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71.
We report on the formation of a metal-molecule complex that can be used as a molecular switch. Using a cryogenic scanning tunneling microscope, a covalent bond was formed reversibly between a gold atom and a perylene-3,4,9,10-tetracarboxylic dianhydride molecule supported by a thin insulating film. The bonded and the nonbonded state of the complex were found to be associated with different charge states, and the switching between the two states was accompanied by a considerable change in the tunneling current. Atomic force microscopy molecular imaging was employed to determine precisely the atomic structure of the complex, and the experimental results were corroborated by density functional theory calculations. 相似文献
72.
Dariusz Dereniowski Öznur Yaşar Diner Danny Dyer 《Discrete Applied Mathematics》2013,161(13-14):1950-1958
73.
Dyer HE Huijser S Schwarz AD Wang C Duchateau R Mountford P 《Dalton transactions (Cambridge, England : 2003)》2008,(1):32-35
The reaction of Sm{N(SiMe3)2}3 with the bis(phenol)amines H2O2N(R) (H2O2N(R) = RCH2CH2N(2-HO-3,5-C6H2(t)Bu2)2; R = OMe, NMe2 or Me) gave exclusively zwitterions Sm(O2N(R))(HO2N(R)). For R = OMe or NMe2 these were efficient catalysts for the ring-opening polymerisation of epsilon-caprolactone and D,L-lactide with a tendency to form cyclic esters; in contrast, no polymerisation was observed for R = Me. 相似文献
74.
75.
Saito H Sivaguru J Jockusch S Dyer J Inoue Y Adam W Turro NJ 《Chemical communications (Cambridge, England)》2007,(8):819-821
Photoisomerization of encapsulated Z-enecarbamates within the hydrophobic chiral cavities of gamma-CD showed higher diastereoselectivities in the photoproducts than those obtained in solution. The selective encapsulation of the enecarbamates and the following isomerization process are both diastereoselectively controlled by gamma-CD. 相似文献
76.
The orientation-dependent pair distribution function for molecular fluids on site-site potentials is expanded in a topological analog of the diagrammatically proper site-site theory of liquids [D. Chandler et al., Mol. Phys. 46, 1335 (1982)]. The resulting functions are then used to diagrammatically renormalize the molecular fluid theory. A result is that the diagrammatically proper interaction site model theory is shown to be a linearized, minimal angular basis set approximation to this site-renormalized molecular theory. This framework is used to propose a new, exact, and proper closure to the diagrammatically proper interaction site model theory. The resulting equation system contains a bridge function expansion in the proper site-site theory. In addition, the construction of the theory is such that the molecular pair distribution function, in full dimensionality, is intrinsic to the theory. Furthermore, the theory is equivalent to the molecular Ornstein-Zernike treatment of site-site molecules in the basis set expansion of Blum and Torruella [J. Chem. Phys. 56, 303 (1971)]. A significant formal result of the theory is the demonstration that certain classes of diagrams which would otherwise be considered improper in the interaction site model formalism are included in the angular expansion of molecular interactions. Numerical results for several apolar homonuclear models and an apolar heteronuclear model are shown to quantitatively improve upon those of reference interaction site model and our recent proper variant with respect to simulation. Significant numerical results are that the various thermodynamic quantities obey the exact symmetries and sum rules within numerical error for the different sites in the heteronuclear case, even for the low order approximation used in this work, and the theory is independent of the so-called auxiliary site problem common to previous site-site theories. 相似文献
77.
Path coupling is a useful technique for simplifying the analysis of a coupling of a Markov chain. Rather than defining and analysing the coupling on every pair in Ω×Ω, where Ω is the state space of the Markov chain, analysis is done on a smaller set SΩ×Ω. If the coefficient of contraction β is strictly less than one, no further analysis is needed in order to show rapid mixing. However, if β=1 then analysis (of the variance) is still required for all pairs in Ω×Ω. In this paper we present a new approach which shows rapid mixing in the case β=1 with a further condition which only needs to be checked for pairs in S, greatly simplifying the work involved. We also present a technique applicable when β=1 and our condition is not met. 相似文献
78.
The influence of key sol-gel synthesis parameters on the pore structure of microporous silica xerogels was investigated. The silica xerogels were prepared using an acid-catalyzed aqueous sol-gel process, with tetraethoxysilane (TEOS) as the silicon-containing precursor. At high H2O : TEOS ratios, sols synthesized at pH 2–3 yielded minimum values of mean micropore diameter and micropore volume. Analysis of the resulting Type I nitrogen adsorption isotherms and the equilibrium adsorption of N(C4F9)3 indicated micropore diameters for these xerogels of less than approximately 10 Å.Xerogel micropore volumes corresponding to sols prepared at pH 3 and an H2O : TEOS ratio of r = 83 were consistent with nearly close packing of silica spheres in the xerogel. Xerogel microstructure was only weakly dependent upon H2O : TEOS ratio during sol synthesis for r > 10. Xerogel micropore volume increased rapidly with sol aging time during an initial induction period of particle formation. However, the xerogel microstructure changed only slowly with time after this initial period, suggesting potential processing advantages for the particulate sol-gel route to porous silica materials.Surface adsorption properties of the silica xerogels were investigated at ambient temperature using N2, SF6, and CO2. CO2 adsorbed most strongly, SF6 also showed measurable adsorption, and N2 adsorption was nearly zero. These results were consistent with the surface transport of CO2, and to a lesser extent SF6, observed in gas permeation studies performed through thin membrane films cast from similarly prepared silica sols. 相似文献
79.
Various strategies are being pursued to confer the highly specific molecular recognition properties of bioactive molecules to the transducer action of inherently conductive polymers. We have successfully integrated inherently conductive polypyrrole within electrode-supported, UV cross-linked hydroxyethyl methacrylate (HEMA)-based hydrogels. These electroactive composites were used as matrixes for the physical immobilization of several oxidase enzymes to fabricate clinically important biosensors. Measurements were made of the amperometric responses via H2O2 oxidation for each biosensor. Apparent Michaelis constants, Km(app), for glucose oxidase immobilized in p(HEMA) membranes and in p(HEMA)/p(Pyrrole) composite membranes were 13.8 and 43.7 mM respectively compared to 33 mM in solution. The inclusion of polypyrrole in the hydrogel network increased the thermal stability of the immobilized enzyme at 60°C by 30% and 40% compared to p(HEMA) membranes and solution phase respectively. The composite also yielded larger Imax values (19 μA/cm−2) for glucose biosensors compared to similar glucose biosensors fabricated without the conducting polymer (15 μA). Km(app) values for cholesterol oxidase immobilized in the same composite films were ca. three orders of magnitude higher than the Km for the soluble enzyme. The polypyrrole component is shown to reduce diffusive transport but to confer thermal stability to these biosensors. 相似文献
80.
P. E. Dyer C. D. Walton R. Zakaria 《Applied Physics A: Materials Science & Processing》2009,95(2):319-323
Conical structures formed in 157 nm laser-ablated polycarbonate exhibit a well-defined fringe structure with a period of a
few 100 nm surrounding the cone base. Experiments and modelling studies of the interference produced by these micro-conical
mirrors are shown to provide a means of measuring the spatial coherence of the highly multi-mode 157 nm laser. 相似文献