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991.
A comb-like polymer containing crystallized alkyl side chains and the intermolecular hydrogen bonds between the linking groups was fabricated by grafting long-chain fatty amine onto poly(styrene-co-acrylic acid)n (P(S-AA)n, wherein “n” denoted AA feed ratio). The chemical structures and crystallization behaviors of the comb-like polymer P(S-AA)n-g(p) (wherein “p” denoted the number of side-chain carbon atoms) were analyzed by Fourier transform infrared, gel permeation chromatography, X-ray photoelectron spectroscopy, and X-ray diffractometer, differential scanning calorimetry, atomic force microscopy, respectively. It was found that the lamellar morphology could be generated by controlling the grafting density and side chain length of P(S-AA)n-g(p). Moreover, it was identified that the hydrogen bonds between amide groups could enhance the crystallinity and then adjust the interlamellar spacing of lamellar phase. As a result, P(S-AA)70-g(18) with the highest degree of crystallinity and closely packed lamellar morphology showed a good gas-barrier performance, and the nitrogen permeability reached 1.78 × 10?14 cm3·cm/cm2·s·Pa. Furthermore, the permeation switch of the obtained comb-like polymer could reach 500 times traversing the melting point. 相似文献
992.
993.
994.
采用基于纳米示踪的平面激光散射技术(NPLS)对带超声速喷流的后台阶流动精细结构进行了研究. 来流马赫数为3.4, 喷流实测马赫数为2.45, 而名义马赫数为2.5. 结果清晰地揭示了激波、剪切层、混合层、Kelvin-Helmholtz涡、羊角涡及湍流大尺度结构等大量典型流场结构. 基于大量流场精细结构图像, 对典型位置处的结构进行了空间两点相关性分析, 在喷流混合层前端涡结构小于湍流充分发展的尾端, 结构角相对也小. 喷流工作时, 模型台阶下游表面由一薄层气膜覆盖. 获得了模型流向和不同高度展向平面内的流场结构, 对照纹影试验结果, 分析了流动特点及时间演化规律. 采用微型压力扫描系统测试了模型表面的压力系数分布, 靠近喷流下游处压力系数区域0.0146. 针对NPLS图像做了流动的分形维数的分析, 发现在流动初始阶段分形维数接近于1, 越靠下游分形维数越高. 相似文献
995.
Effects of pressure and/or magnetism on the critical superconducting temperature(Tc)ofδ-Mo N single crystal were investigated using a Maglab system.Theδ-Mo N single crystal was synthesized at extreme conditions of high pressure and high temperature.The carrier density ofδ-Mo N single crystal as a function of applied pressure was determined using Hall coefficient measurement. 相似文献
996.
First-principles study of structure and nonlinear optical properties of CdHg(SCN)4 crystal 下载免费PDF全文
Zhang Peng Kong Chui-Gang Zheng Chao Wang Xin-Qiang Ma Yue Feng Jin-Bo Jiao Yu-Qiu Lu Gui-Wu 《中国物理 B》2015,24(2):24221-024221
The geometric structure,electronic structure,and optical properties of CdHg(SCN)4 crystal are calculated by using the density functional perturbation theory and Green function screening Coulomb interaction approximation.The band gap of CdHg(SCN)4 crystal is calculated to be 3.198 eV,which is in good agreement with the experimental value 3.265 eV.The calculated second-order nonlinear optical coefficients are d_(14) = 1.2906 pm/V and d_(15) = 5.0928 pm/V,which are in agreement with the experimental results(d_(14)=(1.4 ±0.6) pm/V and d_(15)=(6.0 ±0.9) pm/V).Moreover,it is found that the contribution to the valence band mainly comes from Cd-4d,Hg-5d states,and the contributions to the valence band top and the conduction band bottom predominantly come from C-2p,N-2p,and S-3p states.The second-order nonlinear optical effect of CdHg(SCN)_4 crystal results mainly from the internal electronic transition of(SCN)~-. 相似文献
997.
SQUID gradiometer techniques are widely used in noise cancellation for biomagnetic measurements.An appropriate gradiometer baseline is very important for the biomagnetic detection with high performance.By placing several magnetometers at different heights along the vertical direction,we could simultaneously obtain the synthetic gradiometers with different baselines.By using the traditional signal-to-noise ratio(SNR) as a performance index,we successfully obtain an optimal baseline for the magnetocardiography(MCG) measurement in a magnetically shielded room(MSR).Finally,we obtain an optimal baseline of 7 cm and use it for the practical MCG measurement in our MSR.The SNR about 38 dB is obtained in the recorded MCG signal. 相似文献
998.
利用团簇模型研究了二氧化碳对质子化甲醇的溶剂化作用.H+(CH3OH)(CO2)n+(n=1~7)的量子化学计算结果表明,需要3个或4个二氧化碳分子完成甲醇的羟基第一溶剂层.除了氢键,二氧化碳分子间的相互作用对大团簇的稳定性也起到了重要的作用.在这些溶剂化作用的早期阶段,不容易发生质子从甲醇到二氧化碳的转移过程.模拟的红外光谱揭示了自由O-H伸缩振动、氢键作用后的O-H伸缩振动、以及二氧化碳的O-C-O伸缩振动频率是研究质子化甲醇溶剂化过程的灵敏探针. 相似文献
999.
通过水热法制备碳微球、共沉淀法制备空心Zn Fe2O4和原位聚合法制备Zn Fe2O4/Si O2/PANI复合物,并表征其结构、形貌、组成和性质.结果表明,Si O2对铁氧体的包覆能提高二元复合物对染料废水的降解性能;铁氧体与二氧化硅物质的量比(nZn Fe2O4/nSi O2)为1:3的Zn Fe2O4/Si O2复合物对染料废水具有较好的降解作用;Zn Fe2O4/Si O2/PANI复合物对染料废水的光催化降解活性随苯胺质量分数(wAn)的增加而增大,当wAn为50%时,Zn Fe2O4/Si O2/PANI复合物对染料废水去除率高达98%.样品因具有磁性而回收方便,重复使用性能良好. 相似文献
1000.
At increasing external load, numerous microcracks propagate in discrete and successive stages within a body of concrete material according to the hierarchy of their tensile fracture strengths. Each microcrack propagation is conditional upon the statistical encounter of its associated fracture criterion. This paper shows the development of a statistical model for the progressive microcrack growth process within a body of concrete material at monotonic uniaxial loading in compression to ultimate failure. This model is formulated by using the Weibull's statistical theory of the strength of materials. The body of heterogeneous concrete material is simulated as a continuum comprising a large population of microscopic “weakest-link” isoenergy elements, each of which contains a unit-volume of representative micro-structural material which is linearly elastic, homogeneous and isotropic. The statistical modelling is derived from the stochastic evaluation of the tensile micro-fracture probabilities of these isoenergy elements at increasing global uniaxial compressive strains. 相似文献