Octacyanidorhenate(V) Ion as an Efficient Linker for Hysteretic Two-Step Iron(II) Spin Crossover Switchable by Temperature,Light, and Pressure

A two-step hysteretic Fe^II spin crossover (SCO) effect was achieved in programmed layered Cs{[Fe(3-CNpy)₂][Re(CN)₈]}⋅H₂O ( 1 ) (3-CNpy=3-cyanopyridine) assembly consisting of cyanido-bridged Fe^II-Re^V square grid sheets bonded by Cs⁺ ions. The presence of two non-equivalent Fe^II sites and the conjunction of 2D bimetallic coordination network with non-covalent interlayer interactions involving Cs⁺, [Re^V(CN)₈]³⁻ ions, and 3-CNpy ligands, leads to the occurrence of two steps of thermal SCO with strong cooperativity giving a double thermal hysteresis loop. The resulting spin-transition phenomenon could be tuned by an external pressure giving the room-temperature range of SCO, as well as by visible-light irradiation, inducing an efficient recovery of the high-spin Fe^II state at low temperatures. We prove that octacyanidorhenate(V) ion is an outstanding metalloligand for induction of a cooperative multistep, multiswitchable Fe^II SCO effect.     

Generation of light-induced electrical potential from ion exchange membranes containing 4,4′-bipyridine moiety. II. Effect of species of anion exchange membranes on photovoltage

Various anion exchange membranes containing the 4,4′-bipyridine moiety as anion exchange groups were prepared from membranous copolymers of chloromethylstyrene and divinylbenzene and membranes of chloromethylated polysulfone and 4,4′-bipyridine. After evaluating the electrochemical properties of the obtained anion exchange membranes, the effect of membrane species on the generation of a photovoltage was examined by irradiation using a xenon lamp. The membranes swelled with ethylene glycol were clamped between two ITO electrodes and sealed by adhesive. The generated photovoltage and photocurrent from about a 120 μm thick membrane were about 80 mV and 400 nA, respectively, in a 200K Ω load resistance, though dependent of membrane species. The voltage decreased with increasing crosslinking by the divinylbenzene in the copolymer membranes. The effect of counter ion species on the voltage was examined and a chloride ion form of membrane showed the highest photovoltage. The membranes with different thicknesses, which were prepared from polysulfone derivatives, were evaluated and the voltage decreased with decreasing thickness. Even a porous membrane from polysulfone derivatives showed a photovoltage though a porous membrane in which a methyl viologen ethylene glycol solution had been impregnated did not have a stable voltage. Also, the anion exchange membrane containing the benzyl trimethylammonium moiety, which is the conventional anion exchange groups, did not show a high and stable photovoltage upon photoirradiation. © 1996 John Wiley & Sons, Inc.     

Fabrication of microfluidic optical waveguides on glass chips with femtosecond laser pulses

We describe the fabrication of microfluidic channel structures on the surface of a borosilicate glass slide by femtosecond laser direct writing for optical waveguide application. Liquid with a variable refractive index is fed into the microchannel, serving as the core of the waveguide. We demonstrate that either a multimode or a single-mode waveguide can be achieved by controlling the refractive index of the liquid.     

Non-secular part of nuclear dipolar broadening detected by zero-field spin relaxation of positive muon

The zero-field spin relaxation function of μ⁺ observed in ZrH₂ has revealed that the second moment of the nuclear dipolar broadening is five times larger than the high-field value. This experiment clearly demonstrates the recovery of the non-secular part of dipolar interaction between unlike spins. A general expression of zero-field relaxation function is presented to account for a slow modulation of random fields on μ⁺ found at room temperature.     

Time Invariance as an Additional Constraint on Nonlocal Realism

We assume that time invariance of physical laws is true. We assume that one source of 2N uncorrelated spin-carrying particles emits them in a state, which can be described as a multipartite pure uncorrelated state (+∞>N≥1). We assume that each of them is a spin-1/2 pure state lying in the \(\frac{z+x}{\sqrt{2}}\) direction. We assume that the measurement setup is two-orthogonal-settings for each of the observers. We show that 2N-particle pure uncorrelated quantum state violates a time invariant nonlocal realistic theory. 2N implies that we consider Bose-Einstein statistics.     

A complete calculation for direct detection of Wino dark matter

In the anomaly-mediated supersymmetry (SUSY) breaking scenario, neutral gaugino of SUL₍₂₎$\mathit{SU}{(2)}_L$ multiplet, Wino, can be the lightest SUSY particle and become a candidate for dark matter. We calculated scattering cross section of Wino dark matter with nucleon, which is responsible for direct detection of the dark matter, on the assumption that the SUSY particles and the heavier Higgs bosons have masses of the order of the gravitino mass in the SUSY standard model. In such a case, the Wino–nucleon coupling is generated by loop processes. We have included two-loop contribution to Wino–gluon interaction in the calculation, since it is one of the leading contributions to the Wino–nucleon coupling. It was found that the spin-independent scattering cross section with proton is ^{10−(46–48)} cm²${10}^{-(46\text{–}48)}{\text{cm}}^2$. While it is almost independent of the Wino mass, the result is quite sensitive to the Higgs boson mass due to the accidental cancellation.     

Quantum dot FRET biosensors that respond to pH, to proteolytic or nucleolytic cleavage, to DNA synthesis, or to a multiplexing combination

Fluorescent acceptors have been immobilized on nanoparticulate quantum dots (QDs), which serve in turn as their FRET donors. The broad excitation and narrow emission bands of QDs mark them as having excellent potential as donors for FRET and, in principle, differently colored QDs could be excited simultaneously. The present work describes the preparation and operation of FRET-based QD bioprobes individually able to detect the actions of protease, deoxyribonuclease, DNA polymerase, or changes in pH. In addition, two such QD-mounted biosensors were excited at a single wavelength, and shown to operate simultaneously and independently of each other in the same sample solution, allowing multiplex detection of the action of a protease, trypsin, in the presence of deoxyribonuclease.