Synthese von in 2-Stellung substituierten 2-Amino- und 3-Amino-1-indanonen

An examination has been made of the reaction of secondary amines with 2-bromo-1-indanones II substituted at position C-2, and with 2-substituted indenones III. 2-Bromo-2-methyl-1-indanone (IIa) and dimethylamine yielded a mixture of the corresponding 2- and 3-amino-methylindanones IVa and Va. 2-Bromo-2-methyl-6-chloro-1-indanone (II b) and morpholine gave a mixture of the 2- and 3-aminocompounds IVe and Ve.     

Der massenspektrometrische zerfall von naphthalin-2.1-diazooxid

The electron-impact-induced fragmentation of naphthalene-2,1-diazooxide shows the stepwise elimination of N₂ and CO like other α-diazoketones. From the mass spectrum of lh¹³C-naphthalene-2,1-diazooxide, it is concluded that no oxirene species participates in the [M ? N₂]⁺· ions.     

Zur Elektronenstoß-Induzierten Methylabspaltung aus Homoadamantan

¹³C labelling of position 4 in homoadamantane shows that in the electron impact induced elimination of CH₃ from the molecular ion each carbon atom of the CH₂-CH₂ bridge participates to the extent of 25%.     

Radioaktive Untersuchungen

Ohne Zusammenfassung