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81.
Aminopolycarboxylic acid-type cellulose (Chelest Fiber Iry) has been studied for its sorption efficiencies with respect to lead from acidic solution. The influence pH and other properties related to sorption kinetic, isotherm, maximum capacity, stability and the mechanism of the sorption were discussed.Lead was quantitatively retained on the proposed adsorbent in the pH range of 2.5-5.5 (studied pH range 1.5-5.5). The maximum sorption capacity was found to be 0.86±0.06 mmol/g adsorbent. The decline in the efficiency of the adsorbent was not observed for repeated adsorption-desorption cycles. It was found that the preconcentration factor of 200 can be achieved. The limit of determination was found to be about 1 μg Pb/2 l. The method was applied to the determination of lead in water samples. 相似文献
82.
83.
Yusuke Asakuma Kyuya Nakagawa Kouji Maeda Keisuke Fukui 《Polymer Degradation and Stability》2009,94(2):240-245
The depolymerization reaction of polyethylene terephthalate (PET) was analyzed using a computational chemistry approach. The reaction is a type of transesterification reaction using alkoxide. In this study we employed the calculated optimum structure, electrostatic potential distribution, activation energy, electric charges and pathway to investigate the mechanism. We found that the tetrahedral intermediate produced by ring formation with alkoxide is an essential feature of the depolymerization process. Moreover, there is a possibility that a PET molecule is depolymerized by multiple alkoxides at the same time. However, the effects of degree of polymerization and the position of attack by the alkoxides do not strongly influence the reactivity. 相似文献
84.
Akira Kotani Kouji Takahashi Hideki Hakamata Satoshi Kojima Fumiyo Kusu 《Analytical sciences》2007,23(2):157-163
Attomole quantities of catechins were determined by a capillary liquid chromatography system with electrochemical detection (CLC-ECD) and the system is applied to the determination of catechins in human plasma. The eight catechins: catechin (C), epicatechin (EC), gallocatechin (GC), epigallocatechin (EGC), catechin gallate (Cg), epicatechin gallate (ECg), gallocatechin gallate (GCg), and epigallocatechin gallate (EGCg), were separated within 10 min using a capillary column (0.2 mm i.d.) and a mobile phase of phosphoric acid (85%)-methanol-water (0.5:27.5:72.5, v/v/v), and were detected at +0.85 V vs. Ag/AgCl. Peak heights were found to be linearly related to the amount of catechins injected, from 200 amol to 500 fmol (r > 0.998). The detection limits of the catechins were 61 amol for EGC, 75 amol for EC, 54 amol for GC, 61 amol for C, 67 amol for GCg, 75 amol for EGCg, 75 amol for ECg and 89 amol for Cg (S/N = 3). Because the present method is highly sensitive and allows facile pretreatment for plasma sample, the time courses of concentrations of catechins (GCg, EC, EGCg, ECg, and Cg) and their conjugates in human plasma obtained from a 10 microl plasma sample after ingestion of green tea could be determined. 相似文献
85.
Tetsuji Yata Dr. Yoshihiro Nishimoto Dr. Kouji Chiba Prof. Dr. Makoto Yasuda 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(32):8288-8294
Fluorinated heterocycles have attracted much attention in the pharmaceutical and agrochemical industries. Many strategies have already been developed to achieve the synthesis of fluorinated heterocycles. Formidable challenges remain, however, in the synthesis of fluorinated isocoumarin derivatives that are among the most alluring structural motifs. Herein, the indium-catalyzed C−F bond transformation of 2-(2,2-difluorovinyl) benzoates is reported, which are readily accessible compounds, to give a diverse array of fluorinated isocoumarins. The present reaction proceeds smoothly using inexpensive reagents: a catalytic amount of indium salt in the presence of zinc salt. A theoretical calculation of potential energy profiles showed that the reaction consists of oxymetalation with the elimination of alkyl halide and the β-fluorine elimination. 相似文献
86.
Kakehi A Suga H Okumura Y Itoh K Kobayashi K Aikawa Y Misawa K 《Chemical & pharmaceutical bulletin》2010,58(11):1502-1510
The alkaline treatment of the pyridinium salts, readily available from the S-alkylations of 3-amino-4-(1-pyridinio)thiophene-5-thiolates with various alkyl halides, in chloroform at room temperature afforded the corresponding thieno[3',4':4,5]imidazo[1,2-a]pyridine derivatives in low to moderate yields via the intramolecular cyclization of the resulting 1,5-dipoles followed by the aromatization of the primary cycloadducts. Interestingly, the reactions using unsymmetrical 3-amino-4-[1-(3-methylpyridinio)]thiophene-5-thiolates afforded only 8-methylthieno[3',4':4,5]imidazo[1,2-a]pyridines and the other 6-methyl derivatives were not formed at all. In addition the isolation of a byproduct in the condensation reaction of pyridinium salt with the solvent (CHCl?) is also discussed. 相似文献
87.
Higuchi R Inoue S Inagaki K Sakai M Miyamoto T Komori T Inagaki M Isobe R 《Chemical & pharmaceutical bulletin》2006,54(3):287-291
A ganglioside molecular species GP-3 (1) has been obtained from the water-soluble lipid fraction of the chloroform/methanol extract of the starfish Asterina pectinifera. The structure of the ganglioside has been determined on the basis of chemical and spectroscopic evidence. Compound 1 represents new ganglioside molecular species possessing two moles of sialic acids at the inner part of the sugar moiety. Partial hydrolysis by hot water and an enzymatic hydrolysis by means of endoglycoceramidase (EGCase) have proved useful for structure elucidation of the complex oligosaccharide moiety. Moreover, 1 exhibits neuritogenic activity toward the rat pheochromocytoma cell line, PC-12 cells, in the presence of nerve growth factor (NGF). 相似文献
88.
[Structure: see text] A total synthesis of PD 113,271, an antitumor fostriecin analogue isolated from Streptomyces pulveraceus, was achieved by the chiral pool approach starting with D-galactose and L-tartaric acid. The synthesis of PD 113,271 led to unambiguous assignment of the relative and absolute stereochemistry of its stereocenters. 相似文献
89.
90.
In this paper, we discuss with guaranteed a priori and a posteriori error estimates of finite element approximations for not necessarily coercive linear second order Dirichlet problems. Here, ‘guaranteed’ means we can get the error bounds in which all constants included are explicitly given or represented as a numerically computable form. Using the invertibility condition of concerning elliptic operator, guaranteed a priori and a posteriori error estimates are formulated. This kind of estimates plays essential and important roles in the numerical verification of solutions for nonlinear elliptic problems. Several numerical examples that confirm the actual effectiveness of the method are presented. 相似文献