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71.
Jana A Sarish SP Roesky HW Leusser D Objartel I Stalke D 《Chemical communications (Cambridge, England)》2011,47(19):5434-5436
A well-designed method for the preparation of a β-diketiminatolead(II) monofluoride has been developed using LPbNMe(2) (L = [CH{C(Me)(2,6-iPr(2)C(6)H(3)N)}(2)]) and pentafluoropyridine (C(5)F(5)N). The resulting LPbF was used for the synthesis of amidinatosilicon(II) monofluoride. Moreover the activation of a ketone was observed when the LPbF was treated with PhCOCF(3). 相似文献
72.
Kannan R Bipinlal U Kurungot S Pillai VK 《Physical chemistry chemical physics : PCCP》2011,13(21):10312-10317
Although nitrogen doped CNTs (N-CNTs) are considered as a promising alternative to platinized carbon for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cells (PEMFCs), the origin of the enhanced ORR activity with N-CNTs is not clear at present. Among several plausible reasons, the exposure of edge plane and creation of impurity band/surface states near the Fermi level are considered as major causes behind the catalytic activity. However, CNTs without nitrogen doping are not known to catalyze the ORR. In this work, we study the ORR activity of functionalized carbon nanotubes with different functional groups, such as sulfonic acid and phosphonic acid, in order to understand the role of surface functionalities in catalyzing the reaction. Functionalized CNTs show significantly enhanced activity towards the ORR, while CNTs without such surface functional groups do not reveal any such special ORR activity. Linear sweep voltammetry experiments with different rotation rates show diffusion controlled limiting current values for functionalized CNTs, and the 'n' values derived from Koutecky-Levich plots are 3.3 and 1.7 for S-MWCNTs and P-MWCNTs, respectively. This work demonstrates the ORR activity of functionalized MWCNTs, which opens up new strategies for electrocatalyst design in PEMFCs. 相似文献
73.
We call a point ??dynamically special?? if it has a dynamical property, which no other point has. We prove that, for continuous self maps of the real line, all dynamically special points are in the closure of the union of the full orbits of periodic points, critical points and limits at infinity. We completely describe the set of dynamically special points of real polynomial functions. The following characterization for the set of special points is also obtained: A subset of ${\mathbb{R}}$ is the set of dynamically special points for some continuous self map of ${\mathbb{R}}$ if and only if it is closed. 相似文献
74.
An easy and efficient protocol for the stereoselective one-pot synthesis of oxazinobenzothiazole derivatives is described. 相似文献
75.
J. D. Sudha C. K. S. Pillai 《Journal of polymer science. Part A, Polymer chemistry》2003,41(2):335-346
Hydrogen‐bonded aromatic–aliphatic polyester–amides (PEAs) were prepared by solution/melt polycondensation of aromatic–aliphatic amidodiols 1,4‐bis(4‐hydroxybutyramide)benzene (BHBB), 1,4‐bis(5‐hydroxy pentamide)benzene, 1,4‐bis(6‐hydroxyhexamide)benzene, 1,4‐bis(4‐hydroxybutyramidexylene), 1,4‐bis(5‐hydroxypentamidexylene, 1,4‐bis(4‐hydroxybutyramide)benzene, and 1,4‐bis(6‐hydroxyhexamidexylene) with terephthaloyl chloride/dimethyl terephthalate. Aromatic–aliphatic amido diols were prepared by the aminolysis of γ‐butyrolactone, δ‐valerolactone, and ?‐caprolactone with aromatic diamines such as paraphenylene diamine and paraxylene diamine. The monomers and polymers were characterized by chemical analysis (hydroxyl value and elemental analysis), Fourier transform infrared spectroscopy, 1H NMR, and 13C NMR. The thermal‐ and phase‐transition behaviors of the polymers were investigated by differential scanning calorimetry in combination with hot‐stage optical microscopy. Crystallinity of polymers was examined with wide‐angle X‐ray diffraction. The polymers exhibited liquid crystallinity with layered structures formed by self‐organization of the hetero intermolecular hydrogen‐bonded networks indicating smectic phases except for PEAs prepared from BHBB. The hydrogen atom of the phenyl‐substituent group forces the neighboring carbonyl groups out of plane of the rings preventing formation of layered structures in the case of BHBB. The PEAs retained intermolecular hydrogen bonding even in the mesomorphic state, and variations in the hydrogen‐bonded lamellae/micelles might be responsible for the variations from one smectic to another texture. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 335–346, 2003 相似文献
76.
