全文获取类型
收费全文 | 600篇 |
免费 | 10篇 |
国内免费 | 4篇 |
专业分类
化学 | 478篇 |
晶体学 | 7篇 |
力学 | 8篇 |
数学 | 10篇 |
物理学 | 111篇 |
出版年
2023年 | 3篇 |
2022年 | 3篇 |
2019年 | 8篇 |
2016年 | 6篇 |
2015年 | 7篇 |
2014年 | 13篇 |
2013年 | 28篇 |
2012年 | 29篇 |
2011年 | 31篇 |
2010年 | 25篇 |
2009年 | 16篇 |
2008年 | 37篇 |
2007年 | 27篇 |
2006年 | 30篇 |
2005年 | 34篇 |
2004年 | 28篇 |
2003年 | 17篇 |
2002年 | 29篇 |
2001年 | 9篇 |
2000年 | 7篇 |
1999年 | 9篇 |
1998年 | 6篇 |
1997年 | 6篇 |
1996年 | 6篇 |
1995年 | 8篇 |
1994年 | 7篇 |
1993年 | 5篇 |
1992年 | 10篇 |
1991年 | 3篇 |
1990年 | 6篇 |
1989年 | 4篇 |
1987年 | 9篇 |
1986年 | 3篇 |
1985年 | 19篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 9篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1978年 | 10篇 |
1977年 | 6篇 |
1976年 | 7篇 |
1975年 | 5篇 |
1974年 | 8篇 |
1973年 | 13篇 |
1972年 | 4篇 |
1971年 | 5篇 |
1970年 | 2篇 |
1967年 | 3篇 |
排序方式: 共有614条查询结果,搜索用时 0 毫秒
11.
12.
Infrared cyclotron resonance was observed in n-type InSb, GaAs and Ge in very high magnetic fields up to 1.3 MOe at room temperature using a CO2 laser. A large shift of the cyclotron mass due to the non-parabolicity of the energy band was found in each material. The band edge masses of electrons at room temperature were evaluated to be for InSb, m for GaAs and m for Ge. The linewidth was measured in GaAs and Ge in the high fields. 相似文献
13.
Geoffrey B Edwards Kaoru Yamanouchi Kozo Kuchitsu Masaaki Sugie Harutoshi Takeo Chi Matsumura Keiichiro Ogawa Yoshito Takeuchi 《Journal of Molecular Spectroscopy》1985,111(2):301-319
The microwave spectrum of 1-pyrroline has been measured from 8 to 48 GHz. The transitions have been assigned to those of the ground state and the four lowest excited states of the ring-puckering vibration of monomer, which is a five-membered ring molecule with one CN double bond. The trimer, which exists in the liquid phase, has not been detected in the gas phase. The geometrical structure of the monomer has been estimated by an ab initio calculation and the trimer by a molecular mechanics calculation. The former is consistent with the experimental rotational constants. A gas-phase infrared spectrum has also been measured, and the ring-puckering potential has been determined by an analysis of the combination bands of the ring-puckering mode and the ring-stretching modes. The potential is described using a puckering coordinate, z, as V(z) = az2 + bz4, where and ; these values are intermediate of the corresponding values for cyclopentene and 1-pyrazoline. The nuclear quadrupole coupling constants, χaa = ?4.39(10), χbb = 1.04(10), and χcc = 3.35(10) MHz, have been determined by an analysis of well-resolved hyperfine splittings. These constants have been reproduced by an ab initio calculation with a 4-31G(N1) basis set. 相似文献
14.
Osamu Kido Mami Kurumada Katsuya Kamitsuji Toshiaki Tanigaki Takeshi Sato Yuki Kimura Hitoshi Suzuki Yoshio Saito Chihiro Kaito 《Physica E: Low-dimensional Systems and Nanostructures》2006,31(2):169-173
The synthesis of Al–Cr single quasicrystal (QC) nanoparticles of the decagonal phase was achieved by introducing an advanced gas flow evaporation method. By obtaining successive electron diffraction patterns for single-QC nanoparticles, the phase transformation temperature of a single-QC nanoparticle was determined to be 700 °C. It was also determined that part of the QC nanoparticle decomposed into hex-Al8Cr5 and Al during the phase transformation. Since the grain growth did not occur during the phase transformation in the present experiment, the inherent phase transformation temperature could be measured. 相似文献
15.
Yuki?KanazawaEmail authorView authors OrcID profile Tetsuya?Yamada Aki?Kido Koji?Fujimoto Kyoko?Takakura Hiroaki?Hayashi Yasutaka?Fushimi Satoshi?Kozawa Koji?Koizumi Makiko?Okuni Naomi?Ueda Kaori?Togashi 《Applied magnetic resonance》2017,48(2):125-134
To visualize the condition of impregnation of polyethylene glycol (PEG) in waterlogged wood, we demonstrated magnetic transfer (MT) magnetic resonance imaging (MRI) through a series of process of PEG impregnation. Three different samples were examined; reference wood, 10 cm cut wood, and 5 cm cut wood. During this study, the upper section sample was kept immersed in water, for the middle and lower sections the concentration of PEG solution was changed at 20 wt% intervals from 20 to 100 wt%. The impregnated periods of each PEG solution concentration were 14 days. Then, MR imaging were performed with/without MT pulse. The MTR value for both 10 cm- and 5 cm-samples were shown to decrease at 20 wt% PEG at peak concentration. When the sample volume was large, e.g., 10 cm-sample, the MTR value decreased to 100 wt% PEG concentration. In contrast, when a sample volume was small, e.g., 5 cm-sample, MTR value decreased to 60 wt% PEG concentration. In conclusion, MTR analysis makes it possible to nondestructively visualize and evaluate the inner condition concerning the PEG impregnation method for waterlogged wood. 相似文献
16.
