首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   676篇
  免费   79篇
  国内免费   83篇
化学   509篇
晶体学   13篇
力学   36篇
综合类   5篇
数学   97篇
物理学   178篇
  2024年   1篇
  2023年   12篇
  2022年   12篇
  2021年   21篇
  2020年   17篇
  2019年   20篇
  2018年   10篇
  2017年   19篇
  2016年   21篇
  2015年   35篇
  2014年   32篇
  2013年   42篇
  2012年   51篇
  2011年   58篇
  2010年   45篇
  2009年   40篇
  2008年   41篇
  2007年   33篇
  2006年   35篇
  2005年   41篇
  2004年   32篇
  2003年   28篇
  2002年   17篇
  2001年   16篇
  2000年   13篇
  1999年   18篇
  1998年   11篇
  1997年   11篇
  1996年   11篇
  1995年   20篇
  1994年   12篇
  1993年   10篇
  1992年   14篇
  1991年   4篇
  1990年   6篇
  1989年   4篇
  1988年   1篇
  1987年   3篇
  1986年   3篇
  1985年   2篇
  1984年   1篇
  1983年   1篇
  1982年   3篇
  1976年   2篇
  1974年   4篇
  1973年   1篇
  1971年   1篇
  1957年   2篇
  1945年   1篇
排序方式: 共有838条查询结果,搜索用时 31 毫秒
101.
A smooth C1 interpolation for two-dimensional contact problems using paxametric curve technique was developed and implemented. The parametric curve can ensure C1 continuity of the contact surfaces and provide a unique surface normal vector. Some numerical examples were used to illustrate the advantages of the newly developed representation of contact surface. The results reveal a significant improvement in the prediction of contact stresses and contactarea. The predicted contact stresses are less sensitive to the mismatch in meshes of the different contacting bodies.  相似文献   
102.
Summary The application of capillary electrophoresis (CE) to the separation and determination of the active ingredient, 10-hydroxy-2-decenoic acid, in royal jelly with direct on-column UV detection at 214 nm is described. Using a cathodic injection and anodic detection scheme, 10-hydroxy-2-decenoic acid (10-HDA) was separated and detected in less than 10 min in a fused silica capillary column with a phosphate buffer at pH 7.3 with an applied voltage of 20 KV followed by direct UV detection. The use of cetyltrimethylammonium bromide (CTAB) as electroosmotic flow modifier allows the rapid separation of 10-HDA from other constituents in royal jelly by reversing the direction of electroosmotic flow. The influence of organic solvents in the electrolyte on separation selectivity is also discussed.  相似文献   
103.
A system for transformation and regeneration of Lycium barbarum L. , an important Chinese medical plant, has been established. Young stem segments from Lycium barbarum L. were infected with Agrobacterium tumefaciens C58cl(pGV3850: :ineo1130), and the transformed calli selected from the callus induction medium containing 50 fig/ml kanamycin could regenerate buds on differentiation medium containing 25 μg/ml kanamycin. 30% of the regenerated buds were normal in morphology. The normal buds could develop into whole plantlets after they were transferred to the rooting medium to induce roots. Nopa-line detection, NPT-Ⅱ enzyme activity assay and Southern blotting hybridization indicated that the foreign genes had been integrated into the genome of Lycium barbarum L. and expressed in the plant. In the processes of experiments, it was found that (i) after the pre-processes, the explants which formed callus quickly were easy to transform ; (Ⅱ) the rate of normal regenerated plants from transgenic calli was hig  相似文献   
104.
For pt.I, see ibid., vol.20, no.3, p.155-162 (1992). Based on an analytical study of the stability problems of gyrotron traveling wave amplifiers (gyro-TWTs), an extremely high power second-harmonic gyro-TWT has been designed, evaluated and optimized with a self-consistent nonlinear numerical simulation code. The design, which is based on the magnetron-injection-gun (MIG)-type beam, is presented. Using a 100 kV, 25 A MIG beam with α=1 and an axial velocity spread of 5%, nonlinear self-consistent analysis of a three-stage second-harmonic gyro-TWT amplifier predicts a peak output power of 533 kW, peak efficiency of 21.3% and a 7.4% saturated bandwidth, which verifies the theoretical predictions that a stable harmonic gyro-TWT can generate power levels an order of magnitude higher than those possible from a fundamental gyro-TWT. It is shown that the positioning of the electron beam is very important. A multistage structure is used to recover the loss in gain resulting from shortening the interaction sections to ensure stability  相似文献   
105.
