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151.
Kondo M Mates TE Fischer DA Wudl F Kramer EJ 《Langmuir : the ACS journal of surfaces and colloids》2010,26(22):17000-17012
Interfaces between phenylacetylene (PA) monolayers and two silicon surfaces, Si(111) and Si(100), are probed by X-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, and the results are analyzed using ab initio molecular orbital calculations. The monolayer systems are prepared via the surface hydrosilylation reaction between PA and hydrogen-terminated silicon surfaces. The following spectral features are obtained for both of the PA-Si(111) and PA-Si(100) systems: a broad π-π* shakeup peak at 292 eV (XPS), a broad first ionization peak at 3.8 eV (UPS), and a low-energy C 1s → π* resonance peak at 284.3 eV (NEXAFS). These findings are ascribed to a styrene-like π-conjugated molecular structure at the PA-Si interface by comparing the experimental data with theoretical analysis results. A conclusion is drawn that the vinyl group can keep its π-conjugation character on the hydrogen-terminated Si(100) [H:Si(100)] surface composed of the dihydride (SiH(2)) groups as well as on hydrogen-terminated Si(111) having the monohydride (SiH) group. The formation mechanism of the PA-Si(100) interface is investigated within cluster ab initio calculations, and the possible structure of the H:Si(100) surface is discussed based on available data. 相似文献
152.
Mitsushiro Nomura Shigemi Kondo Eriko Suzuki Glenn V. Alea Chikako Fujita-Takayama Masatsugu Kajitani 《Journal of organometallic chemistry》2010,695(21):2366-2895
Eight new sulfur-rich [CpCo(dithiolene)] complexes were synthesized from [Zn(dmit)2]2− as a starting material. The structures, electrochemical behavior and electronic absorption spectra of the sulfur-rich [CpCo(S2C2S2Y)] complexes could be compared with the early data of analogous Ni complexes. [CpCo(pddt)] (Y = -(CH2)3-), [CpCo(dpdt)] (Y = -CH2C(CH2)CH2-), [CpCo(bddt)] (Y = -(CH2)4-), [CpCo(dtdt)] (Y = -CH2SCH2-) and [CpCo(poddt)] (Y = -CH2C(O)CH2-) crystallized in all isostructural with the corresponding paramagnetic [CpNi(dithiolene)] complexes, but [CpCo(dmid)] (Y = CO), [CpCo(dddt)] (Y = -(CH2)2-) and [CpCo(F2pddt)] (Y = -CH2CF2CH2-) crystallized in non-isostructural with them. These molecules are associated with intermolecular short S?S contacts in the crystals. [CpCo(F2pddt)] did not show any remarkable S?S contacts but indicated interesting fluorine segregation and Cp?Cp face-to-face interactions. Redox potentials of [CpCo(dithiolene)] complexes were obtained with the cyclic voltammetry measurements and dimerized by electrochemical oxidations. Electronic absorption spectra of [CpCo(dithiolene)] complexes showed visible absorption in the range of 585-701 nm as lowest energy wavelengths (? = 9800-11,800 M−1 cm−1) in solutions, and they were higher energy than those of [CpNi(dithiolene)] complexes (near-IR). 相似文献
153.
A photo-induced radical pair of FADH· and Y8· and in BLUF protein SyPixD was studied by pulsed electron paramagnetic resonance (EPR) spectroscopy. Blue light illumination
at 150 K for 30 min followed by cooling to 50 K during illumination induced the stable radical pair. The EPR signal has been
characterized by a Pake doublet signal with complete S = 1 spin state. The radical pair was utilized as a probe to analyze the oligomer of SyPixD. The relative arrangement of PixD
proteins in the complex was investigated by pulsed electron–electron double resonance (PELDOR) with the orientation selection.
Based on the decameric structure in the crystal, the possible structure for the PELDOR results was discussed. 相似文献
154.
