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101.
Hiroshi Oki Ichiro Oura Tatsuhito Nakamura Kenichi Ogata Shin-ichi Fukuzawa 《Tetrahedron: Asymmetry》2009,20(18):2185-2191
A series of diphosphine ClickFerrophos ligands (CF), based on a triazoleferrocene backbone, was synthesized in a four-step sequence via click chemistry methodology. In addition to the four previously synthesized ligands CF1, CF4, CF7 and CF10, six novel CF ligands CF2–3 and CF5–8 were prepared. Hydrogenation reactions of alkenes and ketones were significantly improved upon by using CF ligands as rhodium- or ruthenium-complexes in which the % ee values can be optimized by choosing the appropriate CF ligand depending on the substrate. 相似文献
102.
Masahiro Yoshida Tsutomu Matsui Yasuo Hatate Takayuki Takei Koichiro Shiomori Shiro Kiyoyama 《Journal of polymer science. Part A, Polymer chemistry》2008,46(5):1749-1757
Nylon‐polystyrene microcapsules with immobilized ferroelectric liquid crystalline segments were prepared, and permeability control of an encapsulated core material was investigated under an external electric field. A ferroelectric liquid crystal monomer possessing both mesogenicity and chirality responded effectively to the external electrical field. Permeation of the material (oxprenolol) contained in the inner aqueous core of the microcapsules was enhanced under a weak electric field (2 V). Furthermore, the permeability of oxprenolol did not depend on the external electric field in the absence of the ferroelectric liquid crystal segments. To clarify the controlled‐release mechanism of the core material, the light transmittance of the polymer membranes was quantitatively evaluated under an external electric field using a handmade polarized light transmittance apparatus. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1749–1757, 2008 相似文献
103.
104.
Akitoshi Ogata 《Tetrahedron letters》2008,49(19):3071-3074
Titanocene(II)-promoted alkenylation of functionalized alkynes with (Z)-alkenyl sulfones proceeded with high regio- and stereoselectivity to produce functionalized dienes. Conjugated dienylcarboxylic acids and dienylphosphonic esters were obtained using acetylenic lithium carboxylates and dialkyl phosphonates as starting materials. 相似文献
105.
Katsumi Katoh Shunsuke Ito Yuji Ogata Jun-ichi Kasamatsu Hiroshi Miya Masaaki Yamamoto Yuji Wada 《Journal of Thermal Analysis and Calorimetry》2010,99(1):159-164
In order to prevent the spontaneous ignition of nitrocellulose (NC), NC is stabilized by washing with industrial water in
its synthesis process. However, there is a possibility that the components in industrial water contribute to the thermal stability
of NC. In this way, the purpose of this study is to clarify the effect of industrial water components on the thermal stability
of NC. In experiments, a heat flux calorimeter was used to observe the thermal behavior of NC with the residue of vaporized
industrial water. The induction period of heat release of NC with 2-mass% residues was approximately 2–5 h shorter than that
of NC alone whose induction period was observed at 7 h. Those results indicate that the residue destabilized NC. On the other
hand, when the additive amount of the residue was increased, the induction period gradually increased as well. Based upon
these results, we assume that inorganic salts contributing to stabilization and destabilization competitively coexist in the
industrial water components. The same thermal analysis was performed on NC with CaCO3, CaSO4, CaCl, ZnSO4, NaCl, and CuCl. Those salts are predicted to exist in the industrial water. In the results, the induction period of NC with
2-mass% CaCO3 was approximately 15-h longer than that of NC alone, while the induction period with the inorganic salts CaSO4, CaCl, ZnSO4, NaCl, and CuCl was 4–5-h shorter. Therefore, when the industrial water components accumulate in NC, the destabilization
by inorganic salts such as CaSO4, CaCl, ZnSO4, NaCl, and CuCl and the stabilization by compounds such as CaCO3 are thought to countervail against each other. 相似文献
106.
Tsunewaki K 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2011,87(8):529-549
A homology search of wheat chloroplast (ct) and mitochondrial (mt) genomes identified 54 ctDNA segments that have homology with 66 mtDNA segments. The mtDNA segments were classified according to their origin: orthologs (prokaryotic origin), xenologs (interorganellar DNA transfer origin) and paralogs (intraorganellar DNA amplification origin). The 66 mtDNA sequences with homology to ctDNA segments included 14 paralogs, 18 orthologs and 34 xenologs. Analysis of the xenologs indicated that the DNA transfer occurred unidirectionally from the ct genome to the mt genome. The evolutionary timing of each interorganellar DNA transfer that generated a xenolog was estimated. This analysis showed that 2 xenologs originated early in green plant evolution, 4 in angiosperm evolution, 3 in monocotyledon evolution, 9 during cereal diversification and 8 in the evolution of wheat. Six other xenologs showed recurrent transfer from the ct to mt genomes in more than one taxon. The two remaining xenologs were uninformative on the evolutionary timing of their transfer. The wheat mt nad9 gene was found to be chimeric, consisting of the cereal nad9 gene and its 291 bp 5'-flanking region that included a 58 bp xenolog of the ct-ndhC origin. 相似文献
107.
We present a new method of smoothing discrete breakup cross sections calculated by the continuum-discretized coupled-channels method based on the complex-scaling method. One of the advantages of this approach is to be applicable to many-body breakup reaction systems. In this work, we apply the new smoothing method to analyses of 12C(6He, nn 4He) and 208Pb(6He, nn 4He) reactions at 240 MeV/A. 相似文献
108.
Radical additions of S-thiophosphinyl dithiocarbonate to terminal aromatic alkynes afford (E)-1-aryl-1-thio-2-thiophosphinylethene derivatives regio- and stereoselectively in high yields. The transformations of the products are also described. 相似文献
109.
Koichiro Ohtake 《代数通讯》2013,41(15):1533-1540