Bildung von Mischkristallen bei Verbindungen vom Huréaulith-Typ

We investigated to what an extent mixed crystals of phosphates (arsenates) of Mn and Cd, [M₅(HPO₄)₂(PO₄)₂ · 4 H₂O], with Fe(II), Co, Ni, Zn and Cu can be formed.     

Refining of Diesel and Ship Fuels by Extraction and Combined Methods. Part 1. Use of Ionic Liquids as Extractants

Russian Journal of Applied Chemistry - Modern and perspective environmental requirements to the quality of diesel and ship fuels are considered. Data on the selectivity and solvency of ionic...     

Potential use of deep eutectic solvents to facilitate lignocellulosic biomass utilization and conversion

High reliance on crude oil for energy consumption results in the urgent need to explore and develop alternative renewable sources. One of the most promising routes is the transformation of biomass into biofuels and chemicals. The introduction of deep eutectic solvents in 2004 received a considerable amount of attention across different research fields, particularly in biomass processing. The effectiveness of deep eutectic solvents in breaking down the recalcitrant structure in biomass highlights its impact on the transformation of biomass into various value-added products. In addition, deep eutectic solvents are widely regarded as promising “green” solvents due to their low cost, low toxicity, and biodegradable properties. In this paper, some background information on lignocellulosic biomass and deep eutectic solvents is given. Furthermore, the roles of deep eutectic solvents in biomass processing are discussed, focusing on the impacts of deep eutectic solvents on the selectivity of chemical processes and dissolution of biomass. This review also highlights the advantages and limitations of deep eutectic solvents associated with their usage in biomass valorization.     

A Dynamic Systems Approach to Understanding Reaching Movements with a Prosthetic Arm

A case study was conducted on an experienced upper extremity prosthetic user that required him to perform a reaching and grasping task with both his prosthetic and normal anatomical hand. We used a scanning task (Wallace, Stevenson, Spear, & Weeks, 1994; Button, Bennett, & Davids, 1998) that required the participant to perform a wide range of coordination patterns defined by the relative phasing between the aperture of the fingers (or artificial prehensor) and the arm. Visual templates of the required finger trajectories in the various required phase conditions served as environmental information for the subject to follow. Based on previous work, we hypothesized that the participant would exhibit at least one stable reaching and grasping pattern in both his anatomical and prosthetic arm. In support of this hypothesis, the results showed a negative sloping relationship between the required relative phase and the mean delta relative phase (required relative phase minus the actual relative phase). The smallest delta relative phase occurred at approximately 80° and 115° relative phase for the anatomical and prosthetic arm, respectively during the scanning task. These results confirm our previous work of the presence of only one attractor in reaching and grasping movements using either the anatomical or prosthetic arm.     

Noninvasive Assessment of UV-induced Skin Damage: Comparison of Optical Measurements to Histology and MMP Expression

Acute exposure to UV radiation (UVR) causes visible skin damage such as erythema and results in local and systemic immunosuppression while chronic exposure can result in photocarcinogenesis. These deleterious effects can be quantified by histology and by bioassays of key biological markers, including matrix metalloproteinases (MMPs), or tryptophan moieties. We now report our results in quantifying UV skin damage with noninvasive optical methods based on reflectance and fluorescence spectroscopy and compare these noninvasive measurements to histopathology and MMP-13 expression. A solar simulator with spectral output nearly identical to that of solar radiation was developed and used in our experiments. SKH1 hairless mice were exposed to solar-simulated UVR at a total dose of 21 MED delivered over 10 weeks. Changes in oxygenated and deoxygenated hemoglobin were measured by diffuse reflectance spectroscopy, and tryptophan changes were monitored via a fluorescence monitor. Our results show that there is an increase in erythema, skin fluorescence, sunburn cells and MMP-13 after a series of suberythemal doses of UV irradiation on a hairless mouse animal model. Increased skin fluorescence is observed with increasing UV exposure. The levels of MMP-13 increase as the cumulative UV dose increases but their increase does not correspond to noninvasively measured changes.     

Decontamination of textile wastewater via TiO2/activated carbon composite materials

Water scarcity and pollution rank equal to climate change as the most urgent environmental turmoil for the 21st century. To date, the percolation of textile effluents into the waterways and aquifer systems, remain an intricate conundrum abroad the nations. With the renaissance of activated carbon, there has been a steadily growing interest in the research field. Recently, the adoption of titanium dioxide, a prestigious advanced photo-catalyst which formulates the new growing branch of activated carbon composites for enhancement of adsorption rate and discoloration capacity, has attracted stern consideration and supports worldwide. Confirming the assertion, this paper presents a state of art review of titanium dioxide/activated carbon composites technology, its fundamental background studies, and environmental implications. Moreover, its major challenges together with the future expectation are summarized and discussed. Conclusively, the expanding of activated carbons composites material represents a potentially viable and powerful tool, leading to the plausible improvement of environmental conservation.     

Diastereoselective formation of a dipalladium(I) complex supported by a bridging tetradentate ligand,and oxidative addition of RS-H across a phosphine-bridged Pd(I)-Pd(I) bond

The ligand CH2(P(o-C6H4NMe2)2)2 (dmapm) gives access to the first example of a dipalladium(I) complex supported by a tetradentate ligand, Pd2Cl2(mu-N,P,P,N-dmapm), which, unlike the well-known Pd2X2(mu-dppm)2 complexes (X = halide, dppm = bis(diphenylphosphino)methane), reacts with thiols to give addition of RS-H across a phosphine-bridged Pd-Pd bond.