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51.
Tairin Kawasaki Naoki Ishida Masahiro Murakami 《Angewandte Chemie (International ed. in English)》2020,59(41):18267-18271
A convenient method is reported to specifically acylate phenolic hydroxyl groups through a radical pathway. When a mixture of an aldehyde and a phenol in ethyl acetate is irradiated with blue light in the presence of iridium and nickel bromide catalysts at ambient temperature, phenoxyl and acyl radicals are transiently generated in situ and cross‐couple to furnish an ester. Aliphatic hydroxy groups remain untouched under the reaction conditions. 相似文献
52.
Adachi I Aihara H Arinstein K Asner DM Aushev T Aziz T Bakich AM Barberio E Belous K Bhardwaj V Bhuyan B Bondar A Bračko M Brodzicka J Browder TE Chang P Chen A Chen P Cheon BG Chilikin K Chistov R Cho IS Cho K Choi Y Dalseno J Danilov M Drásal Z Drutskoy A Eidelman S Epifanov D Esen S Fast JE Feindt M Gaur V Gabyshev N Garmash A Goh YM Golob B Hara T Hayasaka K Hayashii H Hoshi Y Hou WS Hsiung YB Hyun HJ Iijima T Ishikawa A Iwabuchi M Iwasaki Y Jaegle I Julius T Kang JH Katayama N Kawasaki T 《Physical review letters》2012,108(3):032001
We report the first observations of the spin-singlet bottomonium states h(b)(1P) and h(b)(2P). The states are produced in the reaction e(+)e(-)→h(b)(nP)π(+)π(-) using a 121.4 fb(-1) data sample collected at energies near the Υ(5S) resonance with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. We determine M[h(b)(1P)]=(9898.2(-1.0-1.1)(+1.1+1.0)) MeV/c(2) and M[h(b)(2P)]=(10,259.8±0.6(-1.0)(+1.4)) MeV/c(2), which correspond to P-wave hyperfine splittings ΔM(HF)=(+1.7±1.5) and (+0.5(-1.2)(+1.6)) MeV/c(2), respectively. The significances of the h(b)(1P) and h(b)(2P) are 5.5σ and 11.2σ, respectively. We find that the production of the h(b)(1P) and h(b)(2P) is not suppressed relative to the production of the Υ(1S), Υ(2S), and Υ(3S). 相似文献
53.
Satoshi Shogen Masahiro Kawasaki Toshihiro Kondo Yukari Sato Kohei Uosaki 《应用有机金属化学》1992,6(6):533-536
An angle-resolved X-ray photoelectron spectroscopic study has been performed on structures of self-assembling systems, viz ferrocenylthiols on a gold (111) crystal. The angular dependence of the intensities of photoemission reveals that ferrocenyl groups are on the outermost layer, separated from the gold substrate by hydrocarbon chains of the thiol groups. 相似文献
54.
55.
Some predictions are made on dynamic light scattering by critical fluids in the presence of a shear flow. A Doppler shift broadening is predicted to occur whenever the scattering vector has a component along the direction of flow. 相似文献
56.
Fluorescence spectra and lifetimes of single vibronic levels of the first excited singlet state of H2CS have been measured under effusive flow conditions. Fluorescence lifetimes of the single vibronic levels decrease from 140±3 μs (0°) to 68 μs(314151) with increasing excitation energies. The promoting vibrational modes for the non-radiative transition are considered to be the out-of-plane bending (ν4) and the asymmetric rocking (ν6) modes rather than the asymmetric stretching mode (ν5). 相似文献
57.
58.
Choi SK Olsen SL Abe K Abe K Adachi I Aihara H Asano Y Bahinipati S Bakich AM Ban Y Bedny I Bitenc U Bizjak I Bondar A Bozek A Bracko M Brodzicka J Browder TE Chang MC Chang P Chen A Chen WT Cheon BG Chistov R Choi Y Chuvikov A Cole S Dalseno J Danilov M Dash M Drutskoy A Eidelman S Enari Y Fang F Fratina S Gabyshev N Gershon T Gokhroo G Golob B Hara T Hastings NC Hayasaka K Hayashii H Hazumi M Hinz L Hokuue T Hoshi Y Hou S Hou WS Hsiung YB Iijima T Imoto A Inami K Ishikawa A Iwasaki M 《Physical review letters》2005,94(18):182002
We report the observation of a near-threshold enhancement in the omegaJ/psi invariant mass distribution for exclusive B-->KomegaJ/psi decays. The results are obtained from a 253 fb(-1) data sample that contains 275 x 10(6) BB pairs that were collected near the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric energy e(+)e(-) collider. The statistical significance of the omegaJ/psi mass enhancement is estimated to be greater than 8sigma. 相似文献
59.
Shinohara Y Kawasaki N Ueno S Kobayashi I Nakajima M Amemiya Y 《Physical review letters》2005,94(9):097801
Crystallization of n-hexadecane in emulsion droplets was studied using time-resolved two-dimensional small- and wide-angle x-ray scattering with differential scanning calorimetry (2D-SAXS-WAXS-in situ DSC) which provides information about both nano- and subnanoscale structural change. n-hexadecane in droplets reproducibly crystallized into the stable triclinic phase via a transient-rotator phase. This is in contrast with previous results that the rotator phase of n-hexadecane was observed only occasionally for bulk samples. Thus we confirmed the existence of rotator phase in n-hexadecane, which is important for the study of crystallization of soft materials. We suggest that the rotator phase at the interface of oil and water plays a precursor role for bulk crystallization. This study demonstrates that 2D-SAXS-WAXS-in situ DSC is a powerful tool for the study of a transient phase. 相似文献
60.
Li J Zhang ZP Schwartz AJ Abe K Abe K Aihara H Akatsu M Asano Y Aushev T Bakich AM Bay A Bedny I Bitenc U Bizjak I Bondar A Bozek A Bracko M Brodzicka J Browder TE Chao Y Chen A Chen KF Chen WT Cheon BG Chistov R Choi SK Choi Y Chuvikov A Cole S Dalseno J Danilov M Dash M Dong LY Drutskoy A Eidelman S Eiges V Enari Y Fang F Fratina S Gabyshev N Garmash A Gershon T Gokhroo G Haba J Hayasaka K Hayashii H Hazumi M Higuchi T Hokuue T Hoshi H Hou S Hou WS Iijima T Imoto A Inami K Itoh R Iwasaki M 《Physical review letters》2005,94(7):071801
We have searched for mixing in the D(0)-D (0) system by measuring the decay-time distribution of D(0) --> K(+) pi(-) decays. The analysis uses 90 fb(-1) of data collected by the Belle detector at the KEKB e(+) e(-) collider. We fit the decay-time distribution for the mixing parameters x' and y' and also for the parameter R(D), which is the ratio of the rate for the doubly-Cabibbo-suppressed decay D(0)--> K+ pi(-) to that for the Cabibbo-favored decay D(0)--> K-pi(+). We do these fits both assuming CP conservation and allowing for CP violation. We use a frequentist method to obtain a 95% C.L. region in the x'(2) - y' plane. Assuming no mixing, we measure R(D) = (0.381 +/- 0.017(+0.008)(-0.016))%. 相似文献