Mononuclear Transition Metal Cymantrenecarboxylates as Precursors for Spinel-Type Manganites

Novel mononuclear cymantrenecarboxylate complexes of transition metals, [Co(H₂O)₆](CymCO₂)₂·4H₂O (Cym = (η⁵-C₅H₄)Mn(CO)₃) (1), [Ni(H₂O)₆](CymCO₂)₂·4H₂O (2), [Zn(H₂O)₆](CymCO₂)₂·4H₂O (3), [Co(CymCO₂)₂(imz)₂] (imz = imidazole, 4), [Co(CymCO₂)₂(bpy)₂]·2PhMe (bpy = 2,2′-bipyridyl, 5), [Ni(CymCO₂)(bpy)₂(H₂O)][CymCO₂]·0.5MePh·2H₂O (6), [Cu(CymCO₂)₂(imz)₂] (7), and [Cu(CymCO₂)₂(bpy)(H₂O)] (8), were obtained and characterized by single-crystal X-ray analysis. Complexes 1–3 are isostructural. Magnetism of the Co complexes 1, 4, and 5 was studied; it was shown that they exhibit the properties of field-induced single-molecule magnets with magnetization reversal barriers (ΔE/k_B) of 44, 13, and 10 K, respectively. Thermal decomposition of complexes 1–8 was studied by means of DSC and TGA methods. The final products of thermolysis of 1–6 in air, according to powder XRD data, are the pure spinel phases MMn₂O₄; for the cases of copper complexes, the mixtures of CuMn₂O₄ and CuO were found in the products.     

Self-and cross-phase modulation accompanying third-harmonic generation in a hollow waveguide

The influence of self-and cross-phase modulation on third-harmonic generation in a hollow waveguide is investigated. Analytic solutions of the coupled equations for the slowly varying amplitudes of the pump pulse and the third harmonic in a gas-filled hollow waveguide are obtained with consideration of self-and cross-phase modulation and first-order dispersion effects. The possibility of controlling the nonlinear phase trajectory of the third harmonic by cross-phase modulation is demonstrated. Zh. éksp. Teor. Fiz. 115, 1561–1579 (May 1999)     

Sedimentation of particles in shear flows of viscoelastic fluids

An experimental investigation of sedimentation of single particles and concentrated suspensions in Couette flows of viscous and viscoelastic fluids is presented. With the passage from viscous to viscoelastic fluids, a slowing down of the sedimentation was observed. The sedimentation of suspensions in viscoelastic fluids accelerated with increase in the suspension concentration. The development of instabilities during the sedimentation was detected.     

Dicationic disiloxane ionic liquids as heat transfer agents in vacuo

Russian Chemical Bulletin - Bis(trifluoromethylsulfonyl)imidic dicationic liquids containing a disiloxane linker between the imidazole cations have been synthesized. Their thermal stability was...     

Plane steady-state incompressible fluid flow through a porous medium with a nonlinear resistance laws in the presence of a sink

Plane nonlinear fluid flows through a porous medium which simulate a sink located at the same distance from the roof and floor of the stratum for two nonlinear flow laws are constructed. The following flow laws are taken: a power law and a law of special form reducing to analytic functions in the hodograph plane.     

Heterometallic Carboxylate Complexes as Precursors for Mixed Oxides: II. d–d Carboxylates

Russian Journal of General Chemistry - The current status of research into the thermal behavior of heterometallic d–d carboxylates that are suitable candidates for single-source precursors of...     

Catechol in acylation,phosphorylation, and aminomethylation reactions

The reactivity of dihydroquercetin and catechol flavonoids in acylation, phosphorylation, and aminomethylation reactions was compared. The structure of natural polyatomic phenols was shown to affect markedly their chemical behavior.