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31.
A. B. Shishmakov Yu. V. Mikushina O. V. Koryakova M. S. Valova L. A. Petrov 《Russian Journal of Applied Chemistry》2012,85(10):1514-1518
The method of the synthesis of dispersed powders of silicon, titanium, and zirconium dioxides was developed, including formation of cellulose inorganic composites by impregnation of pressed granules of powdered cellulose with solutions of tetraethoxysilane and tetrabutoxy zirconium, hydrolysis of the organometallic constituent of the composite, pyrolysis of the cellulose matrix of the composite, and burning of its carbon constituent. 相似文献
32.
A. V. Pestov O. V. Koryakova I. I. Leonidov Yu. G. Yatluk 《Russian Journal of Applied Chemistry》2010,83(5):787-794
The possibility of using the thermochemical approach to thermal decomposition of solids, previously developed by the author, to interpretation of the mechanism and kinetics of reduction of metal oxides with hydrogen was studied. Many properties of NiO reduction with hydrogen, including formation of metal nuclea, the nature of induction period, autocatalysis effect, equimolar and isobaric periods of reduction, the character of the effect of hydrogen pressure on reduction rate, and the nanocrystalline structure of a reduced metal, were explained in terms of the given approach. 相似文献
33.
A. B. Shishmakov O. V. Koryakova A. S. Seleznev L. A. Petrov S. A. Melkozerov 《Russian Journal of Applied Chemistry》2013,86(2):151-155
A series of TiO2-SiO2 binary xerogels with the titanium content lower than 7 mol % were prepared by joint hydrolysis of tetrabutoxytitanium and tetraethoxysilane in a desiccator in the atmosphere of vapor over 5% aqueous NH3 solution under static conditions. The physicochemical properties of the material were examined by IR spectroscopy and by the kinetic method with hydrogen peroxide decomposition as model reaction. 相似文献
34.
Mel'nichenko E. I. Koryakova M. D. Nikitin V. M. Krysenko G. F. Speshneva N. V. 《Russian Journal of Applied Chemistry》2001,74(1):77-81
IR spectroscopy and X-ray phase and chemical analyses were used to study the physicochemical properties of fluoride-containing amorphous silicon dioxide obtained by hydrolysis of (NH4)2SiF6, and its previously unknown biocide properties were discovered. Results of biotesting are presented. 相似文献
35.
Pasechnik L. A. Shirokova A. G. Koryakova O. V. Sabirzyanov N. A. Yatsenko S. P. 《Russian Journal of Applied Chemistry》2004,77(7):1070-1073
The behavior of scandium compounds in going from alkaline solutions to carbonate and hydrocarbonate solutions was studied. The possibility of coprecipitation of scandium(III) complex carbonate with zinc oxide was examined. 相似文献
36.
V. N. Krasil’nikov O. I. Gyrdasova I. V. Baklanova L. Yu. Buldakova M. Yu. Yanchenko R. F. Samigullina O. V. Koryakova 《Russian Journal of Inorganic Chemistry》2013,58(2):120-126
Quasi-one-dimensional (1D) solid solutions Ti1 ? x Fe x (OCH2CH2O)2 ? x/2 (0 < x ≤ 0.1) with the structure of anatase were prepared by heating the glycolate Ti1 ? x Fe x (OCH2CH2O)2 ? x/2 in an atmosphere of air at a temperature of >450°C. The conditions of formation and the properties of the new glycolate Ti3Fe2(OCH2CH2O)9 were described. It was found that the synthesized Ti1 ? x Fe x O2 ? 2x/2 solid solutions exhibit photocatalytic activity in the reaction of hydroquinone oxidation in an aqueous solution on irradiation with UV light. A correlation between the rate of oxidation of hydroquinone and the concentration of iron in the catalyst was established. A procedure for the preparation of titanium dioxide with the structure of anatase doped with iron and carbon (Ti1 ? x Fe x O(2 ? x/2) ? yCy) and also composites on its basis, which contain an excess amount of carbon, was proposed. 相似文献
37.
A. B. Shishmakov Yu. V. Mikushina M. S. Valova O. V. Koryakova L. A. Petrov 《Russian Journal of Applied Chemistry》2007,80(12):2107-2110
A procedure was developed for modification of titanium dioxide xerogel by addition of powder cellulose in the stage preceding hydrolysis of tetramethoxytitanium. The resulting catalytic systems based on the new material were studied in a model liquid-phase catalytic process of oxidative dehydrogenation of trimethylhydroquinone with atmospheric oxygen. 相似文献
38.
O. V. Fedorova O. V. Koryakova M. S. Valova I. G. Ovchinnikova Yu. A. Titova G. L. Rusinov V. N. Charushin 《Kinetics and Catalysis》2010,51(4):566-572
The effect of nanosized copper and aluminum oxides, which have a higher sorption capacity than that of bulk samples, on the
Hantzsch reaction was studied. The adsorption of starting benzaldehydes and ethyl acetoacetate on the surface of copper and
aluminum nanooxides resulted in the activation of these molecules and accelerated the Hantzsch reaction. In addition, considerable
activation of ammonia and intermediates (chalcone and enamine) on the surface of aluminum nanooxide facilitated an increase
in the rate and selectivity of the process. The experimental results were used to develop a one-pot method for the preparation
of nifedipine and nitrendipine. 相似文献
39.
40.
A. B. Shishmakov L. S. Molochnikov D. O. Antonov Yu. V. Mikushina O. V. Koryakova L. A. Petrov 《Russian Journal of Inorganic Chemistry》2016,61(9):1085-1091
ZrO2–SiO2 xerogels have been synthesized through hydrolysis of a mixture of tetrabutoxyzirconium and tetraethoxysilane in a desiccator in a vapor of a 15% aqueous NH3 atmosphere. ZrO2–SiO2–Cu(II) xerogels were synthethized analogously through joint hydrolysis of a mixture of the organometallic precursors and copper(II) chloride. The effect of synthesis conditions on the physical and chemical properties of the resulting material has been studied. 相似文献