A new structure of water layer on Cu(111) electrode surface during hydrogen evolution

A layered structure of water molecules formed on a Cu(111) electrode surface during hydrogen evolution in sulfuric acid solution was studied by surface X-ray diffraction and infrared reflection absorption methods. Water molecules in the surface layers take a closest pack-like stacking structure with nearest-neighbor oxygen-oxygen distances in intra-(0.322(5) nm) and inter-(0.275(15) nm) layers of multi-domains; the infrared spectra of the layered water on the Cu electrode surface showed the existence of free OH(OD) and hydrogen-bonded OH(OD) of water molecule.     

The exact decomposition of gauge variables in lattice Yang–Mills theory

In this Letter, we consider lattice versions of the decomposition of the Yang–Mills field a la Cho–Faddeev–Niemi, which was extended by Kondo, Shinohara and Murakami in the continuum formulation. For the SU(N)$\mathit{SU}(N)$ gauge group, we propose a set of defining equations for specifying the decomposition of the gauge link variable and solve them exactly without using the ansatz adopted in the previous studies for SU(2)$\mathit{SU}(2)$ and SU(3)$\mathit{SU}(3)$. As a result, we obtain the general form of the decomposition for SU(N)$\mathit{SU}(N)$ gauge link variables and confirm the previous results obtained for SU(2)$\mathit{SU}(2)$ and SU(3)$\mathit{SU}(3)$.     

Anomalies in the Fermi surface and band dispersion of quasi-one-dimensional CuO chains in the high-temperature superconductor YBa2Cu4O8

We have investigated the electronic states in quasi-one-dimensional CuO chains by microprobe angle resolved photoemission spectroscopy. We find that the quasiparticle Fermi surface consists of six disconnected segments, consistent with recent theoretical calculations that predict the formation of narrow, elongated Fermi surface pockets for coupled CuO chains. In addition, we find a strong renormalization effect with a significant kink structure in the band dispersion. The properties of this latter effect [energy scale (～40 meV), temperature dependence, and behavior with Zn-doping] are identical to those of the bosonic mode observed in CuO2 planes of high-temperature superconductors, indicating they have a common origin.     

Synthesis of macrosphelides with a thiazole side chain: new antitumor candidates having apoptosis-inducing property

Hybrid compounds of macrosphelides and epothilones, both of which are natural macrolides having a 16-membered skeleton, were designed and synthesized using a ring-closing metathesis (RCM) strategy. Some of these hybrids were found to exhibit notable apoptosis-inducing activity against human lymphoma cells with higher potency than parent natural macrosphelides, and to be a promising lead compound for development of a new antitumor agent.     

Design and synthesis of 5'-deoxy-5'-phenyladenophostin A, a highly potent IP3 receptor ligand

[structure: see text] 5'-Deoxy-5'-phenyladenophostin A (5), designed as a useful IP(3) receptor ligand based on the previous structure-activity relationship studies, was successfully synthesized via two key stereoselective glycosidation steps. This compound proved to be a highly potent IP(3) receptor agonist.     

A singular value decomposition algorithm based on solving hyperplane constrained nonlinear systems

A new algorithm for singular value decomposition (SVD) is presented through relating SVD problem to nonlinear systems whose solutions are constrained on hyperplanes. The hyperplane constrained nonlinear systems are solved with the help of Newton’s iterative method. It is proved that our SVD algorithm has the quadratic convergence substantially and all singular pairs are computable. These facts are also confirmed by some numerical examples.     

Dependence of the Electrically Controlled Birefringence on Applied Frequency in a Nematic Liquid Crystal

Detailed studies on the dependence of the ECB effect on the applied frequency have been made in a nematic liquid crystal MBBA. It is found experimentally that, when the applied voltage is just above the threshold voltage, there are strong dependences of both the delay time and the mean deformation angle of the molecular director subjected to a constant voltage setup on the applied frequency. Those applied frequency dependences of the ECB effect can be interpreted in terms of the dielectric alignment in an electrically conducting nematic liquid crystal. We have measured the capacitance of the deformed liquid crystal cell varying the applied frequency. The experimental results are compared with the Gruler and Cheung theoretical prediction, and good agreements are obtained between them when the applied voltage is just above the threshold voltage.