Michiro Kondo 《Mathematica Slovaca》2014,64(5):1093-1104
We define states on bounded commutative residuated lattices and consider their property. We show that, for a bounded commutative residuated lattice X,
- If s is a state, then X/ker(s) is an MV-algebra.
- If s is a state-morphism, then X/ker(s) is a linearly ordered locally finite MV-algebra.
- s is a state-morphism on X.
- ker(s) is a maximal filter of X.
- s is extremal on X.
155.
The present paper is devoted to a micromechanical model of porous rocks and its application to a sandstone. This original model takes advantage of a recent homogenization-based macroscopic yield function which couples Drucker-Prager type plasticity of the solid matrix and evolving porosity. Its formulation and implementation are described. Application to a Vosges sandstone shows that, except for very low confining pressures for which the mechanical behavior is quasi-brittle, the model predicts well the ductile behavior at moderate or high confining pressures (for which the pore collapse mechanism is expected to play a dominant role). 相似文献
156.
157.
Shin-ichiro Hayashi Munenori Yoshioka Shuji Usui Kiyofumi Haneda Takahiro Kondo Kim B. McAuley Takahiro Tominaga 《Radiation Physics and Chemistry》2010,79(7):803-808
In radiotherapy treatment, polymer gel dosimetry can be used for verifying three-dimensional (3D) dose distributions. Gelatin is generally used as a gelling agent in the dosimeters. In this paper, another role of gelatin in a methacrylic-acid-based gel dosimeter (MAGAT) is investigated. Temperature increases due to exothermic polymerization in the irradiated gel are measured directly. Dose–R2 responses are also obtained using MRI. It is shown that no appreciable increases in either temperature or R2 are observed in MAGAT dosimeters made without gelatin, and that significant temperature and R2 increases are observed when very low gelatin concentrations are used. These results indicate that gelatin is an important enabler for radiation-induced free-radical polymerization in methacrylic-acid-based gels. When gelatin is replaced by amino acids, changes in temperature are observed, along with small changes in R2. The resulting dosimeter solutions remain transparent because the polymer does not precipitate as it does in regular MAGAT dosimeters containing gelatin. When the amino acids are replaced by acids without amino groups, no temperature or R2 changes are observed, indicating that no polymer forms. These results show that amino groups (and possibly other functional groups) on the gelatin catalyze the radiation-induced free-radical polymerization that occurs in MAGAT dosimeters. 相似文献
158.
Effect of solvent composition on chiral recognition ability of molecularly imprinted DIDE derivatives. 总被引:2,自引:0,他引:2
In the present study, molecularly imprinted materials from the tetrapeptide derivative, H-Asp(OcHex)-Ile-Asp(OcHex)-Glu(OBzl)-CH2-, were adopted as samples to study the effect of the polarity of the environment on the chiral (molecular) recognition ability. The optimum composition, with the best chiral recognition, is a 50 vol% aqueous ethanol solution. 相似文献
159.
160.
P. G. Reutens F. S. Merritt M. J. Oreglia P. Auchincloss R. E. Blair C. Haber S. R. Mishra E. Oltman M. Ruiz F. J. Sciulli M. H. Shaevitz W. H. Smith R. Zhu R. Coleman H. E. Fisk B. Jin T. Kondo D. Levinthal W. Marsh P. A. Rapidis H. B. White D. Yovanovitch A. Bodek F. Borcherding N. Giokaris K. Lang I. E. Stockdale 《Zeitschrift fur Physik C Particles and Fields》1990,45(4):539-550
We report a measurement of the electroweak parameters sin2θ w and ? based on the ratios of neutral current to charged current events measured in the Fermilab narrow-band neutrino beam at energies of 30–240 GeV. The data are fully corrected for radiative effects, heavy-quark production, and other effects. The best value for sin2θ w obtained, sin2θ w =0.239±0.011, is consistent with the most recent values fromW andZ production, as well as from other neutrino experiments. 相似文献