全文获取类型
收费全文 | 569篇 |
免费 | 12篇 |
国内免费 | 1篇 |
专业分类
化学 | 484篇 |
晶体学 | 3篇 |
力学 | 3篇 |
数学 | 27篇 |
物理学 | 65篇 |
出版年
2022年 | 2篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 4篇 |
2017年 | 2篇 |
2016年 | 7篇 |
2015年 | 4篇 |
2014年 | 4篇 |
2013年 | 40篇 |
2012年 | 31篇 |
2011年 | 31篇 |
2010年 | 24篇 |
2009年 | 19篇 |
2008年 | 35篇 |
2007年 | 38篇 |
2006年 | 32篇 |
2005年 | 42篇 |
2004年 | 32篇 |
2003年 | 31篇 |
2002年 | 42篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1998年 | 11篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1987年 | 2篇 |
1985年 | 5篇 |
1984年 | 15篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 5篇 |
1979年 | 6篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 7篇 |
1972年 | 8篇 |
1971年 | 5篇 |
1970年 | 5篇 |
1969年 | 3篇 |
1968年 | 2篇 |
1967年 | 3篇 |
1966年 | 7篇 |
排序方式: 共有582条查询结果,搜索用时 15 毫秒
51.
Fujii T Naito A Yamaguchi S Wada A Funahashi Y Jitsukawa K Nagatomo S Kitagawa T Masuda H 《Chemical communications (Cambridge, England)》2003,(21):2700-2701
A novel hydroperoxo-copper(II) complex with a square-planar geometry has been prepared, which has exhibited a higher selectivity and catalytic reactivity for dimethyl sulfide, in contrast to that with a trigonal-bipyramidal one. 相似文献
52.
53.
[reaction: see text] Treatment of allenes with tetraallylmanganate provides allylated products with high regioselectivity. A catalytic amount of MnCl(2) combined with allylmagnesium chloride also achieves efficient allylmetalation of allenes. The resulting alkenylmagnesium species react with various electrophiles. In the presence of molecular oxygen, the alkenylmagnesium undergoes diallylation reaction. A cyclization reaction of 1,2,6-heptatriene with tetraallylmanganate is also described. 相似文献
54.
Florian J. Stadler Tatsuhiro Takahashi Koichiro Yonetake 《European Polymer Journal》2011,(5):1048-1053
Ethene-/α-olefin copolymers having a wide range of comonomers between 8 and 26 carbon atoms in length were characterized by wide angle X-ray diffraction (WAXD). It was found that the crystallinities for the shorter comonomers (C8, C12) matched fairly well with the crystallinities from DSC and volumetric measurements, while for the longer comonomers (C18, C26) distinct differences between the three methods were found. This was explained by the presence of an additional crystalline phase of the side chains slightly deforming the amorphous peak. 相似文献
55.
Masahiro Yoshida Tsutomu Matsui Yasuo Hatate Takayuki Takei Koichiro Shiomori Shiro Kiyoyama 《Journal of polymer science. Part A, Polymer chemistry》2008,46(5):1749-1757
Nylon‐polystyrene microcapsules with immobilized ferroelectric liquid crystalline segments were prepared, and permeability control of an encapsulated core material was investigated under an external electric field. A ferroelectric liquid crystal monomer possessing both mesogenicity and chirality responded effectively to the external electrical field. Permeation of the material (oxprenolol) contained in the inner aqueous core of the microcapsules was enhanced under a weak electric field (2 V). Furthermore, the permeability of oxprenolol did not depend on the external electric field in the absence of the ferroelectric liquid crystal segments. To clarify the controlled‐release mechanism of the core material, the light transmittance of the polymer membranes was quantitatively evaluated under an external electric field using a handmade polarized light transmittance apparatus. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1749–1757, 2008 相似文献
56.
57.
Tsunewaki K 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2011,87(8):529-549
A homology search of wheat chloroplast (ct) and mitochondrial (mt) genomes identified 54 ctDNA segments that have homology with 66 mtDNA segments. The mtDNA segments were classified according to their origin: orthologs (prokaryotic origin), xenologs (interorganellar DNA transfer origin) and paralogs (intraorganellar DNA amplification origin). The 66 mtDNA sequences with homology to ctDNA segments included 14 paralogs, 18 orthologs and 34 xenologs. Analysis of the xenologs indicated that the DNA transfer occurred unidirectionally from the ct genome to the mt genome. The evolutionary timing of each interorganellar DNA transfer that generated a xenolog was estimated. This analysis showed that 2 xenologs originated early in green plant evolution, 4 in angiosperm evolution, 3 in monocotyledon evolution, 9 during cereal diversification and 8 in the evolution of wheat. Six other xenologs showed recurrent transfer from the ct to mt genomes in more than one taxon. The two remaining xenologs were uninformative on the evolutionary timing of their transfer. The wheat mt nad9 gene was found to be chimeric, consisting of the cereal nad9 gene and its 291 bp 5'-flanking region that included a 58 bp xenolog of the ct-ndhC origin. 相似文献
58.
59.
Radical additions of S-thiophosphinyl dithiocarbonate to terminal aromatic alkynes afford (E)-1-aryl-1-thio-2-thiophosphinylethene derivatives regio- and stereoselectively in high yields. The transformations of the products are also described. 相似文献
60.
Koichiro Ohtake 《代数通讯》2013,41(15):1533-1540