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101.
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103.
Hui H. Chin Leonid V. Azroff Agya R. Saini Robert W. Lenz 《Journal of Polymer Science.Polymer Physics》1989,27(10):2001-2009
Semiflexible thermotropic aromatic polyesters with lateral groups were aligned magnetically and mechanically in monodomains after separation into high-molecular-weight (polymer) and low-molecular-weight (oligomer) fractions. Based on the x-ray intensity distributions recorded for a series of seven different substituents in the arylsulfonyl substituted group, a novel smectic structure was determined for H, F, Cl, OCH3, and CH3 in the para position while a normal nematic alignment prevailed when it contained Br or NO2. 相似文献
104.
Simulating the non-perturbative and non-Markovian dynamics of open quantum systems is a very challenging many body problem, due to the need to evolve both the system and its environments on an equal footing. Tensor network and matrix product states (MPS) have emerged as powerful tools for open system models, but the numerical resources required to treat finite-temperature environments grow extremely rapidly and limit their applications. In this study we use time-dependent variational evolution of MPS to explore the striking theory of Tamascelli et al. (Phys. Rev. Lett. 2019, 123, 090402.) that shows how finite-temperature open dynamics can be obtained from zero temperature, i.e., pure wave function, simulations. Using this approach, we produce a benchmark dataset for the dynamics of the Ohmic spin-boson model across a wide range of coupling strengths and temperatures, and also present a detailed analysis of the numerical costs of simulating non-equilibrium steady states, such as those emerging from the non-perturbative coupling of a qubit to baths at different temperatures. Despite ever-growing resource requirements, we find that converged non-perturbative results can be obtained, and we discuss a number of recent ideas and numerical techniques that should allow wide application of MPS to complex open quantum systems. 相似文献
105.
A theory suitable for studying pulses propagating through a layered fluid-saturated porous medium is presented. Biot's theory is used to describe the constitutive equation of a fluid-saturated porous solid. Since fast and slow compressional waves exist in a Biot solid even at normal incidence, there is mode conversion at the interface and, therefore, the transmission and reflection coefficients are 2x2 matrices. We use matrix methods in developing the solution of the wave propagation problem. A generalized ray expansion algorithm is obtained by using the Gauss-Seidel matrix iterative method. The arrivals of the fast and the slow waves are easily identified. A compact computational algorithm is developed using combinatorial analysis and the Cayley-Hamilton theorem. 相似文献
106.
Kee CH Ariffin A Awang K Takeya K Morita H Hussain SI Chan KM Wood PJ Threadgill MD Lim CG Ng S Weber JF Thomas NF 《Organic & biomolecular chemistry》2010,8(24):5646-5660
The syntheses of fourteen unusual o-carboxamido stilbenes by the Heck protocol revealed surprising complexity related to intriguing substituent effects with mechanistic implications. The unexpected cytotoxic and chemopreventive properties also seem to be substituent dependent. For example, although stilbene 15d (with a 4-methoxy substituent) showed cytotoxicity on HT29 colon cancer cells with an IC(50) of 4.9 μM, the 3,4-dimethoxy derivative (15c) is inactive. It is interesting to observe that the 3,5-dimethoxy derivative (15e) showed remarkable chemopreventive activity in WRL-68 fetal hepatocytes, surpassing the gold standard, resveratrol. The resveratrol concentration needed to be 5 times higher than that of 15e to produce comparable elevation of NQO1. 相似文献
107.
Zhi‐Chang Liu Dr. Chih‐Hsien Chen Dr. Hsian‐Wen Wang Yen‐Chin Huang Ming‐Jui Kao Tsong‐Shin Lim Prof. Tien‐Yau Luh Prof. 《化学:亚洲杂志》2010,5(6):1425-1438
Polynorbornenes appended with porphyrins containing a range of different linkers are synthesized. The use of bisamidic chiral alanine linkers between the pending porphyrins and the polymeric backbone has been shown to bring the adjacent porphyrin chromophores to more suitable orientation for exciton coupling owing to hydrogen bonding between the adjacent linkers. The hydrogen bonding between the adjacent pendants in these polymers may induce a cooperative effect and therefore render single‐handed helical structures for these polymers. Such a cooperative effect is reflected in the enhancement of FRET efficiencies between zinc–porphyrin and free base porphyrin in random copolymers. 相似文献
108.
Chin Chye Teo Swee Ngin Tan Jean Wan Hong Yong Choy Sin Hew Eng Shi Ong 《Journal of chromatography. A》2010,1217(16):2484-2494
Pressurized hot water extraction (PHWE) has become a popular green extraction method for different classes of compounds present in numerous kinds of matrices such as environmental, food and botanical samples. PHWE is also used in sample preparation to extract organic contaminants from foodstuff for food safety analysis and soils/sediments for environmental monitoring purposes. The main parameters which influence its extraction efficiency are namely the temperature, extraction time, flow rates and addition of modifiers/additives. Among these different parameters studied, temperature is described as the most important one. It is reported that the extraction of certain compounds is rather dependent on pressurized water with different applied temperature. Thus, the stability and reduced solubilities of certain compounds at elevated temperatures are highlighted in this review. With some modifications, a scaled-up PHWE could extract a higher amount of desirable compounds from solid and powdered samples such as plant and food materials. The PHWE extracts from plants are rich in chemical compounds or metabolites which can be a potential lead for drug discovery or development of disease-resistant food crops. 相似文献
109.
110.
Nonwoven fibers of cellulose were obtained by electrospinning of cellulose in an ionic liquid, 1-butyl-3-methylinmidazolium
chloride (BMIMCl), which is known to be one of the non-volatile solvents. The electrospinning setup was modified in such a
way that the syringe was contained in a constant-temperature chamber because of the high melting point of BMIMCl, and the
electrospun fibers were collected on the water, which immediately removed the remnant solvent from the electrospun cellulose
fibers. The effect of the viscosity of the cellulose solution in BMIMCl on the size and the structure of the fibers was investigated.
The crystalline structure of cellulose was examined by X-ray diffraction. Also, the effect of dimethyl sulfoxide, which was
expected to induce swelling of cellulose, was studied. The minimum diameter of the continuous electrospun cellulose fibers
obtained in this work ranged between 500 and 800 nm. 相似文献