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AA Yan LI Kai CAO ZhongHua & HU WenRui Key Laboratory of Microgravity 《中国科学:物理学 力学 天文学(英文版)》2011,(2)
The dependency of the critical Marangoni number on the geometrical aspect ratio of the floating half zone is essential to predict the onset of oscillatory thermocapillary convection.The experimental studies in the microgravity conditions on floating half zones of several centimeters in diameter have predicted that the critical Marangoni number increases with the increasing aspect ratio,and the terrestrial experimental studies have predicted the contradictory conclusion for floating half zones of several mil... 相似文献
13.
Non-Gravitational Effects with Density-Matching in Evaluating the Influence of Sedimentation on Colloidal Coagulation
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The method of density matching between the solid and liquid phases is often adopted to effectively eliminate the effect of sedimentation of suspensions in studies on dynamic behaviour of a colloidal system. However, the associated changes in the solvent composition may bring side effects to the properties investigated and therefore might lead to a faulty conclusion if the relevant correction is not made. To illustrate the importance of this side effect, we present an example of the sedimentation influence on the coagulation rate of suspensions of 2μm (diameter) polystyrene. The liquid mixtures, in the proper proportions of water (H2O), deuterium oxide (D2O) and methanol (MeOH) as the liquid phase, density-matched and unmatched experiments are performed. Besides the influence of viscosity, the presence of methanol in solvent media, used to enhance the sedimentation effect, causes significant changes (reduction) in rapid coagulation rates compared to that in pure water. Without the relevant corrections for those non-gravitational factors it seems that gravitational sedimentation would retard the coagulation. The magnitude of the contribution from the non-gravitational factor is quantitatively determined, making the relevant correction possible. After necessary the influence of the sedimentation on coagulation rates at corrections for all factors, our experiments show that the initial stage of the coagulation is not observable. 相似文献
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A. V. Polukeev S. A. Kuklin P. V. Petrovskii A. S. Peregudov F. M. Dolgushin M. G. Ezernitskaya A. A. Koridze 《Russian Chemical Bulletin》2010,59(4):745-749
Iridium pincer complexes [C6H3-2,6-(OPBut
2)2]Ir(H)Cl (10) and [4-EtOOCC6H2-2,6-(OPBut
2)2]Ir(H)Cl (11) react with protic acids undergoing metallation of one of the tert-butyl groups to form double cyclometallated products [4-R-C6H2-2-(OPBut
2)-6-(OP(But)CMe2CH2)]IrCl (12, R = H; 13, R = COOEt), which are stable in air. Complex 12 reacts with CO and ButNC giving the corresponding 18-electron complexes [C6H3-2-(OP-But
2)-6-(OP(But)CMe2CH2)]Ir(L)Cl (14, L = CO; 15, L = CNBut). The structure of compound 14 was established by X-ray diffraction analysis. 相似文献
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S. A. Kuklin F. M. Dolgushin P. V. Petrovskii A. A. Koridze 《Russian Chemical Bulletin》2006,55(11):1950-1955
First ruthenocene-based palladium complexes PdCl[{2,5-(But
2PCH2)2C5H2} Ru(Cp′)] (Cp′ = C5H5 (4) or C5Me5 (5)) were synthesized. Comparative single-crystal X-ray diffraction study of complexes 4 and 5 showed that the deviations of the cyclopentadienyl rings in these complexes from being parallel are 2.6 and 10.1°, respectively.
In addition, the shift of the palladium atom relative to the plane of the metallated cyclopentadienyl ligand is 0.007 Å for
4 and 0.336 Å for 5. These differences in the structures of complexes 4 and 5 are due to close contacts between the pseudoequatorial tert-butyl groups at the phosphorus atoms and the unmetallated cyclopentadienyl ring.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1879–1884, November, 2006. 相似文献
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We discuss the notion of spin squeezing considering two mutually exclusive classes of spin-s states, namely, oriented and non-oriented states. Our analysis shows that the oriented states are not squeezed while non-oriented
states exhibit squeezing. We also present a new scheme for construction of spin-s states using 2s spinors oriented along different axes. Taking the case of s=1, we show that the ‘non-oriented’ nature and hence squeezing arise from the intrinsic quantum correlations that exist among
the spinors in the coupled state. 相似文献
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