State of irremovable water in solid polymer films examined by fourier transform infrared spectroscopy I: poly(ethylene glycol) dimethyl ether

The state of the sorbed water, including the water that cannot be removed by the reduced pressure and water-sorption processes, into poly(ethylene glycol) dimethyl ether (PEG-DME) film was examined by Fourier transform infrared (FT-IR) spectroscopy. The spectrum of the irremovable water could be obtained without a thermal treatment frequently used as the dehydration procedure. It was found that the irremovable water mainly existed in the crystalline region of PEG-DME film, and that its hydrogen-bonding (HB) structure differed from that of the water sorbed from the air. Moreover, the amount of water having the same HB structure as the irremovable water increased with the water contents. These findings could not be revealed by the spectrum of the sorbed water obtained by the conventional dehydration procedure. The experimental procedure examined here allowed us to investigate the true aspects of the irremovable water and the water-sorption processes.     

Anionische Polymerisation von tert-Butylacrylat

Ohne Zusammenfassung     

Shear flow rheological properties of vinylon- and glass-fiber reinforced polyethylene melts

Shear viscosity, shear stress and first normal-stress difference have been investigated for glass- and vinylon-fiber filled polyethylene melts over a wide range of shear rate by means of three kinds of instruments. The influence of fiber content and fiber properties on the rheological properties is discussed. The viscosity increases with increasing aspect ratio and fiber content, and the influence of these parameters on the flow properties is evident at low shear rates. The first normalstress difference increases more rapidly with increasing glass fiber content, especially at low shear stresses. The influence of vinylon fibers on the first normal stress-difference vs. shear-stress relationship is different from that of glass fibers.     

Handling and stability performance of four-track steering vehicles

The advantages of using a four-track steering (4TS) vehicle are less slippage and sinkage of the tracks in turning, compared with conventional skid-steering tracked vehicles. This paper describes the steerability and the mobility of the 4TS vehicle for on- and off-road conditions. Mathematical models have also been developed to predict the effects of various types of differential torque transfer on the handling behavior of a vehicle. A turning vehicle motion was simulated and compared with the experimental data. The results demonstrate that the proposed mathematical model could accurately assess the steering performance of a 4TS vehicle.     

A mathematical model for spatial motion of tracked vehicles on soft ground

A mathematical model which predicts spatial motion of tracked vehicles on non-level terrain has been developed. The motion of the vehicle is represented by three translational and three rotational degrees of freedom. In order to incorporate the inelastic deformation of soil, a soil-track interaction model is introduced; this constitutive model relates the traction exerted on the track by soil to the slip velocity and sinkage of the track. The model is based upon available soil plasticity theories and furnishes mechanics-based interpretation of Bekker's empirical relations. For planar motion the proposed model reduces to the existing equations of motion by introducing kinematic constraints on the vertical translation, pitching and rolling degrees-of-freedom.