Photon counting with a loop detector

We propose a design for a photon-counting detector that is capable of resolving multiphoton events. The basic element of the setup is a fiber loop, which traps the input field with the help of a fast electro-optic switch. A single weakly coupled avalanche photodiode is used to detect small portions of the signal field extracted from the loop. We analyze the response of the loop detector to an arbitrary input field and discuss both the reconstruction of the photon-number distribution of an unknown field from the count statistics measured in the setup and the application of the detector in conditional-state preparation.     

Coupled LC-GC: The capacity of silica gel (HP)LC columns for retaining fat

Many applications of coupled LC-GC in food analysis require that LC separates large quantities of triglycerides from the components of interest. The capacities of silica gels to retain triglycerides have been determined for n-hexane as mobile phase as well as some eluent mixtures. Conclusions are drawn for practical applications.     

On-line solvent evaporator for coupled LC systems

The mobile phase of a fraction eluted from a first LC column is removed by an on-line evaporator in order to reconcentrate the solute material or to exchange the eluent before performing a subsequent LC separation. Evaporation essentially occurs by concurrent evaporation, i.e. the solvent evaporates at a rate equal to the flow rate of the incoming eluent, and is driven by the overflow principle, i.e. vapors leave the tube as a result of the expansion resulting from evaporation. The liquid is introduced into a small tube (e.g., 4 cm × 1.3 mm i.d.) which is packed, e.g., with a coarse silica gel. The outlet of the evaporator is connected to vacuum in order to enable evaporation at reduced temperature and to increase retention of the volatile components. With normal phase eluents, evaporation rates may approach 1 ml/min; n-dodecane was the most volatile n-alkane fully retained by the evaporator.     

A Facile Conversion of Tertiary Amines into [2-(dialkylamino)vinyl]triphenylphosphonium salts

Halogenation of Et₃N, (i-Pr)₂EtN, and N-ethylmorpholine or of enamines with dichlorotriphenylphosphorane gives in up to 75% yield the corresponding [2-(dialkylamino)vinyl]triphenylphosphonium chlorides, which can be readily converted into the corresponding stable crystalline tetraphenylborates (Schemes 2 and 3).