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101.
Photoinduced Charge‐Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?
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Dr. Jinxuan Liu Wencai Zhou Jianxi Liu Dr. Ian Howard Dr. Goran Kilibarda Dr. Sabine Schlabach Damien Coupry Dr. Matthew Addicoat Satoru Yoneda Yusuke Tsutsui Dr. Tsuneaki Sakurai Prof. Dr. Shu Seki Dr. Zhengbang Wang Peter Lindemann Dr. Engelbert Redel Prof. Thomas Heine Prof. Dr. Christof Wöll 《Angewandte Chemie (International ed. in English)》2015,54(25):7441-7445
For inorganic semiconductors crystalline order leads to a band structure which gives rise to drastic differences to the disordered material. An example is the presence of an indirect band gap. For organic semiconductors such effects are typically not considered, since the bands are normally flat, and the band‐gap therefore is direct. Herein we show results from electronic structure calculations demonstrating that ordered arrays of porphyrins reveal a small dispersion of occupied and unoccupied bands leading to the formation of a small indirect band gap. We demonstrate herein that such ordered structures can be fabricated by liquid‐phase epitaxy and that the corresponding crystalline organic semiconductors exhibit superior photophysical properties, including large charge‐carrier mobility and an unusually large charge‐carrier generation efficiency. We have fabricated a prototype organic photovoltaic device based on this novel material exhibiting a remarkable efficiency. 相似文献
102.
Molecular Diversity - In designing drug dosing for hemodialysis patients, the removal rate (RR) of the drug by hemodialysis is important. However, acquiring the RR is difficult, and there is a need... 相似文献
103.
G Tanabe S Nakamura N Tsutsui G Balakishan W Xie S Tsuchiya J Akaki T Morikawa K Ninomiya I Nakanishi M Yoshikawa O Muraoka 《Chemical communications (Cambridge, England)》2012,48(69):8646-8648
With the aid of an in silico method, α-glucosidase inhibitors with far more potent activities than salacinol (1), a potent natural α-glucosidase inhibitor isolated from an Ayurvedic traditional medicine Salacia reticulata, have been developed. 相似文献
104.
Kobayashi H Tsuchiya K Ogino K Vacha M 《Physical chemistry chemical physics : PCCP》2012,14(29):10114-10118
Single-molecule study of phenylenevinylene oligomers revealed distinct spectral forms due to different conjugation lengths which are determined by torsional defects. Large spectral jumps between different spectral forms were ascribed to torsional flips of a single phenylene ring. These spectral changes reflect the dynamic nature of electron delocalization in oligophenylenevinylenes and enable estimation of the phenylene torsional barriers. 相似文献
105.
Kousuke Tobari Mitsuru OhtakeKatsumasa Nagano Masaaki Futamoto 《Journal of magnetism and magnetic materials》2012,324(6):1059-1062
Co/Pd epitaxial multilayer films were prepared on Pd(111)fcc underlayers hetero-epitaxially grown on MgO(111)B1 single-crystal substrates at room temperature by ultra-high vacuum RF magnetron sputtering. In-situ reflection high energy electron diffraction shows that the in-plane lattice spacing of Co on Pd layer gradually decreases with increasing the Co layer thickness, whereas that of Pd on Co layer remains unchanged during the Pd layer formation. The CoPd alloy phase formation is observed around the Co/Pd interface. The atomic mixing is enhanced for thinner Co and Pd layers in multilayer structure. With decreasing the Co and the Pd layer thicknesses and increasing the repetition number of Co/Pd multilayer film, stronger perpendicular magnetic anisotropy is observed. The relationships between the film structure and the magnetic properties are discussed. 相似文献
106.
