全文获取类型
收费全文 | 164篇 |
免费 | 0篇 |
专业分类
化学 | 96篇 |
力学 | 4篇 |
数学 | 3篇 |
物理学 | 61篇 |
出版年
2022年 | 2篇 |
2021年 | 1篇 |
2020年 | 3篇 |
2019年 | 2篇 |
2018年 | 9篇 |
2017年 | 6篇 |
2016年 | 8篇 |
2015年 | 2篇 |
2014年 | 3篇 |
2013年 | 7篇 |
2012年 | 6篇 |
2011年 | 9篇 |
2010年 | 6篇 |
2009年 | 2篇 |
2008年 | 10篇 |
2007年 | 2篇 |
2006年 | 5篇 |
2005年 | 9篇 |
2004年 | 7篇 |
2003年 | 8篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 4篇 |
1996年 | 4篇 |
1994年 | 1篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1979年 | 4篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有164条查询结果,搜索用时 15 毫秒
141.
A. T. Teleshev M. P. Koroteev O. P. Kronova G. V. Malysheva G. Z. Kaziev E. E. Nifantiev 《Polymer Science Series D》2012,5(3):219-220
Wood residue crumbling with a rotary-pulse device is considered. Structural analysis of the resulting materials is carried out. 相似文献
142.
Pavel S. Koroteev Andrey B. Ilyukhin Andrey V. Gavrikov Konstantin A. Babeshkin Nikolay N. Efimov 《Molecules (Basel, Switzerland)》2022,27(3)
Novel mononuclear cymantrenecarboxylate complexes of transition metals, [Co(H2O)6](CymCO2)2·4H2O (Cym = (η5-C5H4)Mn(CO)3) (1), [Ni(H2O)6](CymCO2)2·4H2O (2), [Zn(H2O)6](CymCO2)2·4H2O (3), [Co(CymCO2)2(imz)2] (imz = imidazole, 4), [Co(CymCO2)2(bpy)2]·2PhMe (bpy = 2,2′-bipyridyl, 5), [Ni(CymCO2)(bpy)2(H2O)][CymCO2]·0.5MePh·2H2O (6), [Cu(CymCO2)2(imz)2] (7), and [Cu(CymCO2)2(bpy)(H2O)] (8), were obtained and characterized by single-crystal X-ray analysis. Complexes 1–3 are isostructural. Magnetism of the Co complexes 1, 4, and 5 was studied; it was shown that they exhibit the properties of field-induced single-molecule magnets with magnetization reversal barriers (ΔE/kB) of 44, 13, and 10 K, respectively. Thermal decomposition of complexes 1–8 was studied by means of DSC and TGA methods. The final products of thermolysis of 1–6 in air, according to powder XRD data, are the pure spinel phases MMn2O4; for the cases of copper complexes, the mixtures of CuMn2O4 and CuO were found in the products. 相似文献
143.
A. M. Zheltikov N. I. Koroteev A. N. Naumov 《Journal of Experimental and Theoretical Physics》1999,88(5):857-867
The influence of self-and cross-phase modulation on third-harmonic generation in a hollow waveguide is investigated. Analytic
solutions of the coupled equations for the slowly varying amplitudes of the pump pulse and the third harmonic in a gas-filled
hollow waveguide are obtained with consideration of self-and cross-phase modulation and first-order dispersion effects. The
possibility of controlling the nonlinear phase trajectory of the third harmonic by cross-phase modulation is demonstrated.
Zh. éksp. Teor. Fiz. 115, 1561–1579 (May 1999) 相似文献
144.
T. V. Dudakova M. P. Koroteev K. A. Lyssenko M. Yu. Antipin E. E. Nifant’ev 《Russian Chemical Bulletin》2004,53(12):2810-2815
The reactions of 3-hydroxy- and 5,7-dihydroxyflavones with hexaethylphosphorous triamide proceed according to a classical scheme, but the reaction of 5,7-dihydroxyflavone occurs regioselectively. Dismutation of phosphites, which has been studied earlier only for the simplest aryl systems, is extended to flavonoids.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2698–2702, December, 2004. 相似文献
145.
