正交优化红枣多糖的超声波提取工艺

建立了UV-Vis分光光度测定红枣中多糖含量的方法.考察了乙醇体积、超声温度、超声时间、料液比4因素对多糖含量测定的影响.在单因素试验结果的基础上,进行正交试验设计,试验结果表明:最佳测定条件为A2B2C3D2,即超声温度为50℃,超声时间为60min,料液比为1∶30(g/mL),乙醇用量为30mL.方法平均回收率为96.87％,RSD为1.11％(n=5).该法快速、灵敏、准确,可用于红枣多糖的提取及含量测定.     

An Interconnect Bus Power Optimization Method

A simple yet accurate interconnect parasitical capacitance model is presented. Based on this model a novel interconnect bus optimization methodology is proposed. Combining wire spacing with wire ordering, this methodology focuses on bus dynamic power optimization with consideration of bus performance requirements. The optimization methodology is verified under a 65 nm technology node and it shows that with 50% slack in the routing space, a 33.039% power saving can be provided by the proposed optimization methodology for an intermediate video bus compared to the 27.68% power saving provided by uniform spacing technology. The proposed methodology is especially suitable for computer-aided design of nanometer scale on-chip buses.     

颗粒圆孔射流碰撞并行直接数值模拟算法研究

本文对空间模式发展的颗粒圆孔射流碰撞进行了并行直接数值模拟算法研究。气相采用可压缩的N-S方程直接求解。颗粒相采用Lagrangian方法跟踪实际的颗粒运动。利用并行求解算法,实现了颗粒穿越边界面的模拟以及高效颗粒碰撞算法。考虑了颗粒和流体的双相耦合以及颗粒之间的碰撞。在本文的计算条件下,颗粒的直径远小于网格的间距,平均的Kolmogorov尺度和网格的间距在一个量级。气相和颗粒相的应力与实验的对比研究表明,本文的颗粒并行程序是可信的。     

红外焦平面探测器制冷组件可靠性研究进展

红外焦平面探测器制冷组件的可靠性研究对推进组件工程化应用具有重要意义。介绍了国外在组件的可靠性模型、失效模式、加速应力以及可靠性试验等方面的研究进展,并对国内的组件可靠性研究状况作了简要分析,总结了对组件可靠性研究的总体思路,为国内红外焦平面探测器制冷组件的可靠性研究提供参考。     

Study of conditions of the formation of multidimensional spectroscopic fluorescence images of motor fuels and liquid mineral technical oils

Conditions and specific features of the use of fluorescence spectra for the formation of multidimensional spectroscopic images of liquid mineral technical oils and petrols are studied. Possibilities of the identification of corresponding samples by the method of pattern recognition using multifactor statistical processing of multidimensional analytical signals on the basis of principal component analysis are considered. The optimum conditions of the formation of spectroscopic fluorescence images are found.     

MODELLING OF RELEASE OF GAS FROM HIGH-PRESSURE PIPELINES

The problem investigated is the break of a high-pressure pipeline carrying natural single-phase gas which may condensate (retrograde) when the pressure drops. Single-phase non-ideal gas is assumed using a general- ized equation of state. Taking advantage of the choked massflow condition, the break is split into a pipe flow problem and a dispersion flow problem, both solved using a finite difference control volume scheme. The transient flow field from the pipeline break location is expanded analytically, using an approximation of the governing equations, until ambient pressure is reached and matched to the corresponding gas dispersion flow field using as subgrid model a jet box with a time-varying equivalent nozzle area as an internal boundary of the dispersion domain. The turbulence models used for the pipe and dispersion flow fields are an empirical model of Reichard and the k–ϵ model for buoyant flow respectively. The pipe flow simulations indicate that the flow from the pipeline might include dispersed condensate which will affect quantitatively the mass flow rate from the pipeline and qualitatively the gas dispersion if the condensate rains out. The transient dispersion simulation shows that an entrainment flow field develops and mixes supersaturated gas with ambient warmer air to an unsaturated mixture. Because of the inertia of the ambient air, it takes time to develop the entrainment flow field. As a consequence of this and the decay of the mass flow with time, the lower flammability limit of the gas–air mixture reaches its most remote downstream position relatively early in the simulation (about 15 s) and withdraws closer to the break location.     

Some unexpected proportionalities between components of the spin—other-orbit interaction in the f shell

The reduced matrix elements of the component z _i of the inter-electronic spin-other-orbit interaction have been calculated for all the states of the atomic f shell. Three of the z _i , each of which belongs to the irreducible representation (30) of Racah's group G₂, are found to exhibit matrix elements that are often related to one another in ways that go beyond what the Wigner-Eckart theorem, generalized to G₂, would predict. Examples are presented for matrix elements whose bras belong to the IR (20) of G₂ and whose kets belong to (31). The challenges to current theory are discussed.     

Chemical oxidative polymerization of aminodiphenylamines

The course of oxidation of 4-aminodiphenylamine with ammonium peroxydisulfate in an acidic aqueous ethanol solution as well as the properties of the oxidation products were compared with those of 2-aminodiphenylamine. Semiconducting oligomers of 4-aminodiphenylamine and nonconducting oligomers of 2-aminodiphenylamine of weight-average molecular weights 3700 and 1900, respectively, were prepared by using an oxidant to monomer molar ratio of 1.25. When this ratio was changed from 0.5 to 2.5, the highest conductivity of oxidation products of 4-aminodiphenylamine, 2.5 x 10 (-4) S cm (-1), was reached at the molar ratio [oxidant]/[monomer] = 1.5. The mechanism of the oxidative polymerization of aminodiphenylamines has been theoretically studied by the AM1 and MNDO-PM3 semiempirical quantum chemical methods combined with the MM2 molecular mechanics force-field method and conductor-like screening model of solvation. Molecular orbital calculations revealed the prevalence of N prim-C10 coupling reaction of 4-aminodiphenylamine, while N prim-C5 is the main coupling mode between 2-aminodiphenylamine units. FTIR and Raman spectroscopic studies confirm the prevalent formation of linear N prim-C10 coupled oligomers of 4-aminodiphenylamine and suggest branching and formation of phenazine structural units in the oligomers of 2-aminodiphenylamine. The results are discussed with respect to the oxidation of aniline with ammonium peroxydisulfate, leading to polyaniline, in which 4-aminodiphenylamine is the major dimer and 2-aminodiphenylamine is the most important dimeric intermediate byproduct.     

Evolution of polyaniline nanotubes: the oxidation of aniline in water

The course of aniline oxidation with ammonium peroxydisulfate in aqueous solutions has been investigated. The reaction was terminated at various times and the intermediates collected. Besides the precipitates, the films deposited in situ on silicon windows have also been studied. The kinetic course of polymerization is controlled by the acidity level, which changes during the polymerization from pH 8 to a final value close to pH 1. It has two distinct exothermic phases. Gel-permeation chromatography indicates that aniline oligomers are produced at first at high pH, while polyaniline follows after the pH becomes sufficiently low. The growth of polyaniline nanotubes was observed by optical microscopy and confirmed by electron microscopy. The molecular structure of the reaction intermediates was studied in detail by FTIR spectroscopy. Oxidation products are markedly sulfonated, and they contain phenazine units. Aniline oligomers are more soluble in chloroform than the polymer fraction, which contains nanotubes.