Tsutsui H Fujii S Sakamoto T Min JZ Todoroki K Toyo'oka T 《Journal of separation science》2012,35(13):1551-1559
Mass spectrometry (MS) has become a popular analytical technique because of its high sensitivity and specificity. Therefore, the use of a chiral derivatization reagent for the MS detection seems to be efficient for the enantiomeric separation of racemates. However, the number of chiral reagents for the liquid chromatography (LC)-tandem mass spectrometry (MS/MS) analysis is very limited. The applicability of commercially available chiral amines as the derivatization reagents for the enantiomeric separation of chiral carboxylic acids is reported in this paper by using non-steroidal anti-inflammatory drugs (NSAIDs), i.e. ibuprofen, flurbiprofen, and loxoprofen. The efficiency of the chiral reagents was evaluated in terms of tagging easiness, separation by reversed-phase chromatography, and detection sensitivity by electrospray ionization (ESI)-MS/MS. Among the tested eight chiral amines, i.e. (R)-(+)-4-(3-aminopyrrolidin-1-yl)-7-(N,N-dimethylaminosulfonyl)-2,1,3-benzoxadiazole (DBD-APy), (S)-(+)-1-(2-pyrrolidinylmethyl)-pyrrolidine (PMP), L-prolinamide, (3R)-(-)-1-benzyl-3-aminopyrrolidine, (S)-(+)-1-cyclohexyl-ethylamine, (3R)-(+)-3-(trifluoroacetamido)-pyrrolidine (TFAP), (R)-(-)-1-aminoindan (AI), and (S)-(+)-tetrahydrofurfuryl-amine, DBD-APy, PMP, AI, and TFAP could be used as the chiral reagents for the enantiomeric separation of the NSAIDs. The Rs values and the detection limits of the derivatives were in the range of 1.29-3.85 and 0.57-0.96 fmol, respectively. These four reagents were applied for the determination of the NSAIDs in rat plasma. 相似文献
107.
Kei Kamada Takayuki Yanagida Jan Pejchal Martin Nikl Takanori Endo Kousuke Tsutumi Yoshiyuki Usuki Yutaka Fujimoto Akihiro Fukabori Akira Yoshikawa 《Journal of Crystal Growth》2012,352(1):84-87
Pr:Gd3(Ga,Al)5O12 single crystals were grown by the micro-pulling down (μ-PD) method. All grown crystals were greenish and transparent with 3.0 mm in diameter, 15–30 mm in length. Neither visible inclusions nor cracks were observed. Luminescence and scintillation properties were measured. The substitution at the Al3+ sites by Ga3+ in garnet structure has been studied. In these crystals, Pr3+ 5d–4f emission is observed with 340 nm wavelength. Pr1%:Gd3Ga3Al2O12 shows highest emission intensity. The light yield of Pr:Gd3Ga3Al2O12 sample with 3 mmφ×1 mm size was around 4500 photon/MeV. Scintillation decay time was 7.9 ns (0.5%), 46 ns (0.7%) and 214 ns (98.8%). 相似文献
108.
109.
Network DEA: A slacks-based measure approach 总被引:2,自引:0,他引:2
Traditional DEA models deal with measurements of relative efficiency of DMUs regarding multiple-inputs vs. multiple-outputs. One of the drawbacks of these models is the neglect of intermediate products or linking activities. After pointing out needs for inclusion of them to DEA models, we propose a slacks-based network DEA model, called Network SBM, that can deal with intermediate products formally. Using this model we can evaluate divisional efficiencies along with the overall efficiency of decision making units (DMUs). 相似文献
110.
D. Reznik T. Fukuda A.Q.R. Baron S. Tsutsui K. Yamada 《Journal of Physics and Chemistry of Solids》2008,69(12):3103-3107
Inelastic X-ray scattering (IXS) was used to study the Cu-O bond-stretching vibrations in the static stripe phase compound La1.48Nd0.4Sr0.12CuO4. It was found that the intrinsic width in Q-space of the previously reported huge anomalous phonon softening and broadening is approximately 0.08 r.l.u. HWHM. A detailed comparison was also made to inelastic neutron scattering (INS) studies, which indicate a two-peak lineshape (with superimposed broad and narrow peaks) in the vicinity of the anomaly. The high resolution IXS data show that the narrow peak is mostly an artifact of the poor transverse Q-resolution of INS. Otherwise, the agreement between the INS and IXS was excellent. 相似文献