Growth modes and electronic properties were analyzed for Au nano-particles grown on stoichiometric and reduced TiO2(1 1 0) substrates by medium energy ion scattering (MEIS) and photoelectron spectroscopy(PES) using synchrotron-radiation-light. Initially, two-dimensional islands (2D) with a height of one and two atomic layers grow and higher coverage increases the islands height to form three-dimensional (3D) islands for the stoichiometric TiO2(1 1 0) substrate. In contrast, 3D islands start to grow from initial stage with a small Au coverage (?0.1 ML, 1 ML = 1.39 × 1015 atoms/cm2: Au(1 1 1)) probably due to O-vacancies acting as a nucleation site. Above 0.7 ML, all the islands become 3D ones taking a shape of a partial sphere and the Au clusters change to metal for both substrates. We observed the Au 4f and Ti 3p core level shifts together with the valence band spectra. The Ti 3p peak for the O-deficient surface shifts to higher binding energy by 0.25 ± 0.05 eV compared to that for the stoichiometric surface, indicating downward band bending by an electron charge transfer from an O-vacancy induced surface state band to n-type TiO2 substrate. Higher binding energy shifts of Au 4f peaks observed for both substrates reveal an electron charge transfer from Au to TiO2 substrates. The work functions of Au nano-particles supported on the stoichiometric and reduced TiO2 substrates were also determined as a function of Au coverage and explained clearly by the above surface and interface dipoles. 相似文献
17.
A. Ikegami Y. Kimura H. Suzuki T. Sato T. Tanigaki O. Kido M. Kurumada Y. Saito C. Kaito 《Surface science》2003,540(2-3):395-400
Titanium carbide formation by the solid–solid reaction on the surface of Ti nanoparticles was studied in situ using a high-resolution transmission electron microscope with a heating stage. The cross-sectional image of the Ti surface was clearly observed. Vacuum-deposited carbon covered the whole the surface of Ti nanoparticles in spite of the partly evaporation on the nanoparticle surface. The diffusion of the carbon atoms inside the Ti nanoparticles depended on the size of the nanoparticles. When the Ti nanoparticle diameter was less than 30 nm, carbon atoms diffused into the Ti nanoparticle and formed TiC. The superstructure of the Ti nanoparticles was observed, which revealed the growth process of TiC to be the diffusion of carbon atoms. For Ti nanoparticles with diameter larger than 30 nm it was observed that diffusion of Ti atoms into the carbon layer was dominant, which resulted in formation of TiC in the carbon layer at the surface of Ti nanoparticles. 相似文献
18.
Kozo Okazaki Masato Hibi Yoshitaka Teraoka Takuya Nakata Kouichi Yonetani Shunji Sugai 《Journal of Physics and Chemistry of Solids》2008,69(12):3078-3081
We have investigated electron-boson coupling in the optical conductivity of high-Tc superconductors through the optical self-energy. The real part of the self-energy (ReΣop(ω)) of YBa2Cu3Oy (YBCO) shows a characteristic doping dependence. In the optimally doped YBCO, ReΣop(ω) has a single peak around 65 meV, which corresponds to the kink structure of the band dispersion. On the other hand, in the under-doped YBCO, the peak structure of ReΣop(ω) splits into two parts. To evaluate contribution from the phonons in electron-boson coupling, we have measured oxygen-isotope effects by substituting 16O→18O for the optimally doped and under-doped YBCO. 相似文献
19.
Ahmad A. Salaimeh Jeffrey J. Campion Belal Y. Gharaibeh Martin E. Evans Kozo Saito 《Infrared Physics & Technology》2011,54(6):517-524
Quantifying viable bacteria in liquids is important in environmental, food processing, manufacturing, and medical applications. Since vegetative bacteria generate heat as a result of biochemical reactions associated with cellular functions, thermal sensing techniques, including infrared thermography (IRT), have been used to detect viable cells in biologic samples. We developed a novel method that extends the dynamic range and improves the sensitivity of bacterial quantification by IRT. The approach uses IRT video, thermodynamics laws, and heat transfer mechanisms to directly measure, in real-time, the amount of energy lost as heat from the surface of a liquid sample containing bacteria when the specimen cools to a lower temperature over 2 min. We show that the Energy Content (EC) of liquid media containing as few as 120 colony-forming units (CFU) of Escherichia coli per ml was significantly higher than that of sterile media (P < 0.0001), and that EC and viable counts were strongly positively correlated (r = 0.986) over a range of 120 to approximately 5 × 108 CFU/ml. Our IRT approach is a unique non-contact method that provides real-time bacterial enumeration over a wide dynamic range without the need for sample concentration, modification, or destruction. The approach could be adapted to quantify other living cells in a liquid milieu and has the potential for automation and high throughput. 相似文献
20.
Ahmad A. SalaimehJeffrey J. Campion Belal Y. Gharaibeh Martin E. Evans Kozo Saito 《Infrared Physics & Technology》2012,55(1):170-172
We previously showed that infrared thermography (IRT) could be used to quantify viable Escherichiacoli, a representative gram-negative bacterium, in liquid growth media. Here, we evaluated the ability of IRT to enumerate a viable representative gram-positive organism, Staphylococcusaureus. We found that the energy content (EC) of the media was strongly positively correlated (r = 0.999) to measured viable counts of S.aureus ranging from 85 colony-forming units (CFU)/ml to ∼4 × 108 CFU/ml. The EC of S.aureus was ∼2-fold higher than that of E.coli at comparable cell concentrations suggesting that IRT may be used to distinguish genera. 相似文献