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51.
Fluoro-, chloro-, bromo-, and iodocyclopropane derivatives were obtained in 10–80% yields by the reaction of FCHI2, ClCHI2, BrCHI2, and CHI3, respectively, with Cu in the presence of olefins. The reaction was electrophilic, and proceeded stereospecifically, i.e., cis and trans olefins afforded cyclopropane derivatives whose configurations with respect to the substituents from original olefins were cis and trans, respectively. Since isomeric olefins were not detected in the reaction mixture which would be expected from the insertion of the corresponding free monohalocarbenes into C—H bonds, the reaction seemed to proceed via organocopper intermediates rather than free monohalocarbenes. With respect to the configuration of the halogen introduced by the new reaction, the cis or endo isomers were generally obtained predominantly over the corresponding trans or exo isomers. 相似文献
52.
Kunio Fujiwara 《Foundations of Physics》1980,10(3-4):309-331
We investigate the novel problem of what happens in special relativity and in relativistic field theories whenthree-dimensional space is quantized. First we examine the equation for elastic waves on a linear chain, the simplest example of a quantized medium, and propose, on its analogy, a nonlinearp-k relationp=k(sinhkl)/kl for light and material waves. Here,kl is a new variable which represents the space-quantization effect on the plane wave of wave numberk=|k|. (Note thatkl=0 givesp=k.) This relation makes the light velocity in vacuum dependent onkl. We postulate, however, that the phase and group velocities of each individual light wave are still invariant, and try to generalize special relativity to the case ofkl 0. This can be simply done if the invariance ofkl is assumed. Our results suggest that localization might be a relative concept. One interesting consequence of our proposal is that relativistic field theories become automatically finite. This comes out without violating unitarity or causality. A precise measurement of velocities of high-energy photons or massive particles is desirable for checking our proposal. 相似文献
53.
Yanagi T Kitajima A Anzai K Kodama K Mizoguchi J Fujiwara H Sakiyama H Kamoda O Kamei C 《Chemical & pharmaceutical bulletin》1999,47(11):1650-1654
Of 4-amino-5-chloro-2-methoxy-N-(1-ethyl-2-hydroxymethyl-4- pyrrolidinyl)benzamide, four optical isomers, (2S,4S)-1 (TKS159), (2S,4R)-25, (2R,4S)-26 and (2R,4R)-27, were prepared from optically active 4-amino-1-ethyl-2-hydroxymethylpyrrolidine di-p-toluenesulfonate [(2S,4S)-14, (2S,4R)-17, (2R,4S)-20 and (2R,4R)-23, respectively]. The requisites, (2S,4S)-14, (2S,4R)-17, (2R,4S)-20 and (2R,4R)-23, were prepared from a commercially available trans-4-hydroxy-L-proline. The absolute configurations of (2S,4S)-1 (TKS159), (2S,4R)-25, (2R,4S)-26 and (2R,4R)-27 were spectroscopically determined. Of the benzamide derivatives, four optical isomers, (2S,4S)-1, (2S,4R)-25, (2R,4S)-26 and (2R,4R)-27, showed a relatively potent affinity for 5-hydroxytryptamine 4 (5-HT4) receptors in a radioligand binding assay ([3H]GR113808). The activities of 25-27 were less effective than that of 1 for the gastric emptying of a phenol red semisolid meal in rats. All this suggests that the most potent of the isomers was 4-amino-5-chloro-2-methoxy-N-[(2S,4S)-1-ethyl-2- hydroxymethyl-4-pyrrolidinyl]benzamide (1). 相似文献
54.
Y. Kameo A. Katayama A. Fujiwara T. Haraga M. Nakashima 《Journal of Radioanalytical and Nuclear Chemistry》2007,274(1):71-78
A rapid determination method in which beta-ray spectrometry was combined with solid phase extraction using Sr Rad Disk was
developed for the determination of 89Sr and 90Sr in low-level radioactive waste. Various amounts of 89Sr, 90Sr, and 90Y retained by the Sr Rad Disk was measured by a beta-ray spectrometer, and it was found that both 89Sr and 90Sr were simultaneously determined with <30% error (2σ) at 89Sr/90Sr radioactivity ratio of 0.3 to 45. The present method was successfully applied to actual radioactive liquid waste samples
arising from nuclear facilities in Japan Atomic Energy Agency. Strontium was simply separated from interfering nuclides such
as 137Cs and 154Eu, and matrix components by the Sr Rad Disk, and the results obtained by beta-ray spectrometry was in good agreement with
that of the conventional analysis. 相似文献
55.
Concise construction of the trans-fused 7/7/6/6 tetracyclic ether part of hemibrevetoxin B (1) was achieved by a convergent strategy based on coupling reaction of an acyl anion equivalent, reductive cyclization of an α,ε-dihydroxyketone, and introduction of a methyl group at the central ring junction by the Nicolaou method. The resultant tetracyclic ether was transformed into the known intermediate, which was already converted to 1 by the Yamamoto group, thereby completing the formal total synthesis of 1. 相似文献
56.
Computer-aided structure elucidation methodology is discussed. Major processes involved in computer-aided structure elucidation systems are partial-structure elucidation, structure generation, and structure examination. For the three representative systems CONGEN, CASE, and CHEMICS, these processes are examined. There are four necessary conditions for automated chemical structure elucidation systems: reliability, width of application, ease of modification and portability. 相似文献
57.
58.
Okuyama Y Nakano H Takahashi K Hongo H Kabuto C 《Chemical communications (Cambridge, England)》2003,(4):524-525
Easily prepared, chiral sulfideoxathiane ligands are described which give excellent enantioselectivity (up to 99% ee) in the Pd-catalyzed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with a range of alkyl malonate nucleophiles. 相似文献
59.
A new heterocyclic compound, [1]benzopyrano[2,3,4-kl]acridin-3-ol was synthesized by cyclization of xanthone derivatives. The key compound, 1-(3'-methoxyanilino)-xanthone, was prepared from 1-aminoxanthone. [1]benzopyrano[2,3,4-kl]acridin-3-ol analogues, [1]benzothiopyrano[2,3,4-kl]acridin-3-ol, pyrido[3',2':5,6]pyrano[2,3,4-kl]acridin-3-ol and pyrido[3',2':5,6]thiopyrano[2,3,4-kl]acridin-3-ol were synthesized by the same method. 相似文献
60.