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101.
Christensen KE Bonneau C Gustafsson M Shi L Sun J Grins J Jansson K Sbille I Su BL Zou X 《Journal of the American Chemical Society》2008,130(12):3758-3759
We report a new open-framework silicogermanate SU-61 containing 26-ring channels with a low framework density. It can be seen as a crystalline analogue to the mesoporous silica MCM-41. The structure is built from the assembly of (Ge,Si)10(O,OH)28 clusters. It is the first time that silicon has been successfully introduced in the Ge10 cluster in significant amounts ( approximately 21% of the tetrahedral sites). Five- and six-coordinated Ge10 clusters have previously been observed in other germanate compounds leading to either dense or open structures. In SU-61, the seven-coordinated clusters fall onto yet another underlying net, the osf net. SU-61, along with other Ge10 based frameworks, shows the versatility of the germanate system to adopt defined topologies playing on the connectivity of the clusters following the principles of net decoration and scale chemistry. 相似文献
102.
In this paper we present the application of regressive models to simulation of car-to-pole impacts. Three models were investigated: RARMAX, ARMAX and AR. Their suitability to estimate physical system parameters as well as to reproduce car kinematics was examined. It was found out that they not only estimate the one quantity which was used for their creation (car acceleration) but also describe the car’s acceleration, velocity and crush. A virtual experiment was performed to obtain another set of data for use in further research. An AR model to predict the behavior of a low-speed car impacting a rigid barrier was created and verified. 相似文献
103.
The total syntheses of anithiactins A-C (1–3) and thiasporine A (4) have been achieved in good overall yields. The key reaction in the synthetic sequence was the Suzuki-Miyaura cross-coupling between 2-aminophenylboronic acid hydrochloride and methyl 2-bromothiazole-4-carboxylate forming the common intermediate methyl 2-(2-aminophenyl)thiazole-4-carboxylate (8), which could be further transformed by hydrolysis, alkylation, and aminolysis to give the four title natural products. This work represents the first total synthesis of anithiactin B (2) and C (3). 相似文献
104.
105.
Activation of crystalline cellulose surfaces through the chemoenzymatic modification of xyloglucan 总被引:6,自引:0,他引:6
Brumer H Zhou Q Baumann MJ Carlsson K Teeri TT 《Journal of the American Chemical Society》2004,126(18):5715-5721
Cellulose constitutes an important raw material for many industries. However, the superb load-bearing properties of cellulose are accompanied by poor chemical reactivity. The hydroxyl groups on cellulose surfaces can be reacted but usually not without loss of fiber integrity and strength. Here, we describe a novel chemoenzymatic approach for the efficient incorporation of chemical functionality onto cellulose surfaces. The modification is brought about by using a transglycosylating enzyme, xyloglucan endotranglycosylase, to join chemically modified xyloglucan oligosaccharides to xyloglucan, which has a naturally high affinity to cellulose. Binding of the chemically modified hemicellulose molecules can thus be used to attach a wide variety of chemical moieties without disruption of the individual fiber or fiber matrix. 相似文献
106.
The paper analyzes the efficiency of deploying false targets as part of a defense strategy. It is assumed that the defender has a single object that can be destroyed by the attacker. The defender distributes its resource between deploying false targets and protecting the object from outside attacks. The attacker cannot distinguish the false targets from the defended object (genuine target). Therefore the attacker has no preferences for attacking one target rather than another target. The defender decides how many false targets to deploy whereas the attacker decides how many targets to attack. The article assumes that both the defender and attacker have complete information and full rationality. The optimal number of false targets and the attacked targets are obtained for the case of fixed and variable resources of the defender and the attacker as solutions of a non-cooperative game between the two agents. 相似文献
107.
A system of independent components is defended by a strategic defender and attacked by a strategic attacker. The reliability of each component depends on how strongly it is defended and attacked, and on the intensity of the contest. In a series system, the attacker benefits from a substitution effect since attacker benefits flow from attacking any of the components, while the defender needs to defend all components. Even for a series system, when the attacker is sufficiently disadvantaged with high attack inefficiencies, and the intensity of the contest is sufficiently high, the defender earns maximum utility and the attacker earns zero utility. The results for the defender (attacker) in a parallel system are equivalent to the results for the attacker (defender) in a series system. Hence, the defender benefits from the substitution effect in parallel systems. With budget constraints the ratio of the investments for each component, and the contest success function for each component, are the same as without budget constraints when replacing the system values for the defender and attacker with their respective budget constraints. 相似文献
108.
G protein coupled receptors of the secretin family are activated by peptide hormones of about 30 residues in length. There is considerable sequence homology within both the hormone and receptor families. The receptors possess in addition to the integral membrane domain a characteristic extracellular domain of about 120 residues in length, having conserved cysteine residues, which are involved in disulphide bridge formation, and tryptophanes, which have been shown to be critical for hormone binding. This extracellular domain does not have detectable homology to any known protein fold. In order to be able to propose a structure for this domain we have used ab initio prediction methods combined with constraints based on experimental results for the disulphide connectivity. The results of computational tools for predicting secondary structure and accessibility, together with ligand binding and mutational data and other structural considerations were used in the ab initio protein folding programs DRAGON and GADGET and also the simpler program RAMBLE, which was able to explore different permutations of disulphide bond connectivity, tryptophan side chain orientation and chain topology. The methods generated a limited number of plausible models but no single unique solution was found under the constraints. One of these was refined into a full atomic model that contained a possible peptide binding site comprising the most conserved residues. 相似文献
109.
Elin E. Halvorsen-Weare Kjetil Fagerholt Lars Magne Nonås Bjørn Egil Asbjørnslett 《European Journal of Operational Research》2012
The supply vessel planning problem is a maritime transportation problem faced by amongst others the energy company Statoil. A set of offshore installations requires supplies from an onshore supply depot on a regular basis, a service performed by a fleet of offshore supply vessels. The problem consists of determining the optimal fleet composition of offshore supply vessels and their corresponding weekly voyages and schedules. We present a voyage-based solution method for the supply vessel planning problem. A computational study shows how the solution method can be used to solve real-life problems. Statoil has implemented a planning tool based on the voyage-based solution method and reports significant savings. 相似文献
110.
Sakhi AK Russnes KM Smeland S Blomhoff R Gundersen TE 《Journal of chromatography. A》2006,1104(1-2):179-189
A method for the simultaneous quantification of reduced and oxidized glutathione in human plasma employing a two-dimensional chromatographic system with parallel porous graphitized carbon (PGC) columns coupled with fluorescence (FLD) and coulometric electrochemical detection (ED) has been developed. Post-sampling oxidation of reduced glutathione (GSH) was prevented by derivatizing the -SH group with monobromobimane (MBB) and the glutathione-bimane adduct (GSMB) was detected by FLD. Oxidized glutathione (GSSG) was detected by ED optimized to give lowest possible limits of detection (LOD). The method is fully validated and is currently used for determination of GSH, GSSG and its redox potential in different clinical studies. 相似文献