Infrared active modes of cubic strontium titanate

It is shown that there are nine optically active modes of SrTiO₃ and not twelve as stated byNarayanan andVedam in a previous article in this Journal.     

Cost allocation in a bank ATM network

We consider a situation in which a group of banks consider connecting their Automated Teller Machines (ATMs) in a network, so that the banks customers may use ATMs of any bank in the network. The problem studied is that of allocating the total transaction costs arising in the network, among the participating banks. The situation is modeled as a cooperative game with transferable utility. We propose two allocations, and discuss their relation to the core and other well-known solution concepts, as well as to population monotonicity.Endre Bjørndal has enjoyed the hospitality of Tilburg University, and has also received financial support from Telenor AS and the Norwegian School of Economics and Business Administration.     

On-fiber derivatization for direct immersion solid-phase microextraction. Part II. Acylation of amphetamine with pentafluorobenzoyl chloride for urine analysis

On-fiber derivatization was used for solid-phase microextraction (SPME) in order to increase the detectability and extractability of drugs in biological samples. Amphetamine, which was used as a model compound, was derivatized with pentafluorobenzoyl chloride (PFBCl) and subjected to gas chromatography with electron capture or mass spectrometric detection. Extraction was performed by direct immersion of a 100 microm polydimethylsiloxane-coated fiber into buffered human urine. On-fiber derivatization was performed either after or simultaneously with extraction. The former procedure gave cleaner chromatograms but the latter turned out to be superior with respect to linearity and repeatability. For the on-fiber derivatization of amphetamine an excess of reagent is required. Because a considerable part of the PFBCl loaded on to the fiber is used up by reaction with matrix compounds and water, a reagent loading time of 5 min was needed to obtain a linear range (r = 0.9756) from 250 pg mL(-1) to 15 ng mL(-1). Due to an interfering matrix compound, the limit of detection was also found to be dependent on the reagent loading time, i.e., the limit of detection for a PFBCl loading time of 5 min is 250 pg mL(-1) whereas that for a 1 min loading time it is 100 pg mL(-1). The relative standard deviation (n = 7) of the method was about 11% at an amphetamine concentration of 1 ng mL(-1). The applicability of the method for the determination of drugs in biological samples is shown.     

Penetrative convection in sublayer of water including density inversion

Numerical solutions of stability and convective flow in an infinite horizontal water layer, including density inversion, have been obtained using a finite element code. The evolution of the temperature field and flow pattern near the onset of convection are studied in detail. It is known that natural convection develops primarily in the lower unstably stratified layer. Of interest is the penetration of the convection rolls into the upper stably stratified layer and concurrent liquid entrainment as a function of the increasing Rayleigh number at different aspect ratios. Individual convection rolls may grow and expand before splitting up into two roll cells. It is shown that changing the aspect ratio influences critical Rayleigh number, flow symmetry, flow pattern, and transitions between flow patterns. Numerical results on heating from above or from below, agree well with available results in the literature. A correlation to predict critical Rayleigh numbers is given for the case of heating from above.     

Transverse single spin asymmetries in polarized proton-proton collisions at PHENIX

The PHENIX experiment probes the transverse spin structure of the proton with asymmetries of particle production in polarized proton collisions. This talk summarizes the measurements of A _N in hadron production at forward and at mid rapidities.     

Scaling theory for percolative charge transport in disordered molecular semiconductors

We present a scaling theory for charge transport in disordered molecular semiconductors that extends percolation theory by including bonds with conductances close to the percolating one in the random-resistor network representing charge hopping. A general and compact expression is given for the charge mobility for Miller-Abrahams and Marcus hopping on different lattices with Gaussian energy disorder, with parameters determined from numerically exact results. The charge-concentration dependence is universal. The model-specific temperature dependence can be used to distinguish between the hopping models.     

Visualization of convective solidification in a vertical layer of Eutectic Ga-In Melt

 A vertical layer of an eutectic gallium indium mixture was subjected to a horizontal temperature gradient. The well stirred melt was first solidified and then remelted in a slow, quasi-steady fashion. Real-time visualization of the processing is provided by radioscopy. It was observed that gravitational segregation leads to 1) a break down of convection, and 2) an early solidification of β-indium, followed by an eutectic solidification of most of the remaining melt. The amount of observed concentrational segregation is higher than predicted by theory. The experimental findings have never been predicted in modeling efforts of similar situations including convection; possible reasons are discussed. Received: 13 March 1996/Accepted: 28 May 1996