Raman scattering study of toluene vibrational relaxation in benzene-toluene liquid system

The polarizes and depolarized profiles of the 520 cm^?1 Raman line of toluene in benzene solutions have been measured as a function of concentration. The vibrational correlation functions were obtained by Fourier inversion of Raman band contours. The concentration dependence of the experimental vibrational correlation time has been compared with that computed from the Fischer-Laubereau vibrational dephasing model modified for use in binary mixtures.     

Surface photovoltage spectroscopy and surface piezoelectric effect in GaAs

“Real” (111) surfaces of n-type GaAs were investigated employing surface photovoltage spectroscopy and the surface piezoelectric effect. Surface states at the energy position E_c ? E_t ? 0.72 eV were found on both the Ga and the As surfaces. Both types of surfaces exhibited a barrier of about 0.55 V. No variations in the surface barrier or the energy position of the surface states were observed in various ambients at atmospheric pressure (dry air, wet air, ammonia and ozone). However, the capture cross-section of the surface states for electrons, as determined from the surface piezoelectric effect transients (of the order of 10^?13 cm²), was found to be sensitive to the ambient. It decreased in wet air and increased in ozone. This effect was more pronounced on the As than on the Ga surfaces. Additional surface states were found to be present in the energy region of 0.9 to 1.0 eV, below the bottom of the conduction band. However, their exact energy positions could not be determined due to interference caused by the carrier trapping of the surface states at E_c ? E_t ? 0.72 eV.     

Designing strategy to enhance mode selectivity of higher-output oxide-confined vertical-cavity surface-emitting lasers

Performance of modern oxide-confined (OC) vertical-cavity surface-emitting diode lasers (VCSEL s) is more sensitive to the construction details than in the case of other VCSEL s. In particular, a stable single-fundamental-mode operation is difficult to be achieved in these VCSEL s especially in higher-output large-size continuous-wave (cw) operating devices at higher temperatures. In the present paper, an operation of OC VCSEL s has been investigated with the aid of the comprehensive fully self-consistent model using the (GaIn)(NAs)/GaAs quantum-well VCSEL with two oxide apertures as a typical example. A new approach is proposed to enhance cw RT single-fundamental-mode low-threshold operation in higher-output OC VCSEL s. One of their oxide apertures should be shifted to the node position of the resonator standing wave where it is working as the electrical aperture only. Then diameters of both apertures may be changed independently giving an additional degree of freedom for VCSEL designing, which enables their optimisation. While the larger-diameter optical aperture placed in the anti-node position creates an efficient radial waveguiding effect, the smaller-diameter electrical aperture enhances a more uniform current injection into the VCSEL active region. Due to combining influence of both the apertures, the single-fundamental-mode operation is predicted in a large device with the 10-m-diameter active region even for 80 K active-region temperature increase over RT of the ambient. An impact of intentional detuning at room-temperature (RT) of VCSEL active-region gain spectrum towards shorter wavelengths with respect to the resonator mode improves mode selectivity is also analysed. PACS  42.55.Px; 02.60.Cb; 85.60.Bt     

Ergodic Properties of the Quantum Geodesic Flow on Tori

We study ergodic averages for a class of pseudodifferential operators on the flatN-dimensional torus with respect to the Schrödinger evolution. The later can be consider a quantization of the geodesic flow on . We prove that, up to semi-classically negligible corrections, such ergodic averages are translationally invariant operators.Mathematics Subject Classifications (2000) 58J50, 58J40, 81S10.     

Solid-state structure of polypeptide-based rod-coil block copolymers: Folding of helices

This work compares the solid-state structures of films made from a polystyrene-poly(Z-L-lysine) (1) and a polystyrene-poly(-benzyl-L-glutamate) (2) block copolymer, both having virtually the same numbers of repeating units and block length ratios. Small-angle X-ray scattering (SAXS) revealed a hexagonal-in-undulated lamellar morphology for both films. The long-period and the thickness of layers obtained for 2 were by a factor of three smaller as compared to 1, indicating that PBLGlu helices were folded twice, whereas PZLLys helices were fully stretched. Another difference shows up in the packing of helices, the level of ordering being considerably lower in 2. This might be due to spatial restrictions in the proper alignment of back-folded helical segments.     

Pseudotwistors

We deal with the Hermitian Hurwitz pairs of signature (, s), + s = 5 + 4, | + 1 – s| = 2 + 4m;, m = 0, 1,.... We introduce the Hurwitz twistors for signature (3, 2) and its dual (1, 4) and we indicate the relationship between Hurwitz and Penrose twistors. The signatures (1, 8) and (7, 6) give rise to pseudotwistors and bitwistors, respectively. For pseudotwistors, we prove a counterpart of the Penrose theorem in the local version, on real analytic solutions of the related spinor equations versus harmonic forms, and in the semiglobal version, on holomorphic solutions of those equations versus Dolbeault cohomology groups. We prove an atomization theorem: There exist complex structures on isometric embeddings for the Hermitian Hurwitz pairs so that the embeddings are real parts of holomorphic mappings.     

Michael addition to a chiral non-racemic 2-phosphono-2,3-didehydrothiolane S-oxide

The Michael addition of selected sulfur and nitrogen nucleophiles to a chiral non-racemic 2-phosphono-2,3-didehydrothiolane S-oxide is fully diastereoselective. The enantiomeric excesses of the adducts obtained could be determined by ³¹P NMR spectroscopy using (R)-(+)-tert-butyl(phenyl)phosphinothioic acid as a chiral solvating agent. The addition of thiophenol was monitored by ³¹P NMR spectroscopy which made it possible to observe the formation and evolution of the kinetic and thermodynamic adducts in the reaction mixture. The structures of both enantiomeric thiophenol adducts have been determined by X-ray analysis.     

Lipophilicity Evaluation of the Products Obtained in the Reaction of N3-Substituted Amidrazones with cis-1,2-Cyclohexanedicarboxylic Anhydride

The lipophilicity of the novel 12 products of the reaction of N³-substituted amidrazones with cis-1,2-cyclohexanedicarboxylic anhydride (4 linear, 4 triazole-like and 4 isoindole ones) with potential pharmacologic activity was evaluated by thin layer and liquid chromatography. Using organic-aqueous eluent systems (with methanol or acetonitrile) on RP18 plates and C18 column, a linear relationship between the volume fraction of modifiers and the retention indices was obtained. The retention values, log k or R _M were extrapolated to zero organic modifier content to obtain the log k _w or R _MW values. 12 compounds with known literature lipophilicity were used as a calibration dataset. The results were compared in a multivariate way with in silico methods (ALOGPs, AC_logP, AB/LogP, COSMOFrag, miLogP, ALOGP, MLOGP, KOWWIN, XLOGP3).