The water-insoluble poly-beta-cyclodextrin (poly-CD)/Nafion composite film was easily prepared by casting a mixed solution of poly-CD and Nafion onto substrate plates. FT-IR measurements showed that the 50/50 wt% poly-CD/Nafion composite film remained stable on the glass and quartz substrates after immersion in water for more than 3 h, while a pure poly-CD film was almost completely dissolved by immersion within 1 h. The film stability was also evaluated from the amount of p-nitrophenol (p-NP) inclusion in the film, which was determined from the decrease in UV-vis absorbance of the p-NP solution into which the film was immersed. The composition dependence of the inclusion amount showed that the film was stable up to 50 wt% CD, but became less stable with further increase in the CD concentration in the film. From the isotherms for the inclusion of p-NP and 1-naphthoate (1-Naph) into the film, the inclusion (stability) constants were determined to be 3.7x10(3) M(-1) and 1.9x10(2) M(-1), respectively. These results show that the selective inclusion of CD is retained after preparation of the composite film.  相似文献   
106.
107.
相干性对X光全息图分辨率的影响   总被引:4,自引:4,他引:0  
朱佩平  徐至展 《光学学报》1994,14(11):166-1171
分析计算了X光束的相干性对X光全息图分辨率的影响,结论是X光无透镜傅里叶变换全息术所要求的相干长度和分辨率与样品尺雨戌二次线型关系;X光同轴全息术所要求的相干长度和分辨率的平方以及样品到全息图的距离成正比。  相似文献   
108.
基于支持向量机测定水质中硝酸盐含量   总被引:2,自引:0,他引:2  
针对水质中被测物硝酸盐与干扰物铁离子、铬离子紫外吸收谱线严重重叠的问题,将支持向量机应用于混合重叠光谱分析中,利用核函数将重叠的光谱数据进行高维空间变换后求得SVM回归模型,实现硝酸盐含量的光谱检测。实验结果表明:硝酸盐浓度在0.5—10mg/L范围内,所测得含量的最大相对误差为3.2%;平均回收率为100.9%,本法与传统的方法相比,要求条件较低,不需要物理或化学的分离,分析速度快,有望应用于在线监测污水中硝酸盐的含量。  相似文献   
109.
朱遵略  张小妞  寇素华  施德恒  孙金锋 《中国物理 B》2010,19(11):113602-113602
Interaction potentials for LiCl(X 1 Σ +) are constructed by the highly accurate valence internally contracted mul-tireference configuration interaction in combination with a number of large correlation-consistent basis sets,which are used to determine the spectroscopic parameters (D 0,D e,R e,ω e,ω e χ e,B e and α e).The potentials obtained at the basis sets,i.e.,aug-cc-pV5Z-JKFI for Cl and cc-pV5Z for Li,are selected to study the elastic collision properties of Li and Cl atoms at the impact energies from 1.0×10 12 to 1.0×10 4 a.u.The derived total elastic cross sections are very large and almost constant at ultralow temperatures,and their shapes are mainly dominated by the s-partial wave at very low impact energies.Only one shape resonance can be found in the total elastic cross sections over the present collision energy regime,which is rather strong and obviously broadened by the overlap contributions of the abundant resonances coming from various partial waves.Abundant resonances exist for the elastic partial-wave cross sections until l=22 partial waves.The vibrational manifolds of the LiCl(X 1 Σ +) molecule,which are predicted at the present level of theory and the basis sets cc-pV5Z for Li and the aug-cc-pV5Z-JKFI for Cl,should achieve much high accuracy due to the employment of the large correlation-consistent basis sets.  相似文献   
110.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号