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11.
Klyba L. V. Nedolya N. A. Tarasova O. A. Zhanchipova E. R. 《Russian Journal of Organic Chemistry》2009,45(2):292-303
Russian Journal of Organic Chemistry - Mass spectra of 3,7-di- and 3,6,7-trisubstituted 2-(methylsulfanyl)-4,5-dihydro-3H-azepines were investigated for the first time. The fragmentation of... 相似文献
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E. P. Levanova V. S. Vakhrina V. A. Grabel’nykh I. B. Rozentsveig N. V. Russavskaya A. I. Albanov L. V. Klyba N. A. Korchevin 《Russian Chemical Bulletin》2015,64(9):2083-2089
A reaction of organic dichalcogenides R2Y2 (R = Ph, Bn, Pr; Y = S, Se) with 1,4-dichlorobut-2-yne in the system hydrazine hydrate–KOH leads to four principal products: 1,4-bis(organylchalcogenyl)but-2-ynes, 1-organylchalcogenylbut-1-en-3-ynes, 4-organylchalcogenylbut-1-en-3-ynes, and 3(5)-methylpyrazole. The selectivity of the formation of individual products is determined by the ratio of the substrates used and the reaction temperature. A plausible mechanism of chalcogenation considered in the work agrees with the effect of the nature of chalcogene atoms and organic substituents R on stability of intermediates and products. The stabilization of carbanions by α chalcogene-containing groups corresponds to the following order: PhS > PhSe > BnS > BnSe > PrS. 相似文献
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L. V. Klyba N. A. Nedolya E. R. Sanzheeva O. A. Tarasova 《Russian Journal of Organic Chemistry》2018,54(8):1184-1188
For the first time decomposition was investigated of 4-alkoxy-5-amino-3-methylthiophene-2-carbonitriles under the conditions of electronic (70 eV) and chemical (reagent gas methane) ionization. At the electronic ionization the compounds under study [except for 4-(1-ethoxyethoxy) and 4-(ferrocenylmethoxy) derivatives] form stable molecular ions that decompose mainly by the cleavage of an alkyl radical from the alkoxy-substituent. Further fragmentation of the arising ion [M–Alk]+ depends on the substituent nature in the amino group. In the mass spectrum of 4-(ferrocenylmethoxy)-substituted thiophene peaks of the ion [FcCH2]+ and its fragmentation products prevail. In the mass spectra of chemical ionization predominant peaks belong to ions M+·, [M + H]+ and [M + C2H5]+, and fragment ions are absent. 相似文献
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G. V. Bozhenkov V. A. Savosik E. V. Rudyakova Kha Kuok Khan’ A. I. Albanov L. V. Klyba A. N. Mirskova G. G. Levkovskaya 《Russian Journal of Organic Chemistry》2008,44(12):1745-1751
The reaction of chloroacetyl chloride with 1,2-dichloroethene in the presence of AlCl3 unexpectedly led to the formation of (E)-1,1,4-trichlorobut-3-en-2-one whose structure was proved by 1H and 13C NMR, IR, and mass spectra and independent synthesis. A probable reaction scheme was proposed, which involves transformation of initially formed 1,2,4-trichloro-3-oxobutan-2-yl cation by the action of AlCl3. The high reactivity of the vinylic halogen atom in (E)-1,1,4-trichlorobut-3-en-2-one was demonstrated by its reactions with nitrogen-centered nucleophiles (triethylamine, aniline, 3,5-dimethyl-1H-pyrazole) and sodium sulfide. These reactions involved only the C-Cl bond in the vinyl fragment and afforded (4,4-dichloro-3-oxobut-2-en-1-yl)triethylammonium chloride, 1,1-dichloro-4-phenylaminobut-3-en-2-one, 1-(4,4-dichloro-3-oxobut-2-en-1-yl)-3,5-dimethyl-1H-pyrazole, and 4,4′-thiobis(1,1-dichlorobut-3-en-2-one), respectively. The reaction of 1,1,4-trichlorobut-3-en-2-one with benzylhydrazine gave a mixture of 1,3- and 1,5-disubstituted pyrazoles. 相似文献
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M. G. Voronkov L. V. Klyba S. V. Basenko R. G. Mirskov V. N. Bochkarev 《Russian Chemical Bulletin》1999,48(1):114-116
The mass spectra of some linear and branched methyl(vinyl)siloxanes Me3SiOSi(Me)(R)(OSiMeVin)
n
Y (R=Vin, OSiMe3; Y=OSiMe3, Cl;n=0–2) were studied. The regularities of their fragmentation and an anomalously high probability of elimination of the ethylene
molecule to form the stable 1,3-dioxa-2,4,6-trisilacyclohexane skeleton were revealed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 113–115, January, 1999. 相似文献
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E. P. Levanova V. A. Grabel’nykh N. V. Russavskaya L. V. Klyba E. R. Zhanchipova A. I. Albanov O. A. Tarasova N. A. Korchevin 《Russian Journal of General Chemistry》2009,79(6):1097-1101
2,3-Dichloro-1-propene reacts with sulfur dissolved in the system hydrazine hydrate-KOH (with formation of K2S2 or K2S) to afford bis(2-chloro-1-propene-3-yl)sulfide as the main product in both cases. Under similar conditions tellurium induces β-elimination of both chlorine atoms resulting in the formation of allene and complete regeneration of tellurium metal. 相似文献
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B. A. Trofimov G. F. Myachina T. G. Ermakova N. P. Kuznetsova L. I. Volkova R. G. Sultangareev L. I. Larina L. V. Klyba G. T. Sukhanov G. V. Sakovich 《Russian Journal of Organic Chemistry》2009,45(11):1683-1685
A new catalyst was developed for the synthesis of 2-phenyl-1,2,3-triazole: copper triflate Cu(OSO2CF3)2. The process of cyclization of glyoxal phenylosazone in the presence of Cu(OSO2CF3)2 was optimized that made it possible to increase the yield of the target product to 82%. 相似文献