Quantization of the Kadomtsev–Petviashvili equation

We propose a quantization of the Kadomtsev–Petviashvili equation on a cylinder equivalent to an infinite system of nonrelativistic one-dimensional bosons with the masses m = 1, 2,.... The Hamiltonian is Galilei-invariant and includes the split and merge terms \(\Psi _{{m_1}}^\dag \Psi _{{m_2}}^\dag {\Psi _{{m_1} + {m_2}}}\) and \(\Psi _{{m_1} + {m_2}}^\dag {\Psi _{{m_1}}}{\Psi _{{m_2}}}\) for all combinations of particles with masses m ₁, m ₂, and m ₁ + m ₂ for a special choice of coupling constants. We construct the Bethe eigenfunctions for the model and verify the consistency of the coordinate Bethe ansatz and hence the quantum integrability of the model up to the mass M=8 sector.     

Comfortable, flexible upholstery fire barriers on base of bast, wool and thermostable fibres

The paper presents elastic barrier materials developed at the INF which play a role of filling and fire barrier material at the same time in upholstery furniture, reducing the development and spread of fire on flammable materials. The presented results of flammability and biophysical tests confirm the comfort of products.The developed barrier materials use natural fibres (wool, flax FR) characterized by good air permeability, hygroscopicity, moisture transport, elimination of electrostatic charges and have effect on climate of interiors also when blended with thermostable fibres such as Polyacrylate. These flexible structures based on blend of natural fibres and thermostable fibres with at least two barrier effects i.e. durable resistance to fire, thermal insulation, control of electrostatic phenomena.     

The -Cys-Cys- motif in Helicobacter pylori's Hpn and HspA proteins is an essential anchoring site for metal ions

The Hpn and HspA proteins from H. pylori are significant for nickel homeostasis and protect the cells from higher concentrations of external metal ions. Both proteins have a unique histidine- and cysteine-rich domain at the C terminus. The interactions of Ni(2+), Bi(3+), Zn(2+) and Cd(2+) ions with C-terminal Ac-CCSTSDSHHQ-NH(2) and Ac-EEGCCHGHHE-NH(2) fragments from Hpn and the Ac-GSCCHTGNHD-NH(2) sequence from HspA were studied by potentiometry, mass spectrometry, circular dichroism and UV-Vis spectroscopy. Ac-CC-NH(2) was used as a reference peptide. The studies have shown that nickel ions form planar complexes with a {2S(-),N(-)} binding mode. The thiol sulfurs of the -Cys-Cys- motif are also the anchoring sites for Bi(3+), Zn(2+) and Cd(2+) ions. The studied protein fragments have the highest affinity for Bi(3+) ions. The thermodynamic stability of Ni(2+) is much higher then that of Zn(2+).     

Alternative spiroketalization methods toward purpuromycin: a hemiketal conjugate addition strategy and use of an electron-rich isocoumarin precursor

Two methods are presented that were designed to circumvent the persistent problem of benzofuran formation and instead yield a spiroketal of the rubromycin family type. First, using an alternative disconnection, a hemiketal conjugate addition to a naphthaquinone electrophile was investigated. Synthesis of the requisite electrophile provided insight into the selective oxidation and functionalization of the naphthalene portion. Second, the electronic features of the isocoumarin ring system were adjusted, and the corresponding reactivity further supports the hypothesis that electron-rich isocoumarins are capable of spiroketalization. Robust, flexible syntheses from simple precursors were developed that allowed multiple reduced isocoumarins to be generated. Combined, the data presented herein give insight into the sensitivities of this family and illuminate other potential methods of spiroketalization. In addition, the convergent assembly of substrates containing different naphthaquinone and isocoumarin subunits highlights the utility of our 1,3-dipolar cycloaddition approach to generate analogs of these structures for SAR, as well as chemical reactivity studies.     

Correction: Dermatan sulfate in tunicate phylogeny: Order-specific sulfation pattern and the effect of [→4IdoA(2-Sulfate)β-1→3GalNAc(4-Sulfate)β-1→] motifs in dermatan sulfate on heparin cofactor II activity

After the publication of the work entitled "Dermatan sulfate in tunicate phylogeny: Order-specific sulfation pattern and the effect of [→4IdoA(2-Sulfate)β-1→3GalNAc(4-Sulfate)β-1→] motifs in dermatan sulfate on heparin cofactor II activity", by Kozlowski et al., BMC Biochemistry 2011, 12:29, we found that the legends to Figures 2 to 5 contain serious mistakes that compromise the comprehension of the work. This correction article contains the correct text of the legends to Figures 2 to 5.     

Measurement of neutron energy spectra and neutron-gamma angular correlations for the muon capture process 16O(μ−, νμxn)14, 15N

Neutron-gamma coincidence spectra have been measured for muon capture in ¹⁶O. The γ-spectrum is dominated by the ground state transitions from the $\text{3}\text{2}{}^{\mathrm{?}}\text{(6.32}\text{MeV}\text{)}\text{and}\text{1}\text{2}{}^{\mathrm{+}}\text{+}\text{5}\text{2}{}^{\mathrm{+}}\text{(5.3}\text{MeV}\text{)}$ states of ¹⁵N that are populated after the emission of one neutron. The neutron energy spectra and the neutron energy dependence of the ny angular correlation coefficient A₂ for these final states are presented. The observed transitions in ¹⁴N and the associated neutron spectra give direct evidence for the emission of two correlated neutrons. The data are discussed in terms of direct neutron emission plus emission via giant resonance intermediate states of ¹⁶N. The large yield for the emission of one and two fast neutrons is explained by a capture mechanism involving short-range nucleon-nucleon correlations.     

Eine neue Synthese von Dihydrofuryliumsalzen

Ohne Zusammenfassung     

A class of affine maximal hypersurfaces

We describe a class of affine maximal surfaces lying in the threedimensional affine space. Every bounded domain in the plane may covered by an unbounded domain which is the range of definition of an affine maximal surface.     

Theoretical analysis of the structural and electronic properties of metalloporphyrin pi-cation radicals

A method for analyzing the A(1u)/A(2u) contents of metalloporphyrin pi-cation radicals is developed and applied to a series of unsubstituted planar metalloporphines (MPs) (M=Cr, Mn, Fe, Co, Ni, Cu, and Zn). The structures and electronic properties of the MPs and their cation radicals were calculated by density functional theory (DFT) and subsequently analyzed. It was found that the MPs with small core sizes have a tendency to form A(1u)-type radicals, while the MPs with large core size have a preference for an A(2u)-type. Neither of these pure-state species, however, is stable under the D(4)(h) symmetry, and both radical cation types are subject to pseudo-Jahn-Teller (pJT) distortion. The pJT distortion leads to structures with lower symmetry and states that have mixed character with respect to the A(1u) and A(2u) components. The degree of mixing could be estimated by employing orbital projection technique or a complementary spin density decomposition. Both techniques produce very similar results, pointing out that the frontier orbital, which becomes empty upon electron removal, plays a critical role in determining electronic properties.