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131.
Stuart J. Allen Kenneth A. Kline 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1968,19(3):425-433
Zusammenfassung Die Grundgleichungen für eine lineare Theorie der Flüssigkeiten mit starker Konzentration suspendierter Partikel werden auf das Problem der geradlinigen Strömung mit Flüssigkeitsreibung zwischen zwei Platten angewandt. Es werden die Geschwindigkeit, die Partikeldeformation und die Spannungen bestimmt. 相似文献
132.
133.
Chabinyc ML Toney MF Kline RJ McCulloch I Heeney M 《Journal of the American Chemical Society》2007,129(11):3226-3237
Poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2-b]thiophene), PBTTT, is a semiconducting polymer that forms thin film transistors (TFTs) with high field effect mobility on silicon dioxide dielectrics that are treated with alkyltrichlorosilanes ( approximately 0.2 to 0.5 cm2/V s) but forms TFTs with poor mobility on bare silicon dioxide (<0.005 cm2/V s). The microstructure of spin-coated thin films of PBTTT on these surfaces was studied using synchrotron X-ray diffraction and atomic force microscopy. PBTTT crystallizes with lamellae of pi-stacked polymer chains on both surfaces. The crystalline domains are well-oriented relative to the substrate in the as-spun state and become highly oriented and more ordered with thermal annealing in the liquid crystalline mesophase. Although the X-ray scattering from PBTTT is nearly identical on both surfaces, atomic force microscopy showed that the domain size of the crystalline regions depends on the substrate surface. These results suggest that electrical transport in PBTTT films is strongly affected by the domain size of the crystalline regions and the disordered regions between them. 相似文献
134.
Hydrazine fuels for bimetallic catalytic microfluidic pumping 总被引:1,自引:0,他引:1
Ibele ME Wang Y Kline TR Mallouk TE Sen A 《Journal of the American Chemical Society》2007,129(25):7762-7763
135.
Kumari H Kline SR Schuster NJ Barnes CL Atwood JL 《Journal of the American Chemical Society》2011,133(45):18102-18105
Small-angle neutron scattering (SANS) studies were used to probe the stability and geometry of copper-seamed C-alkylpyrogallol[4]arene (PgC(n)Cu; n = 11, 13, 17) hexamers in solution. Novel structural features are observed at chain lengths greater than 10 in both solid and solution phase. Scattering data for the PgC(11)Cu and PgC(13)Cu in chloroform fitted as core-shell spheres with a total spherical radius of about 22.7 and 22.9 ? respectively. On the other hand, the scattering curve for the PgC(17)Cu hexamer at both 1% and 5% mass fractions in o-xylene did not fit as a discrete sphere but rather as a uniform ellipsoid. The geometric dimensions of the ellipsoid radii are 24 ? along the minor axis and 115 ? along the major axis. It is expected that an individual hexamer with heptadecyl chains would exhibit a uniform radius of ca. 24 ?. However, an approximate ratio of 1:5 between radii lengths for the minor axis and major axis is consistent with interpenetration of the heptadceyl chains of adjacent hexamers to form a single ellipsoidal assembly. 相似文献
136.
Zhang X Richter LJ DeLongchamp DM Kline RJ Hammond MR McCulloch I Heeney M Ashraf RS Smith JN Anthopoulos TD Schroeder B Geerts YH Fischer DA Toney MF 《Journal of the American Chemical Society》2011,133(38):15073-15084
We describe a series of highly soluble diketo pyrrolo-pyrrole (DPP)-bithiophene copolymers exhibiting field effect hole mobilities up to 0.74 cm(2) V(-1) s(-1), with a common synthetic motif of bulky 2-octyldodecyl side groups on the conjugated backbone. Spectroscopy, diffraction, and microscopy measurements reveal a transition in molecular packing behavior from a preferentially edge-on orientation of the conjugated plane to a preferentially face-on orientation as the attachment density of the side chains increases. Thermal annealing generally reduces both the face-on population and the misoriented edge-on domains. The highest hole mobilities of this series were obtained from edge-on molecular packing and in-plane liquid-crystalline texture, but films with a bimodal orientation distribution and no discernible in-plane texture exhibited surprisingly comparable mobilities. The high hole mobility may therefore arise from the molecular packing feature common to the entire polymer series: backbones that are strictly oriented parallel to the substrate plane and coplanar with other backbones in the same layer. 相似文献
137.
