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111.
A simple dipeptide, (S)-phenylglycyl-(R)-phenylglycine (S,R-1), formed inclusion compounds with a small amide such as formamide, acetamide, N,N-dimethylformamide (DMF), or N,N-dimethylacetamide. By single-crystal X-ray analysis, the inclusion compounds were shown to have a wavy layer structure. The molecules of S,R-1 are arranged in parallel via ionic pairing of the carboxyl and amino groups to construct the wavy layers. The guest molecules were accommodated in a channel cavity between the layers by means of hydrogen bonding with (+)NH(3) of S,R-1. The cavity is surrounded by the phenyl groups of S,R-1 that conformationally rotate so as to make the cavity size fit the guest amide. 相似文献
112.
113.
Kousuke?Kuto Hiroshi?Matsuzawa Rui?PengEmail author 《Calculus of Variations and Partial Differential Equations》2017,56(4):112
Cui and Lou (J Differ Equ 261:3305–3343, 2016) proposed a reaction–diffusion–advection SIS epidemic model in heterogeneous environments, and derived interesting results on the stability of the DFE (disease-free equilibrium) and the existence of EE (endemic equilibrium) under various conditions. In this paper, we are interested in the asymptotic profile of the EE (when it exists) in the three cases: (i) large advection; (ii) small diffusion of the susceptible population; (iii) small diffusion of the infected population. We prove that in case (i), the density of both the susceptible and infected populations concentrates only at the downstream behaving like a delta function; in case (ii), the density of the susceptible concentrates only at the downstream behaving like a delta function and the density of the infected vanishes on the entire habitat, and in case (iii), the density of the susceptible is positive while the density of the infected vanishes on the entire habitat. Our results show that in case (ii) and case (iii), the asymptotic profile is essentially different from that in the situation where no advection is present. As a consequence, we can conclude that the impact of advection on the spatial distribution of population densities is significant. 相似文献
114.
Vattuone L Savio L Gerbi A Okada M Moritani K Rocca M 《The journal of physical chemistry. B》2007,111(7):1679-1683
We have investigated oxygen adsorption on Cu(410) by high-resolution electron energy loss spectroscopy, dosing O2 with a supersonic molecular beam at different surface temperatures and for different angles of incidence and beam energies or by backfilling. In the investigated crystal temperature range (127 < T < 570 K), adsorption is always dissociative. Depending on T, impact energy, and angle of incidence, the oxygen atoms end up in different adsorption configurations, characterized by different vibrational signatures. In particular, at grazing incidence when only the step edge is exposed to O2, the adatoms end up initially preferentially at the step edge. An ordered overlayer forms at half monolayer coverage when the adsorbate is mobile. Oxide patches develop eventually for large exposures performed by backfilling and at high crystal temperature. 相似文献
115.
Akihide Kaizawa Nobuhiro Maruoka Atsushi Kawai Hiroomi Kamano Tetsuji Jozuka Takeshi Senda Tomohiro Akiyama 《Heat and Mass Transfer》2008,44(7):763-769
A waste heat transportation system––trans-heat (TH) system––is quite attractive that uses the latent heat of a phase change
material (PCM). The purpose of this paper is to study the thermophysical properties of various sugars and sodium acetate trihydrate
(SAT) as PCMs for a practical TH system and the heat transfer property between PCM selected and heat transfer oil, by using
differential scanning calorimetry (DSC), thermogravimetry-differential thermal analysis (TG-DTA) and a heat storage tube.
As a result, erythritol, with a large latent heat of 344 kJ/kg at melting point of 117°C, high decomposition point of 160°C
and excellent chemical stability under repeated phase change cycles was found to be the best PCM among them for the practical
TH system. In the heat release experiments between liquid erythritol and flowing cold oil, we observed foaming phenomena of
encapsulated oil, in which oil droplet was coated by solidification of PCM. 相似文献
116.
