全文获取类型
收费全文 | 1886篇 |
免费 | 52篇 |
国内免费 | 6篇 |
专业分类
化学 | 1537篇 |
晶体学 | 31篇 |
力学 | 27篇 |
数学 | 64篇 |
物理学 | 285篇 |
出版年
2023年 | 8篇 |
2022年 | 18篇 |
2021年 | 14篇 |
2020年 | 24篇 |
2019年 | 26篇 |
2018年 | 17篇 |
2016年 | 30篇 |
2015年 | 33篇 |
2014年 | 40篇 |
2013年 | 121篇 |
2012年 | 90篇 |
2011年 | 101篇 |
2010年 | 75篇 |
2009年 | 69篇 |
2008年 | 118篇 |
2007年 | 90篇 |
2006年 | 112篇 |
2005年 | 101篇 |
2004年 | 81篇 |
2003年 | 82篇 |
2002年 | 109篇 |
2001年 | 31篇 |
2000年 | 22篇 |
1999年 | 31篇 |
1998年 | 16篇 |
1997年 | 24篇 |
1996年 | 26篇 |
1995年 | 21篇 |
1994年 | 19篇 |
1993年 | 20篇 |
1992年 | 17篇 |
1991年 | 13篇 |
1990年 | 12篇 |
1989年 | 8篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 12篇 |
1985年 | 35篇 |
1984年 | 27篇 |
1983年 | 14篇 |
1982年 | 28篇 |
1981年 | 20篇 |
1980年 | 27篇 |
1979年 | 23篇 |
1978年 | 17篇 |
1977年 | 16篇 |
1976年 | 17篇 |
1975年 | 15篇 |
1973年 | 12篇 |
1972年 | 8篇 |
排序方式: 共有1944条查询结果,搜索用时 0 毫秒
11.
Gas-phase ionization potentials of tetraphenylporphine and some metallotetraphenylporphines have been determined by the method of photocurrent measurements in nonpolar solvents reported previously [1]. The values obtained range from 5.9 to 6.3 eV, depending on the central metal ion, correlating well with the reported polarographic oxidation potentials. It has been concluded that photoelectron ejection from these complexes in isooctane occurs from the porphyrin π-system in all cases including Co(II) tetraphenylporphine, in which the electron is thought to be removed from the metal in polar solvents. 相似文献
12.
Fukuji Higashi Koichi Kubota Misuzu Sekizuka Morio Higashi 《Journal of polymer science. Part A, Polymer chemistry》1981,19(11):2681-2687
Polyaryl esters of moderate molecular weights were prepared by the direct polycondensation reaction of hydroxybenzoic acids and its derivatives with hexachlorocyclotriphosphatriazene (also known as phosphonitrilic chloride trimer, PNC) as a condensing agent in pyridine. Copolymerization of p-hydroxybenzoic acid with several hydroxybenzic acid derivatives was carried out to improve the processability of the polymer of p-hydroxybenzoic acid, which yields fusible and soluble copolymers of high inherent viscosities. Polymer solubility and thermal behavior were examined. 相似文献
13.
Koichi Tokuda Tatsuro Gueshi Hiroaki Matsuda 《Journal of Electroanalytical Chemistry》1979,102(1):41-48
Faradaic, impedances at model electrodes partially covered with a photoresist layer have been studied theoretically and experimentally. Equations for the faradaic impedance are derived based on the theoretical model and approach described in Part I of this series of papers. Experimental data for the hexacyanoferrate system at various model electrodes give excellent agreement, with theoretical predictions for the diffusion impedance behavior, and the applicability of the derived equations to the estimation of the degree of coverage and the size of the active regions is confirmed. Furthermore, the application of such model electrodes to the kinetic study of electrode reactions with high heterogeneous charge transfer rates is suggested. 相似文献
14.
Yasushi Joh Koichi Harada Heimei Yuki Shunsuke Murahashi 《Journal of polymer science. Part A, Polymer chemistry》1971,9(4):1089-1102
The polymerization of isobutyl vinyl ether by vanadium trichloride in n-heptane was studied. VCl3 ? LiCl was prepared by the reduction of VCl4 with stoichiometric amounts of BuLi. This type of catalyst induces stereospecific polymerization of isobutyl vinyl ether without the action of trialkyl aluminum to an isotactic polymer when a rise in temperature during the polymerization was depressed by cooling. It is suggested that the cause of the stereospecific polymerization might be due to the catalyst structure in which LiCl coexists with VCl3, namely, VCl3 ? LiCl or VCl2 ? 2LiCl as a solid solution in the crystalline lattice, since VCl3 prepared by thermal decomposition of VCl4 and a commercial VCl3 did not produce the crystalline polymer and soluble catalysts such as VCl4 in heptane and VCl3 ? LiCl in ether solution did not yield the stereospecific polymer. It was found that some additives, such as tetrahydrofuran or ethylene glycol diphenyl ether, to the catalyst increased the stereospecific polymerization activity of the catalysts. Influence of the polymerization conditions such as temperature, time, monomer and catalyst concentrations, and the kind of solvent on the formed polymer was also examined. 相似文献
15.
Takuo Kosuge Kuniro Tsuji Koichi Hirai Kentaro Yamaguchi Toshihiko Okamoto Yoichi Iitaka 《Tetrahedron letters》1981,22(35):3417-3420
A new toxin, named neosurugatoxin, was isolated from the toxic Japanese Ivory Shell and its structure was determined by X-ray crystallographic analysis. 相似文献
16.
The kinetics of the flattening of surface corrugations of float glasses were investigated in dry nitrogen at 610 to 670°C. The amplitude of the sinusoidal surface profile decayed exponentially with time while its wavelength remained constant. The dependence of decay rate on wavelength indicated that the process is controlled by the viscous flow. From the obtained rate constant the viscosity was calculated using the surface energy value determined independently by the zero-creep method. The viscosity thus obtained reflects the mass transport property in the vicinity of the glass surface. It was several times larger than that determined by the fibre elongation or intrusion method which should reflect the bulk properties. No difference in the decay rate was observed on both the surfaces of float glass of which only one side had been exposed to molten tin during the glass manufacturing process. 相似文献
17.
Masayuki Hagiwara Shojiro Kimura Haruhiko Yashiro Takanari Kashiwagi Hironori Yamaguchi Koichi Kindo 《Applied magnetic resonance》2009,36(2-4):269-274
We have developed high-field and multifrequency (HFMF) electron spin resonance (ESR) apparatus for the magnetic fields up to 65 T at frequencies up to about 6 THz. In addition to this pulsed field ESR apparatus, we are making a multifrequency ESR apparatus with very high sensitivity in a static field. We report the results of ESR studies on BaCoV2O8 and NiGa2S4, followed by recent developments and future plans of our HFMF ESR apparatus. 相似文献
18.
19.
Koichi Watanabe 《Crystal Research and Technology》1995,30(1):49-54
Single crystals of corundum were grown by the top-seeded solution growth technique from a cryolite, Na3AlF6, solvent. The relationship between the growth rate (mg/h) of a crystal and the temperature difference (= supersaturation) or the rotation rate of a seed crystal was investigated, and optimum growth conditions for obtaining single crystals with good quality are discussed. 相似文献
20.