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11.
G. G. Sadikov A. S. Antsyshkina T. V. Koksharova I. S. Gritsenko V. S. Sergienko 《Crystallography Reports》2007,52(5):819-825
The [Co2 L 4(C4H9COO)4(H2O)] coordination compound of cobalt(II) valerate with nicotinamide (L) is synthesized and studied by IR spectroscopy. The crystal structure of the synthesized compound is determined. The crystals are triclinic, and the unit cell parameters are as follows: a = 10.2759(10) Å, b = 16.3858(10) Å, c = 16.4262(10) Å, α = 100.538(10)°, β = 101.199(10)°, γ = 90.813 (10)°, Z = 2, and space group P \(\bar 1\). The structural units of the crystal are dimeric molecular complexes in which pairs of cobalt atoms are linked by triple bridges formed by oxygen atoms of two bidentately coordinated valerate anions and a water molecule. The octahedral coordination of each cobalt atom is complemented by the pyridine nitrogen atoms of two nicotinamide ligands and the oxygen atom of the monodentate valerate group. The hydrocarbon chains of the valerate anions are disordered over two or three positions each. 相似文献
12.
V. N. Konyukhov L. N. Dianova T. G. Koksharova N. V. Volkova V. A. Bakulev O. S. Anisimova 《Chemistry of Heterocyclic Compounds》1985,21(3):355-358
Aminonitrile cleavage of the cyclic system was observed in the reaction of s-triazolo[1,5-c]pyrimidine derivatives with aryl (alkyl) halides in an alkaline medium or in dimethylfonnamide. It is shown that this transformation proceeds through the formation of intermediate quaternary salts. The effect of electron-acceptor and electron-donor substituents on their stability was ascertained. The structures of the substances were established by means of IR, UV, PMR, and mass spectroscopy.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 421–425, March, 1985. 相似文献
13.
T. V. Koksharova 《Journal of Structural Chemistry》2004,45(2):344-347
The interaction of manganese(II) with diphenylthiocarbazide in ethanol solutions with various concentrations has been investigated. The structure and composition of the products have been determined. Structure refinement was performed for diphenylcarbazide and dehydrodithizone. 相似文献
14.
The catalytic activity of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), and Cu(II) diphenylthiocarbazide complexes in decomposition of hydrogen peroxide was studied. The activation energies of this reaction were correlated with the strength of ligand bonding to the metal atom in the catalyst molecule. 相似文献
15.
The following complexes were synthesized from 3d-metal nitroprussides and thiosemicarbazide: [CrL3][Fe(CN)5H2O] · 6H2O, [FeL3]2[Fe(CN)5NO]3 · 14H2O, [CoL3]2[Fe(CN)5NO]3 · 4H2O, [NiL2][Fe(CN)5NO], [CuL2][Fe(CN)5NO] · 5H2O, and [[ZnL2][Fe(CN)5NO], where L is thiosemicarbazide. Their structures and properties were studied by IR and diffuse reflection spectroscopies and DTA. 相似文献
16.
Koksharova T. V. Ptashchenko A. A. Masleeva N. V. Fel'dman S. V. Pasternak N. N. Stukalov S. A. 《Theoretical and Experimental Chemistry》2002,38(4):263-267
The temperature dependence of the resistivity of tablets of hexacyanoferrate(II)–thiosemicarbazide complexes of chromium(III), manganese(II), iron(III), cobalt(III), nickel(II), copper(II), and zinc(II) was measured in the range 20-90 °C. A relationship between the conductivity of a substance and the rate constant for the catalytic decomposition of hydrogen peroxide is established. 相似文献
17.
18.
A. S. Antsyshkina T. V. Koksharova V. S. Sergienko T. V. Mandzii G. G. Sadikov 《Russian Journal of Inorganic Chemistry》2016,61(1):33-37
Coordination compound [Ni(L)3]Cl2 · 2H2O (L is benzohydrazide) has been synthesized and studied by IR spectroscopy and X-ray diffraction analysis. According to X-ray diffraction, one of the Cl– ions is disordered over two nonequivalent positions. The crystals are monoclinic, a = 15.423(3) Å, b = 9.697(2) Å, c = 18.893(4) Å, ß = 105.99(3)°, space group P21/c, Z = 4. The structural units of the crystal are complex cations [Ni(L)3]2+, in which ligands L are coordinated to the central atom bidentately chelating the metal atoms through the O and N atoms of the hydrazide moiety (Ni–O 2.036(4), 2.051(5), 2.047(5); Ni–N 2.095(5), 2.089(6), 2.097(6) Å). The structural units of the crystal are joined together by cation–anion electrostatic interactions and hydrogen bonds, which involve both H2O molecules, both Cl– anions and the N atoms of chelate rings of the complex cation. 相似文献
19.
A. S. Antsyshkina G. G. Sadikov T. V. Koksharova I. S. Gritsenko V. S. Sergienko 《Russian Journal of Inorganic Chemistry》2009,54(8):1310-1315
The coordination compound of cobalt(II) with nicotinamide [CoL2(H2O)4][C6H4(COO)2] · 2H2O (I) (where L stands for nicotinamide) was synthesized and characterized by IR spectroscopy, conductometry, and thermogravimetry.
The X-ray structure of complex I was determined. Crystals are monoclinic: a = 15.630(2) ?, b = 7.550(2) ?, c = 21.035(4) ?, β = 100.90(5)°, V = 2437.4(4) ?3, Z = 4, space group C2/c. The structural units of complex I are centrosymmetrical cations [CoL2(H2O)4]2+, anions [C6H4(COO)2]2− (lying on axis 2), and molecules of waster of crystallization. Complex cations are packed into layers are alternate with
layers containing anions and free H2O molecules. This is a classical case of π-π-staking interactions that lead to the formation of supramolecular layered assemblies.
Original Russian Text ? A.S. Antsyshkina, G.G. Sadikov, T.V. Koksharova, I.S. Gritsenko, V.S. Sergienko, 2009, published in
Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 8, pp. 1379–1384. 相似文献
20.
T. G. Koksharova L. F. Lipatova V. N. Konyukhov G. N. Smotrina Z. V. Pushkareva 《Chemistry of Heterocyclic Compounds》1973,9(4):513-517
The structures of 1-oxo-4-hydroxypyridazino[4,5-b]quinoxaline and some of its methyl derivatives were established by IR and UV spectroscopy.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 556–561, April, 1973. 相似文献