Tomoaki Kawaguchi Koji Tagawa Fumiyo Senda Takayuki Matsunaga Hiromi Kitano 《Journal of colloid and interface science》1999,210(2):290
Amphiphiles which carry many pendent galactose residues as side chains were prepared by telomerization of 2-methacryloyloxyethyl β-D-galactopyranoside (MEGal) or 3-(2-methacryloyl aminoethylthio)propylD-galactopyranoside (MEPGal, α:β = 3.9:1) using a lipophilic radical initiator. The galactose-carrying amphiphiles (DP (degree of polymerization) = 15) incorporated in liposomes were recognized by a lectin fromRicinus communis(RCA120), which was proven by the increase in turbidity of the liposome suspension after mixing with the lectin. The recognition was largely affected by the distance between the galactose residues and the polymer main chain, and the surface density of the amphiphile in the liposomes. The liposomes containing these galactolipids were not taken up by mouse peritoneal macrophages, probably due to a steric hindrance of polymer main chains from the uptake of D-galactose receptors on the macrophages. 相似文献
117.
118.
The entropy generation analysis of adiabatic combustion systems was performed to quantify the exergy losses which are mainly the exergy destroyed during combustion inside the chamber and in the exhaust gases. The purpose of the present work was therefore: (a) to extend the exergy destruction analysis by including the exhaust gas exergy while applying the hybrid filtered Eulerian stochastic field (ESF) method coupled with the FGM chemistry tabulation strategy; (b) to introduce a novel method for evaluating the exergy content of exhaust gases; and (c) to highlight a link between exhaust gas exergy and combustion emissions. In this work, the adiabatic Sandia flames E and F were chosen as application combustion systems. First, the numerical results of the flow and scalar fields were validated by comparison with the experimental data. The under-utilization of eight stochastic fields (SFs), the flow field results and the associated scalar fields for the flame E show excellent agreement contrary to flame F. Then, the different exergy losses were calculated and analyzed. The heat transfer and chemical reaction are the main factors responsible for the exergy destruction during combustion. The chemical exergy of the exhaust gases shows a strong relation between the exergy losses and combustion emission as well as the gas exhaust temperature. 相似文献
119.
Nakai K Nakada Y Hakuman M Yoshida M Senda Y Tateishi Y Sonoda J Naono H 《Journal of colloid and interface science》2012,367(1):383-393
The standard α(s)-data of N(2) at 87.3 K by graphitized and nongraphitized carbon black samples (GCB-I and NGCB) (cf.Figs. 3 and 4) have been determined on the basis of the high resolution adsorption isotherms of N(2) at 87.3 K, which were repeatedly measured in the pressure range of p/p(o)=5×10(-8)-0.4. The high resolution adsorption isotherms of N(2) by two kinds of activated carbon fibers (ACF-I and ACF-II) were measured from p/p(o)=10(-7) to p/p(o)=0.995 at 77.4 K and from p/p(o)=10(-7) to p/p(o)=0.4 at 87.3 K. Combination of the adsorption isotherms by ACF-I and ACF-II with the standard α(s)-data by NGCB at 77.4 K and 87.3 K make it possible to construct the high resolution α(s)-plots from very low filling (1%) to complete filling (100%). The high resolution α(s)-plots of N(2) at 77.4 K and 87.3 K were analyzed. On the basis of the analyzed result, the porous textures of ACF-I and ACF-II will be discussed. 相似文献
120.
Kousuke Nishimura Ikuya Yamada Kengo Oka Yuichi Shimakawa Masaki Azuma 《Journal of Physics and Chemistry of Solids》2014
A new cubic perovskite BaVO3 was synthesized by high-pressure synthesis at 15 GPa, and 1350 °C. Contrary to our expectations that lattice expansion by Ba substitution for Sr would lead to non-centrosymmetric tetragonal distortion, BaVO3 preserved its cubic crystal structure with a=3.94288(3) Å at room temperature and had Fermi-liquid characteristics as SrVO3 down to the lowest temperature. 相似文献