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排序方式: 共有233条查询结果,搜索用时 31 毫秒
221.
V.K.B. Kota U. Datta Pramanik 《The European Physical Journal A - Hadrons and Nuclei》1998,3(3):243-253
The SUBFF(3) dynamical symmetry limits of interacting boson – fermion – fermion model are identified and they are appropriate for heavy
deformed odd – odd nuclei for configurations with both the odd proton and odd neutron occupying all the natural parity orbits
in the corresponding valence shells. There are three symmetry limits and their correspondence with two quasi-particle (proton-neutron)
Nilsson configurations is established; one of the limits mixes both Nilsson nz's and Λ's and other two limits mix only Nilsson Λ's. The 191Ir (d,t) 190Ir single nucleon transfer spectroscopic strengths are well described by one of the symmetry limits that mixes only Nilsson
Λ's.
Received: 22 June 1998 相似文献
222.
In this article we study an integral invariant which obstructs the existence on a compact complex manifold of a volume form with the determinant of its Ricci form proportional to itself, in particular obstructs the existence of a Kähler-Einstein metric, and has been studied since 1980s. We study this invariant from the view point of locally conformally Kähler geometry. We first see that we can define an integral invariant for coverings of compact complex manifolds with automorphic volume forms. This situation typically occurs for locally conformally Kähler manifolds. Secondly, we see that this invariant coincides with the former one. We also show that the invariant vanishes for any compact Vaisman manifold. 相似文献
223.
Ishiuchi S Sakai M Daigoku K Hashimoto K Fujii M 《The Journal of chemical physics》2007,127(23):234304
The picosecond time-resolved IR spectra of phenol/ammonia (1:3) cluster were measured by UV-IR-UV ion dip spectroscopy. The time-resolved IR spectra of the reaction products of the excited state hydrogen transfer were observed. From the different time evolution of two vibrational bands at 3180 and 3250 cm(-1), it was found that two isomers of hydrogenated ammonia radical cluster .NH(4)(NH(3))(2) coexist in the reaction products. The time evolution was also measured in the near-IR region, which corresponds to 3p-3s Rydberg transition of .NH(4)(NH(3))(2); a clear wavelength dependence was found. From the observed results, we concluded that (1) there is a memory effect of the parent cluster, which initially forms a metastable product, .NH(4)-NH(3)-NH(3), and (2) the metastable product isomerizes successively to the most stable product, NH(3)-.NH(4)-NH(3). The time constant for OH cleaving, the isomerization, and its back reaction were determined by rate-equation analysis to be 24, 6, and 9 ps, respectively. 相似文献
224.
Jupally VR Kota R Van Dornshuld E Mattern DL Tschumper GS Jiang DE Dass A 《Journal of the American Chemical Society》2011,133(50):20258-20266
A systematic study of cross-linking chemistry of the Au(25)(SR)(18) nanomolecule by dithiols of varying chain length, HS-(CH(2))(n)-SH where n = 2, 3, 4, 5, and 6, is presented here. Monothiolated Au(25) has six [RSAuSRAuSR] staple motifs on its surface, and MALDI mass spectrometry data of the ligand exchanged clusters show that propane (C3) and butane (C4) dithiols have ideal chain lengths for interstaple cross-linking and that up to six C3 or C4 dithiols can be facilely exchanged onto the cluster surface. Propanedithiol predominately exchanges with two monothiols at a time, making cross-linking bridges, while butanedithiol can exchange with either one or two monothiols at a time. The extent of cross-linking can be controlled by the Au(25)(SR)(18) to dithiol ratio, the reaction time of ligand exchange, or the addition of a hydrophobic tail to the dithiol. MALDI MS suggests that during ethane (C2) dithiol exchange, two ethanedithiols become connected by a disulfide bond; this result is supported by density functional theory (DFT) prediction of the optimal chain length for the intrastaple coupling. Both optical absorption spectroscopy and DFT computations show that the electronic structure of the Au(25) nanomolecule retains its main features after exchange of up to eight monothiol ligands. 相似文献
225.
Karginov AV Zou Y Shirvanyants D Kota P Dokholyan NV Young DD Hahn KM Deiters A 《Journal of the American Chemical Society》2011,133(3):420-423
We developed a new system for light-induced protein dimerization in living cells using a photocaged analogue of rapamycin together with an engineered rapamycin binding domain. Using focal adhesion kinase as a target, we demonstrated successful light-mediated regulation of protein interaction and localization in living cells. Modification of this approach enabled light-triggered activation of a protein kinase and initiation of kinase-induced phenotypic changes in vivo. 相似文献
226.
Fabrication of circular microfluidic channels by combining mechanical micromilling and soft lithography 总被引:2,自引:0,他引:2
The fabrication of microfluidic channels with complex three-dimensional (3D) geometries presents a major challenge to the field of microfluidics, because conventional lithography methods are mainly limited to rectangular cross-sections. In this paper, we demonstrate the use of mechanical micromachining to fabricate microfluidic channels with complex cross-sectional geometries. Micro-scale milling tools are first used to fabricate semi-circular patterns on planar metallic surfaces to create a master mold. The micromilled pattern is then transferred to polydimethylsiloxane (PDMS) through a two-step reverse molding process. Using these semi-circular PDMS channels, circular cross-sectioned microchannels are created by aligning and adhering two channels face-to-face. Straight and serpentine-shaped microchannels were fabricated, and the channel geometry and precision of the metallic master and PDMS molds were assessed through scanning electron microscopy and non-contact profilometry. Channel functionality was tested by perfusion of liquid through the channels. This work demonstrates that micromachining enabled soft lithography is capable of fabricating non-rectangular cross-section channels for microfluidic applications. We believe that this approach will be important for many fields from biomimetics and vascular engineering to microfabrication and microreactor technologies. 相似文献
227.