Edington C Murata H Koepsel R Andersen J Eom S Kanade T Balazs AC Kolmakov G Kline C McKeel D Liron Z Russell AJ 《Langmuir : the ACS journal of surfaces and colloids》2011,27(24):15345-15351
Cell separation technology is a key tool for biological studies and medical diagnostics that relies primarily on chemical labeling to identify particular phenotypes. An emergent method of sorting cells based on differential rolling on chemically patterned substrates holds potential benefits over existing technologies, but the underlying mechanisms being exploited are not well characterized. In order to better understand cell rolling on complex surfaces, a microfluidic device with chemically patterned stripes of the cell adhesion molecule P-selectin was designed. The behavior of HL-60 cells rolling under flow was analyzed using a high-resolution visual tracking system. This behavior was then correlated to a number of established predictive models. The combination of computational modeling and widely available fabrication techniques described herein represents a crucial step toward the successful development of continuous, label-free methods of cell separation based on rolling adhesion. 相似文献
138.
Kline JL Glenzer SH Olson RE Suter LJ Widmann K Callahan DA Dixit SN Thomas CA Hinkel DE Williams EA Moore AS Celeste J Dewald E Hsing WW Warrick A Atherton J Azevedo S Beeler R Berger R Conder A Divol L Haynam CA Kalantar DH Kauffman R Kyrala GA Kilkenny J Liebman J Le Pape S Larson D Meezan NB Michel P Moody J Rosen MD Schneider MB Van Wonterghem B Wallace RJ Young BK Landen OL MacGowan BJ 《Physical review letters》2011,106(8):085003
The first soft x-ray radiation flux measurements from hohlraums using both a 96 and a 192 beam configuration at the National Ignition Facility have shown high x-ray conversion efficiencies of ~85%-90%. These experiments employed gold vacuum hohlraums, 6.4 mm long and 3.55 mm in diameter, heated with laser energies between 150-635 kJ. The hohlraums reached radiation temperatures of up to 340 eV. These hohlraums for the first time reached coronal plasma conditions sufficient for two-electron processes and coronal heat conduction to be important for determining the radiation drive. 相似文献
139.
This article describes plug-based microfluidic technology that enables rapid detection and drug susceptibility screening of bacteria in samples, including complex biological matrices, without pre-incubation. Unlike conventional bacterial culture and detection methods, which rely on incubation of a sample to increase the concentration of bacteria to detectable levels, this method confines individual bacteria into droplets nanoliters in volume. When single cells are confined into plugs of small volume such that the loading is less than one bacterium per plug, the detection time is proportional to plug volume. Confinement increases cell density and allows released molecules to accumulate around the cell, eliminating the pre-incubation step and reducing the time required to detect the bacteria. We refer to this approach as 'stochastic confinement'. Using the microfluidic hybrid method, this technology was used to determine the antibiogram - or chart of antibiotic sensitivity - of methicillin-resistant Staphylococcus aureus (MRSA) to many antibiotics in a single experiment and to measure the minimal inhibitory concentration (MIC) of the drug cefoxitin (CFX) against this strain. In addition, this technology was used to distinguish between sensitive and resistant strains of S. aureus in samples of human blood plasma. High-throughput microfluidic techniques combined with single-cell measurements also enable multiple tests to be performed simultaneously on a single sample containing bacteria. This technology may provide a method of rapid and effective patient-specific treatment of bacterial infections and could be extended to a variety of applications that require multiple functional tests of bacterial samples on reduced timescales. 相似文献
140.
Wang Y Hernandez RM Bartlett DJ Bingham JM Kline TR Sen A Mallouk TE 《Langmuir : the ACS journal of surfaces and colloids》2006,22(25):10451-10456
Bimetallic nanorods are propelled in aqueous solutions by the catalytic decomposition of hydrogen peroxide to oxygen and water. Several mechanisms (interfacial tension gradients, bubble recoil, viscous Brownian ratchet, self-electrophoresis) have been proposed for the transduction of chemical to mechanical energy in this system. From Tafel plots of anodic and cathodic hydrogen peroxide reactions at various metal (Au, Pt, Rh, Ni, Ru, and Pd) ultramicroelectrodes, we determine the potential at which the anodic and cathodic reaction rates are equal for each metal. These measurements allow one to predict the direction of motion of all possible bimetallic combinations according to the bipolar electrochemical (or self-electrophoretic) mechanism. These predictions are consistent with the observed direction of motion in all cases studied, providing strong support for the mechanism. We also find that segmented nanorods with one Au end and one poly(pyrrole) end containing catalase, an enzyme that decomposes hydrogen peroxide nonelectrochemically, perform the overall catalytic reaction at a rate similar to that of nanorods containing Au and Pt segments. However, in this case there is no observed axial movement, again supporting the bipolar electrochemical propulsion mechanism for bimetallic nanorods. 相似文献