Oxygen-deficiency effect on properties for the ordered-perovskite cuprate,Sr2Cu(Re0.69Ca0.31)Oy (y=6.0−5.4)

We have studied physical properties and crystal structures for oxygen-deficient phases of the cubic ordered-perovskite cuprate, Sr₂Cu(Re_0.69Ca_0.31)O_y (y=6.0−5.4). It was found that the magnetic state undergoes phase transition from ferrimagnetic long-range order for y?5.9 to paramagnetism for y?5.7 via re-entrant-type spin-glass randomness in the narrow composition range around y∼5.8, as the oxygen content y decreases. The electrical resistivity becomes insulated, and the lattice constant expands simultaneously with decrease in y. The abrupt suppression of the ferrimagnetic state was observed in the oxygen-deficiency phase around 5.9?y?5.7. This is presumably attributed to microscopic phase separation accompanied by the partial cut-off of the Cu–O–Cu antiferromagnetic correlation path, which is caused by cation disorder and reduction of the oxidation state of the cations.     

Desorption of chlorine atoms on Si (1 1 1)-(7 × 7) surfaces induced by hole injection from scanning tunneling microscope tips

We investigated desorption of chlorine atoms on Si (1 1 1)-(7 × 7) surfaces induced by hole injection from scanning tunneling microscope tips. The hole-induced desorption of chlorine atoms had a threshold bias voltage corresponding to the energy position of the S3 surface band originated in Si backbonds. The chlorine atom desorption rate was almost proportional to the square of the tunneling current. We have discussed possible mechanisms that two holes injected into Si surface states get localized at the backbonds of chlorinated Si adatoms, which induces the rupture of Cl-Si bonds to result in chlorine atom desorption.     

Hyperfine interaction of 25Al in α-Al2O3 and its quadrupole moment

A brief review is presented of recent work with the Precision Penning Trap Mass Spectrometer, formerly at MIT, now at Florida State University. This includes atomic mass comparisons using single trapped ions; mass comparisons using two simultaneously trapped ions alternated between large and small cyclotron radii; and measurement of the dipole moment of a molecular ion using the polarizability-induced shift in cyclotron frequency.     

<Emphasis Type="Italic">CP</Emphasis> violation due to multi-Froggatt–Nielsen fields

We study how to incorporate CP violation in the Froggatt–Nielsen (FN) mechanism. To this end, we introduce non-renormalizable interactions with a flavor democratic structure to the fermion mass generation sector. It is found that at least two iso-singlet scalar fields with a discrete symmetry imposed are necessary to generate CP violation due to the appearance of the relative phase between their vacuum expectation values. In the simplest model, the ratios of quark masses and the Cabibbo–Kobayashi–Maskawa (CKM) matrix including the CP violating phase are determined by the CKM element |V_us| and the ratio of two vacuum expectation values of FN fields, R=|R|e^iα (a magnitude and a phase). It is demonstrated how the angles φ_i (i=1,...,3) of the unitarity triangle and the CKM off-diagonal elements |V_ub| and |V_cb| are predicted as a function of |V_us|, |R| and α. Although the predicted value of the CP violating phase does not agree with the experimental data within the simplest model, the basic idea of our scenario would be promising if one wants to construct a more realistic model of flavor and CP violation. PACS 11.30.Er; 12.60.-i     

Central administration of dipeptides,beta-alanyl-BCAAs,induces hyperactivity in chicks

Background  

Carnosine (β-alanyl-L-histidine) is a putative neurotransmitter and has a possible role in neuron-glia cell interactions. Previously, we reported that carnosine induced hyperactivity in chicks when intracerebroventricularly (i.c.v.) administered. In the present study, we focused on other β-alanyl dipeptides to determine if they have novel functions.     

Microscopic magnetic property of perpendicular magnetic films of DyxCo100−x measured using soft X-ray magnetic circular dichroism

We have carried out X-ray absorption measurements with its magnetic circular dichroism (MCD) of perpendicular magnetic films of Dy_xCo_100−x (15?x?33) at Dy M_4,5 and Co L_2,3 absorption edges to investigate electronic and spin states of the Dy 4f and Co 3d states, respectively. The replacement of major spin between Dy 4f and Co3d is clearly observed in the spectra between 20?x?25. The expected values of the orbital angular moment ∣〈L_z〉∣ of Dy 4f were estimated to be 1.4-0.8 μ_B while that of Co 3d was estimated to be around 0.2 μ_B.     

Fabricating and aligning pi-conjugated polymer-functionalized DNA nanowires: atomic force microscopic and scanning near-field optical microscopic studies

We report a simple method to functionalize DNA with pi-conjugated polymer, forming highly aligned and integrated arrays of pi-conjugated polymer nanowires of a few nanometers diameter. pi-conjugated polymer, polyphenazasiline, having alkylammonium salts on the N atom (PPhenaz-TMA), synthesized in this study can be directly attached to DNA, which can be organized along stretched and aligned DNA molecules on surfaces as a template. Furthermore, PPhenaz-TMA/DNA nanowires were stretched and aligned on surfaces, even when PPhenaz-TMA/DNA complexes formed in solutions. The resulting PPhenaz-TMA/DNA nanowires could be easily converted to oxidized states or metallic nanowires by using adequate oxidant or metal salts. The direct visualization of PPhenaz-TMA/DNA nanowires and its structural changes have been studied by atomic force microscopy and scanning near-field optical microscopy.     

Design and synthesis of artificial phospholipid for selective cleavage of integral membrane protein

An artificial phospholipid, possessing saturated alkyl chains as a membrane anchor and protein recognition site as well as an Fe(III)-EDTA moiety as a protein cleavable polar head group, was designed and synthesized based on the amidite method for the purpose of examination of cleavage of integral membrane proteins.     

Improved method of the MALDI-TOF analysis of DNA with nanodot sample target plate

We report a new sample target plate for MALDI-TOF mass spectrometry made of SiO2 with 30 nm Pt dots for which a highly reproducible and improved DNA analysis was achieved.