K Nagarajan P Madhavan Pillai A Nagana Goud R K Shah 《Proceedings Mathematical Sciences》1977,86(1):25-39
Decomposition of the diazonium chloride from N-(o-aminobenzoyl)-N-methylbenzylamine led to the formation of 3-benzyl-3, 4-dihydrobenzo-triazin-4-one (8), N-benzoylbenzylamine (11), N-benzylphthalimidine (13) ando-diphenic acid N-methyl amide (14), the last one presumably through the intermediary, the expected dibenzazepinone 16. From the analogue, N-(o-aminobenzoyl)-4-methoxybenzyl amine (4), triazinone 10 and N-benzoyl-4-methoxybenzyl amine (12) were obtained. Application of Pschorr reaction to N-(o-aminobenzoyl)-N-methyl-β-(4-methoxyphenyl) ethyl amine (23) afforded 2-methoxy-7-methyl-5, 6, 7, 8- tetrahydrodibenzo (c, e) azocin-8-one (26), with an interesting conformation. From N-(o-aminophenylacetyl)-p-methoxyaniline were obtained under these conditions, indazole-3-carboxylic acidp-anisidide (35) and N-[2-(4-methoxyphenyl carbamoylmethyl) phenyl]-1-(p-methoxyphenyl) isatin-β-hydrazone (37). The structure of 37 was deduced from spectral data and hydrolysis to the acid 42. Diazotisation of N-(o-aminophenylacetyl)-1, 2, 3, 4-tetrahydroquinoline (47) led to the formation of tetrahydroquinoline (49) ando-hydroxyphenyl acetic acid (50) presumably through the salicylamide 48. A similar reaction on N-(o-aminophenylacetyl) tetrahydroisoquinoline (52) gave the benzofurandione hydrazone 55, besides tetrahydroisoquinoline. Oxindole 45 and benzofuranone 56 were likely precursors for 37 and 55 respectively. Salicylamides 5, 7, 24 and 34 were byproducts in the Pschorr reaction. 相似文献
77.
78.
ZnS: Cu: Cl phosphor prepared under a vacuum firing process is found to give blue electroluminescence with emission peak at 460 nm which remains unaltered with the frequency of the excitation voltage. Addition of excess chlorine in the phosphor gives blue, green and red emission at 460, 520 and 640 nm. The intensity of the blue band decreases and it finally disappears as chlorine concentration is increased. A scheme involving three energy levels attributed to Cu2+, Cu+ and Cl- centres in ZnS explains the experimental results completely. 相似文献
79.
80.
Summary The crystallization ofγ-irradiated polyethylene terephthalate, crystallized over a wide range of temperatures, has been studied by differential scanning
calorimetry. It was found that the difference between theAvrami exponents for the low temperature and pre-melt crystallization processes was not as pronounced as it was for the unirradiated
polymer. The superposability of the low temperature crystallization isotherms along the log time axis and the inability of
the pre-melt isotherms to do this suggest that the crystallization mechanisms are different. The rates of crystallization
and the crystallinity are affected by irradiation, the former being first retarded and then speeded-up with dosage increase,
whilst the latter is a minimum at 2 mrad. The differing rates and crystallinities are discussed with respect to chain scission
and crosslinking.
The relationship between the crystalline melting points and the crystallization temperatures for the premelt process is as
predicted by theory. The melting points of the low temperature crystallization process are higher than those predicted by
theory, annealing or further recrystallization being thought to have occurred.
Contribution No. 462. 相似文献
Zusammenfassung Die Kristallisation vonγ-bestrahlten Poly?thylen-Terephthalaten die in einem gro?en Temperaturbereich kristallisiert wurden, ist mit Hilfe der Differential-Kalorimetrie untersucht worden. Es wurde festgestellt, da? der Unterschied zwischen demAvrami-Exponenten der Tieftemperatur-Kristallisation und der von vorgeschmolzenen Proben ausgehenden Kristallisation nicht so ausgepr?gt war wie bei dem unbestrahlten Polymer. Die Deckungsgleichheit der Tieftemperatur-Kristallisations-Isothermen entlang der log-Zeit-Achse und das Unverm?gen der Vorschmelz-Isothermen, dasselbe zu tun, weisen jedoch darauf hin, da? die Kristallisations-Mechanismen verschieden sind. Die Kristallisations-Geschwindigkeit und die Kristallinit?t werden mit der Bestrahlung ver?ndert, und zwar wird das ersterw?hnte mit zunehmender Strahlungsdosis anfangs verz?gert und dann beschleunigt, w?hrend das letztere ein Minimum bei 2 mrad hat. Die unterschiedlichen Geschwindigkeiten und Kristallinit?ten werden diskutiert mit Rücksicht auf Kettenspaltung und Vernetzung. Das Verh?ltnis zwischen dem Kristall-Schmelzpunkt und der Kristallisations-Temperatur für den Vorschmelz-Proze? ist wie in der Theorie vorhergesagt. Die Schmelzpunkte beim Tieftemperatur-Kristallisations-Proze? sind h?her als theoretisch, vermutlich durch Tempern oder weitere Rekristallisation.
Contribution No. 462. 相似文献