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71.
The title compound crystallizes in the orthorhombic space group P212121 with 4 formula units C18H26O2 in the unit cell. The lattice constants are a = 10.356(2) Å, b = 19.743(3) Å, and c = 7.487(1) Å. The structure was solved by direct methods of phases determination and refined by least-squares calculations to the conventional R = 0.054. The configuration and conformation of the molecule were determined and compared with those of Δ-8,14-anhydrodigitoxigenin. 相似文献
72.
Volker Schubert 《Nachrichten aus der Chemie》1992,40(12):1339-1339
73.
Electrical and photoelectrical properties of IR-devices manufactured on (Hg, Cd)Te-wafers cut from single crystals grown by modified Bridgman method are reported and compared to those of devices made on THM-(Hg, Cd)Te. MIS-structures and photodiodes were used in order to investigate the different materials. The influence of material parameters and device technology respectively is involved in our discussion of device properties. The quality of modified Bridgman-(Hg, Cd)Te was found to be comparable to that of the THM-(Hg, Cd)Te. At T = 80 K and FOV = 60° background limited detectivity of photodiodes with a cut-off wavelength of λco = 10.7 μm was achieved. 相似文献
74.
Two new marine sediment standard reference materials (SRMs) for the determination of organic contaminants 总被引:3,自引:0,他引:3
Wise SA Poster DL Schantz MM Kucklick JR Sander LC Lopez de Alda M Schubert P Parris RM Porter BJ 《Analytical and bioanalytical chemistry》2004,378(5):1251-1264
Two new marine sediment standard reference materials (SRMs), SRM 1941b Organics in Marine Sediment and SRM 1944 New York/New Jersey Waterway Sediment, have been recently issued by the National Institute of Standards and Technology (NIST) for the determination of organic contaminants including polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyl (PCB) congeners, and chlorinated pesticides. Both sediment SRMs were analyzed using multiple analytical methods including gas chromatography/mass spectrometry (GC/MS) on columns with different selectivity, reversed-phase liquid chromatography with fluorescence detection (for PAHs only), and GC with electron capture detection (for PCBs and pesticides only). SRM 1941b has certified concentrations for 24 PAHs, 29 PCB congeners, and 7 pesticides, and SRM 1944 has certified concentrations for 24 PAHs, 29 PCB congeners, and 4 pesticides. Reference concentrations are also provided for an additional 58 (SRM 1941b) and 39 (SRM 1944) PAHs, PCB congeners, and pesticides. SRM 1944, which was collected from multiple sites within New York/New Jersey coastal waterways, has contaminant concentrations that are generally a factor of 10–20 greater than SRM 1941b, which was collected in the Baltimore (Maryland) harbor. These two SRMs represent the most extensively characterized marine sediment certified reference materials available for the determination of organic contaminants.Electronic Supplementary Material Supplementary material is available in the online version of this article at . A link in the frame on the left on that page takes you directly to the supplementary material. 相似文献
75.
Johan Schubert 《International Journal of Approximate Reasoning》2012,53(2):176-189
We construct alternative frames of discernment from input belief functions. We assume that the core of each belief function is a subset of a so far unconstructed frame of discernment. The alternative frames are constructed as different cross products of unions of different cores. With the frames constructed the belief functions are combined for each alternative frame. The appropriateness of each frame is evaluated in two ways: (i) we measure the aggregated uncertainty (an entropy measure) of the combined belief functions for that frame to find if the belief functions are interacting in interesting ways, (ii) we measure the conflict in Dempster’s rule when combining the belief functions to make sure they do not exhibit too much internal conflict. A small frame typically yields a small aggregated uncertainty but a large conflict, and vice versa. The most appropriate frame of discernment is that which minimizes a probabilistic sum of the conflict and a normalized aggregated uncertainty of all combined belief functions for that frame of discernment. 相似文献
76.
In this Letter, we introduce a method of calculating the optimal wafer thickness for silicon solar cells with multicrystalline bulk material. The optimal thickness depends on the relation of bulk recombination to surface recombination and the light trapping. For multicrystalline silicon bulk recombination strongly varies laterally and with injection level, which complicates the calculations. A thickness optimization using the “Efficiency Limiting Bulk Recombination Analysis” (ELBA) takes all these effects correctly into account. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
77.
Holger Fehske Gerald Schubert Gerhard Wellein Alan R. Bishop 《Physics letters. A》2009,373(25):2182-2188
We examine several numerical techniques for the calculation of the dynamics of quantum systems. In particular, we single out an iterative method which is based on expanding the time evolution operator into a finite series of Chebyshev polynomials. The Chebyshev approach benefits from two advantages over the standard time-integration Crank-Nicholson scheme: speedup and efficiency. Potential competitors are semiclassical methods such as the Wigner-Moyal or quantum tomographic approaches. We outline the basic concepts of these techniques and benchmark their performance against the Chebyshev approach by monitoring the time evolution of a Gaussian wave packet in restricted one-dimensional (1D) geometries. Thereby the focus is on tunnelling processes and the motion in anharmonic potentials. Finally we apply the prominent Chebyshev technique to two highly non-trivial problems of current interest: (i) the injection of a particle in a disordered 2D graphene nanoribbon and (ii) the spatiotemporal evolution of polaron states in finite quantum systems. Here, depending on the disorder/electron-phonon coupling strength and the device dimensions, we observe transmission or localisation of the matter wave. 相似文献
78.
79.
By applying diffraction grids to the detection surface the full vector content of the elastic wave field of ultrasonic transducers can be measured using common heterodyne interferometers. The signal to noise ratio is good enough to detect even small edge wave contributions to the elastic wave field. Numerical simulation of the elastic wave propagation by the elastodynamic finite integration technique helps to understand the origin of several field components observed in the measurements. 相似文献
80.
We demonstrate generalized ellipsometry for precise measurement of the principal indices of refraction, the extinction coefficients, and the orientations of the crystal a, b, and c axes of orthorhombic absorbing materials. Stibnite (Sb(2)S(3)) single crystals cut approximately parallel to (100), (010), (001), and (313) are studied at a representative wavelength of 589 nm. The (313) surface is sufficient for retrieval of all optical constants. The expected effects of surface over-layer formation are removed numerically. We propose generalized ellipsometry as a powerful tool for measurement of anisotropic optical function spectra of biaxial materials. 相似文献