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31.
S. G. Kozlova S. P. Gabuda V. E. Fedorov N. G. Naumov Yu. V. Mironov 《Journal of Structural Chemistry》2011,52(4):806-808
A topological method of quantum chemistry (AIM) is used to study the contact area of a triangular bridging group {CS3} in 12-nuclear cluster fragments of {Re12CS17}. It is shown that in the region under consideration the intramolecular interaction is characterized by a ring critical point
(rcp), and its parameters depend on the oxidation state and explain the unusual structural changes in cluster complexes in
redox transformations: [Re12CS17(CN)6]8− ↔ [Re12CS17(CN)6]6−. 相似文献
32.
L. I. Anikhovskaya V. S. Kas’kov E. A. Kuznetsova L. P. Kozlova 《Polymer Science Series D》2009,2(2):124-126
The possibility of using the bonding method to assemble beryllium ABM-1 alloy has been analyzed. Recommendations are given in relation to the types of film adhesives for bonding parts. It has been established that the soundest results in regards to strength properties and anticorrosion protection can be achieved through the anodic oxidation of alloy’s surface and an additional application of an EP-0214 coat. 相似文献
33.
V. A. Shipachev V. G. Isakova S. G. Kozlova I. A. Baidina S. A. Gromilov 《Journal of Structural Chemistry》1999,40(2):214-219
Crystal hydrates were synthesized based on aquaions of noble metals [M(H2O)6]F3·nH2O, where n = 3–8 and M = Ir, Rh. The structure of the resulting crystal hydrates with three aqueous molecules is characterized
by the space group P3, Z = 1 and has a layered form. The positively charged layers [M(H2O)6F
2
+
which alter with negatively charged layers of the composition ∼-·3H2O, are located perpendicular to the c axis. According to X-ray structural and nuclear magnetic resonance data, the water molecules
and the F- ions in the negatively charged layers are disordered.
Translated fromZhurnal Strukturnoi Khimii, Vol.40, No. 2, pp. 259–264, March–April, 1999. 相似文献
34.
V. P. Lezina M. M. Kozlova S. B. Gashev L. V. Gol'tsova A. U. Stepanyants L. D. Smirnov 《Chemistry of Heterocyclic Compounds》1987,23(10):1098-1105
Features of the change in the chemical shifts of the protons of substituted pyridine-, pyrimidine-, 3-hydroxypyridine-, and 5-hydroxypyrimidine-1-oxides, as dependent on the basicity of the medium, were investigated. The ionization constants and the possible forms of the occurrence of the molecules were determined. The character of the influence of the substituents (alkyl, hydroxyl) on the pKa values and the PMR spectral parameters was obtained. The comparison of the results obtained with the data on substituted pyridines and pyrimidines was carried out.For Communication 1, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1369–1376, October, 1987. 相似文献
35.
The flow past triangular slipping wings is considered in strong viscous interaction conditions. It is shown that the solution of each of the problems discussed is not unique. The condition is obtained which has to be satisfied by the solution on the axis of symmetry of a triangular wing of infinite dimensions. The class of self-similar flows in the boundary layer of a thin triangular wing is found.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 94–99, November–December, 1970. 相似文献
36.
利用溶液聚合和成酰胺反应合成了多功能梳状两亲性共聚物,聚(甲基丙烯酸-co-甲基丙烯酸十八酯)-(乙醇胺-乙二胺叶酸)(PSM-EE-FA).用红外光谱(FTIR),核磁共振(1H-NMR)及凝胶渗透色谱(GPC)表征了该聚合物的结构及分子量分布.实验结果证明合成了该聚合物,其数均分子量(Mn)为28600,多分散性为1.375.用该两亲梳状聚合物包覆油溶性CdSe/ZnS量子点,通过相转移作用,得到水溶性靶向量子点(PSM-EE-FA-QDs).该水溶性量子点溶液具有较好的稳定性.通过紫外-可见(UV-Vis)及荧光发射光谱分析对该量子点的光学性质进行研究.结果表明,PSM-EE-FA-QDs的紫外-可见光谱及荧光发射光谱峰形与原量子点基本一致.由于量子点表面聚合物层的形成,峰位发生少量红移.该量子点水溶液的荧光强度是原量子点氯仿溶液的98%,荧光产率是原量子点氯仿溶液的95%.动态光散射(DLS)及透射电镜(TEM)测试结果表明水溶性量子点分布均匀.合成的水溶性量子点不但光学性能稳定,而且聚合物及水溶性量子点的合成方法较为简便. 相似文献
37.
S. P. Gabuda A. S. Kolesnikov S. G. Kozlova A. G. Lundin N. K. Moroz 《Applied magnetic resonance》2011,41(2-4):439-447
The disordered structure of absorbed water in a highly porous zeolite chabazite Ca2[Al4Si8O24]·nH2O (2 ≤ n ≤ 12.8) is studied from motionally narrowed 1H nuclear magnetic resonance spectra at room temperature. Concentration phase transitions were observed at n ≈ 8.3 and n ≈ 10.2. The transitions are accompanied by displacement of Ca2+ ions and variation of the Broensted acid centers at inner surface of zeolite pores. 相似文献
38.
39.
40.
I. V. Kozlov V. B. Odzhaev V. N. Popok I. I. Azarko E. I. Kozlova 《Journal of Applied Spectroscopy》1998,65(4):583-588
Films of polyethylene, polyethylene terephthalate, and polyamine-6 implanted with B+ and N+ ions with an energy of 100 keV are investigated by an EPR method in a dose interval of 1·1014–1·1017 cm−2. It is shown that paramagnetic centers with g=2.0025 formed in the implanted polymers have a nature similar to the nature
of paramagnetic centers of pyrolized and initially conducting polymers. Correspondence of the character of the variation in
paramagnetic characteristics of the modified polymers to the model proposed earlier for the formation of pyrocarbon “drops”
in ion implantation is revealed. The relaxation times for paramagnetic centers in the implanted polymer films are calculated
and assumptions are made about the formation of a quasi-two-dimensional electron gas as well as the possibility of magnetic
ordering in polymer-film layers modified by high-dosage implantation. The effect of oxygen on the electron states of the implanted
polymer specimens is studied.
Belarusian State University, 4, Skorina Ave., Minsk, 220050 Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol.
65, No. 4, pp. 562–567, July–August, 1998. 相似文献