto group in each unit, which were further treated with acetic anhydride and triethylamine to give the corresponding S‐acetylated poly(thiourethane)s in high yield. Exposing the mercapto group containing poly(thiourethane)s to benzoyl chloride and triethylamine provided the corresponding S‐benzoylated poly(thiourethane)s effectively. Thermal properties of the obtained polymers were evaluated by thermogravimetric analysis and differential scanning calorimetry. The obtained polymers showed 10 wt % loss temperature (Td10) in the range from 230 to 274 °C, which was relatively high when compared with the Td10 of an analogous polymer prepared from 1 and 1,6‐hexamethylenediamine. The polymers obtained here exhibited glass transition temperature (Tg) in the range from ?16 °C to 40 °C, which was much lower than the analogous polymer described above, probably due to the soft oligoether segments. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1076–1081 相似文献
432.
433.
Norio Inui Kozo Mochiji Kousuke Moritani Naoki Nakashima 《Applied Physics A: Materials Science & Processing》2010,98(4):787-794
The formation of a nanopore in a graphene sheet by collision with an argon cluster is simulated using molecular dynamics method. The number of removed carbon atoms and the size of the nanopore are obtained as a function of the kinetic energy of the cluster. In contrast to nanosculpting with a monomer ion beam, the size of the nanopore that is created by one shot of the cluster varies because of the variety of atom configuration. However, the mean size of the nanopore can be controlled over a wide range only by changing the kinetic energy of the cluster. This implies that the cleaning and processing of the graphene sheet may be realized simultaneously by changing the acceleration energy of the cluster. 相似文献
434.
435.
Hiroki Miura Kazuki Takeuchi Tetsuya Shishido 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2016,128(1):286-290
Intermolecular [2+2+1] carbonylative cycloaddition of aldehydes with alkynes and subsequent oxidation to γ‐hydroxybutenolides is achieved using a supported ruthenium catalyst. A ceria‐supported ruthenium catalyst promotes the reaction efficiently, even with an ambient pressure of CO or without external CO, thus giving the corresponding γ‐hydroxybutenolide derivatives in good to high yields. Moreover this catalyst can be reused with no loss of activity. 相似文献
436.
437.
Kazuo Nakajima Toshihiro Kusunoki Yukinaga Azuma Noritaka Usami Kozo Fujiwara Toru Ujihara Gen Sazaki Toetsu Shishido 《Journal of Crystal Growth》2002,240(3-4):373-381
The effect of the supply of depleted Si solute elements on the compositional variation in the Si-rich SiGe bulk crystals was studied using the method which was used to grow Ge-rich SiGe single crystals with a uniform composition. By selecting the proper pulling rate, we can obtain Si-rich Si1−xGex bulk crystals with uniform composition of x=0.1 without using the supply mechanism of depleted Si solute elements. When the supply mechanism of Si solute elements was used, the initial composition in Si-rich SiGe crystals can be much more easily determined by controlling the growth temperature than that in Ge-rich crystals because the Si seed crystal is not melted down. The supply of Si solute elements is very effective to change the compositional variation even for Si-rich SiGe crystals. 相似文献
438.
Kazunori Kuwana Kozo Sekimoto Takeaki Minami Takahiro Tashiro Kozo Saito 《Proceedings of the Combustion Institute》2013,34(2):2625-2631
A fire whirl, observed during a wildland fire in Brazil in 2010, occurred over a narrow but long line fire and moved along the line fire at nearly a constant speed. There appeared to be no mountains, tall buildings or trees near the scene, indicating that the fire whirl was generated merely by the interaction between the line fire and background wind. Scale-model experiments having different line fire configurations were designed and performed to reconstruct the above-mentioned Brazil fire whirl. Moving fire whirls were successfully reconstructed during the scale-model experiments, the mechanism and conditions of which are discussed herein. 相似文献
439.
440.
Ken Takaki Kentaro Sonoda Takeshi Kousaka Go Koshoji Tetsuya Shishido Katsuomi Takehira 《Tetrahedron letters》2001,42(52):9211-9214
Divalent lanthanide–imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl- and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions. 相似文献