Reaction of cholest-4-ene-3,6-dione with perbenzoic acid : Formation of novel oxetalactones

Oxidation of 1 with perbenzoic acid (p-toluene-sulphonic acid monohydrate as catalyst) provided novel oxetalactones 4 and 5 along with compounds 2 and 3. Treatment of 2 with perbenzoic acid yielded 4. A probable pathway for the formation of 4 from 1 involving the intermediacy of 2 has been suggested.     

Exact robustness studies of the test of independence based on four multivariate criteria and their distribution problems under violations

Summary Exact robustness studies against non-normality have been carried out for test of independence based on the four multivariate criteria: Hotelling's trace,U ^(p) , Pillai's trace,V ^(p) , Wilks' criterion,W ^(p) , and Roy's largest root,L _(p) . The density functions ofU ^(p) ,W ^(p) andL _(p) have been obtained in the canonical correlation case and further the moments ofU ^(p) and m.g.f. ofV ^(p) have been derived. All of the study is based on Pillai's distribution of the characteristic roots under violations. Numerical results for the power function have been tabulated for the two-roots case. Slight non-normality does not affect the independence test seriously.V ⁽²⁾ is found to be most robust against nonnormality. Yu-Sheng Hsu is now with Georgia State University, Atlanta.     

Polarization studies by the TSC technique on a blend of cellulose acetate and polyvinyl acetate

The thermally stimulated current (TSC) technique has been used to study solvent-cast blends of a cellulose derivative with a vinyl polymer. TSC peaks are observed at 56, 80, and 120°C. Their origin is investigated because the TSC spectra of the blends differ from the spectra of the individual components. Data on blends with components in the weight ratios 25:75, 50:50, and 75:25 indicate that the 50:50 blend shows the greatest polarization. The enhancement of depolarization currents observed on blending is explained on the basis of a Maxwell–Wagner–Sillars polarization due to increased heterogeneity in the structure. Effects of forming conditions (time, temperature, field) on polarization have been investigated. Activation energies and relaxation times are calculated; there is good agreement between the values obtained from the initial-rise and the full-curve methods.     

Analysis of barbiturates by gas chromatography

This review surveys the evolution of gas chromatographyic procedures for the quantification of barbiturates as either the free acids or their derivatives obtained by direct and on-column reactions. Among the aspects discussed, some emphasis is placed on recognized and other sources of interference encountered during analyses.     

Engaging the pyridine-DMAD zwitterion in a novel strategy for the selective synthesis of highly substituted benzene and cyclopentenedione derivatives

[reaction: see text] The pyridine-mediated reaction of dimethyl acetylenedicarboxylate and cyclobutene-1,2-diones affords selective access to either hexasubstituted benzene derivatives or cyclopentenedione derivatives depending on the concentration of pyridine.     

Pyridine-catalyzed addition of diaryl-1,2-diones to dimethyl butynedioate leading to the formation of 1,2-diaroyl dimethyl maleates via an unprecedented rearrangement

[reaction: see text] Pyridine catalyzes the reaction of 1,2-diaryl diones with dimethyl butynedioate to afford diaroyl maleates. This unprecedented rearrangement involves a unique benzoyl migration and proceeds with complete stereoselectivity.     

Mesoporous iron phosphate as an active, selective and recyclable catalyst for the synthesis of nopol by Prins condensation

Mesoporous iron phosphate is found to be a highly active and recyclable heterogeneous catalyst for the selective synthesis of nopol by Prins condensation of beta-pinene and paraformaldehyde in acetonitrile at 80 degrees C.