I. Oreshkin V. I. Panov S. I. Vasil’ev N. I. Koroteev S. A. Magnitskii 《JETP Letters》1998,68(6):521-526
Light-induced conformational transformations of the naphthacenequinone (NQ) molecules are observed by scanning tunneling microscopy
(STM). NQ molecules packed in a Langmuir-Blodgett (LB) film are shown to form stable ordered structures on a surface of highly
oriented pyrolytic graphite (HOPG). The local density of electronic states is found to exhibit the distinct peak which is
characteristic of two-dimensional conductivity. An additional subband of empty electronic states is found for NQ molecules
in form A but not in form B. The constant-height STM images of individual molecules in form A demonstrate an additional structure that is indicative of a conformational transition of the NQ molecules. This transition
involves the transfer of the phenoxy group from one oxygen to another.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 6, 486–490 (25 September 1998) 相似文献
146.
S. Holguin Quinones G. Z. Kaziev A. de Ita A. M. Koroteev V. E. Zavodnik O. A. Kutanova 《Russian Journal of Coordination Chemistry》2007,33(9):648-652
Acid ammonium metaphenyleneamine dodecatungstenphosphate of the composition (C6H4(NH2)(NH3))2H[PW12O40] · 8H2O is synthesized and studied by mass spectrometry, X-ray diffraction, IR spectroscopy, and thermogravimetry. The crystals
are rhombic, space group Pnma, a = 18.421(2), b = 19.569(3), c = 13.443(3) ?, Z = 4, ρ(calc) = 4.431 g/cm3, V = 4845.9(2) ?3.
Original Russian Text ? S. Holguin Quinones, G.Z. Kaziev, A. de Ita, A.M. Koroteev, V.E. Zavodnik, O.A. Kutanova, 2007, published
in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 9, pp. 660–664. 相似文献
147.
Routes for the reaction of a conjugated methylene group of nitroxyl radicals (NR) with secondary amines were suggested and analyzed. Kinetic parameters of the limiting step of this reaction for the NR-amine and diamagnetic analog of NR-amine systems were estimated. The effect of the medium on these reactions was examined. The specific behavior of polyethyleneimine in the reaction with activated methylene groups of 2,2,6,6-tetra methyl-3, 5-dimethylene-4-oxopiperidine-i-oxyl was demonstrated.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 842–849, April, 1996. 相似文献
148.
Dobrokhotova Zh. V. Koroteev P. S. Saushev A. V. Aleksandrov G. G. Novotortsev V. M. Nefedov S. E. Egorov M. P. 《Russian Chemical Bulletin》2003,52(8):1681-1687
Thermal decomposition of the complexes (acac)2Ge(N3)2 (1), (acac)2GeCl2 (2), and (CO)5M=GeCl2(THF) (M = Cr (3), Mo (4), W (5)) was studied by differential scanning calorimetry and thermogravimetry. The phase compositions of the products of thermolysis of compounds 1—3 and 5 were determined by X-ray phase analysis. Possible schemes of thermal decomposition of these compounds were proposed. The heat capacities of complexes 3—5 were studied in the temperature range 113—313 K. The structures of complexes 1 and 5 were established by X-ray diffraction analysis. 相似文献
149.
Koroteev A. M. Krasnov G. B. Koroteev M. P. Nifant’ev E. E. Kulesheva L. N. Antipin M. Yu. Korlyukov A. A. 《Russian Journal of Organic Chemistry》2004,40(4):474-478
Conditions were found for selective hydrolysis of bicyclic phosphites derived from 2,2-bis-(hydroxymethyl)-1-propanol and 2,2-bis(hydroxymethyl)-1-butanol to the corresponding dihydrogen phosphites. The latter were isolated as potassium, sodium, and ammonium salts and were characterized by the 1H, 13C, and 31P NMR spectra. The structure of the ammonium salt was proved by X-ray analysis. 相似文献
150.
The values of isotropic HFS constantsa
N were obtained for nitroxyl radicals (NR) of the piperidine series in hexane and water. The interrelation between rate constants for NR reduction and oxidation reactions, isotropic HFS constantsa
N, inductive constants of the piperidine substituents, and electrochemical characteristics of NR were found. The dependence of the rate constants for the reduction of NR by hydrazobenzene (HB) and its oxidation by tetranitromethane (TNM) upon the Hammett type inductive constants
EPR, obtained using HFS constantsa
N as the basis, was analyzed. The solvent effect on the reduction and oxidation reaction rate constants, the kinetic isotopic effect of the reduction reaction for a number of NR-HB systems, and alternative reaction mechanisms are considered.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1074–1079, June, 1993. 相似文献