Kota Thirumala Prasad Kollipara Mohan Rao 《Journal of organometallic chemistry》2008,693(18):3049-3056
Reactions of the dinuclear complexes [(η6-arene)Ru(μ-Cl)Cl]2 (arene = C6H6, p-iPrC6H4Me) and [(η5-C5Me5)M(μ-Cl)Cl]2 (M = Rh, Ir) with 2-substituted-1,8-naphthyridine ligands, 2-(2-pyridyl)-1,8-naphthyridine (pyNp), 2-(2-thiazolyl)-1,8-naphthyridine (tzNp) and 2-(2-furyl)-1,8-naphthyridine (fuNp), lead to the formation of the mononuclear cationic complexes [(η6-C6H6)Ru(L)Cl]+ {L = pyNp (1); tzNp (2); fuNp (3)}, [(η6-p-iPrC6H4Me)Ru(L)Cl]+ {L = pyNp (4); tzNp (5); fuNp (6)}, [(η5-C5Me5)Rh(L)Cl]+ {L = pyNp (7); tzNp (8); fuNp (9)} and [(η5-C5Me5)Ir(L)Cl]+ {L = pyNp (10); tzNp (11); fuNp (12)}. All these complexes are isolated as chloro or hexafluorophosphate salts and characterized by IR, NMR, mass spectrometry and UV/Vis spectroscopy. The molecular structures of [1]Cl, [2]PF6, [4]PF6, [5]PF6 and [10]PF6 have been established by single crystal X-ray structure analysis. 相似文献
228.
Polepally AR Kumar VV Bhamidipati R Kota J Naveed SA Reddy KH Mamidi RN Selvakumar N Mullangi R Srinivas NR 《Biomedical chromatography : BMC》2008,22(9):960-976
The discovery of small-molecule novel chemical entities (NCEs) is often a complex play between appropriate structural requirements and optimization of the desired efficacy, safety and pharmacokinetic properties. One of the typical structural variants such as having an active carbon-carbon double bond (alpha, beta-unsaturated carbonyl group) in xenobiotics may lead to stability issues. Such functionalities are extremely reactive, paving way to nucleophilic attack by endogenously occurring and ubiquitous nucleophiles like thiols. While it is easy to make a unilateral decision to not pursue the development of xenobiotics with such functionalities, we question the wisdom of such a decision. In this report, we present in vitro methodologies with appropriate examples to illustrate the ease of assessing the reactivity of the xenobiotics containing double bonds with a known nucleophile. The protocols involve simple reaction procedures followed by measurements using standard laboratory equipments (UV spectrophotometer, HPLC and LC-MS). Our data suggests that not all xenobiotics with carbon-carbon double bonds readily form a Michael's adduct product with glutathione. Hence, the criterion for dropping discovery compounds because of alpha,beta-unsaturated double bonds needs to be reconsidered. Copyright (c) 2008 John Wiley & Sons, Ltd. 相似文献
229.
Keiji Fushimi Kota Anzai Shinji Tokuyama Yoshikazu Kiriiwa Noriyuki Matsumoto Atsushi Sekiya Daisuke Hashizume Kazuo Nagasawa Hirofumi Hirai Hirokazu Kawagishi 《Tetrahedron》2012,68(4):1262-1265
Five novel compounds (1–3, 5, and 6), and two known ones (4 and 7) were isolated from the culture broth of Agrocybe praecox. Their structures were determined by the interpretation of spectroscopic data. Compounds 1–4 inhibited hypocotyl growth of lettuce, and 1, 3, and 4 inhibited the root growth. 相似文献
230.
Iori Yamada Kota Shiba Tania Guadalupe Peaflor Galindo Motohiro Tagaya 《Molecules (Basel, Switzerland)》2022,27(18)
Theranostics (bifunction of therapeutics and diagnostics) has attracted increasing attention due to its efficiency that can reduce the physical and financial burden on patients. One of the promising materials for theranostics is calcium phosphate (CP) and it is biocompatible and can be functionalized not only with drug molecules but also with rare earth ions to show photoluminescence that is necessary for the diagnostic purpose. Such the CP-based hybrids are formed in vivo by interacting between functional groups of organic molecules and inorganic ions. It is of great importance to elucidate the interaction of CP with the photofunctional species and the drug molecules to clarify the relationship between the existing state and function. Well-designed photofunctional CPs will contribute to biomedical fields as highly-functional ormultifunctional theranostic materials at the nanoscales. In this review, we describe the hybridization between CPs and heterogeneous species, mainly focusing on europium(III) ion and methylene blue molecule as the representative photofunctional species for theranostics applications. 相似文献