Thermally induced oscillatory relaxation of dc resistivity and ac susceptibility in Y−Ba−Cu−O during N−S transition

Dc resistivity and ac susceptibility have been measured simultaneously on Y–Ba–Cu–O specimens under the effect of a temperature gradient. During cooling process, an intermediate (normal-superconducting) state of samples forms in the vicinity ofT _c and an artificial, local, step-like change of temperature induces an oscillatory relaxation of the measured parameter. This phenomenon has been interpreted in the framework of a vortexglass model as a collective relaxation of vortices inside a domain volume defined by vortex-glass correlation length. Close to theT _c the domain relaxation time and the correlation length have been determined as 51 s and 2 mm, respectively.     

Electron stimulated desorption of O+ ions: Energy dependence of the desorption efficiency from adsorbed oxygen on metal surfaces and its bearing on the mechanism

Measurements of the structure in the curve of desorption yield versus electron energy for ESD of O⁺ from β₁-oxygen on polycrystalline W and W(100), and from oxidized V are reported. They show definite structure around the core ionization thresholds of the metal atoms. This may be taken as evidence for the existence of Auger mechanisms of ESD, e.g. that proposed recently by Knotek and Feibelman for oxidic oxygen.     

A novel electron spectroscopy for surface studies

The method makes use of the decrease in the elastically backscattered electron current at characteristic excitation thresholds of surface atoms, when the primary energy is scanned. By means of electronic differentiation the structures in the energy dependence of the coefficient of elastic reflection are made visible. They can give information on the elemental composition and electronic structure of the surface layer.     

Small x resummation in collinear factorisation

The summation of the small x-corrections to hard-scattering QCD amplitudes by collinear factorisation method is reconsidered and the K-factor is derived in leading ln?x approximation with a result differing from the corresponding expression by Catani and Hautmann (Nucl. Phys. B 427, 475, 1994). The significance of the difference is demonstrated in the examples of structure function F _L and of exclusive vector meson electroproduction. The formulation covers the channels of non-vanishing conformal spin n paving the way for new applications.     

Dynamics of magnetic domain wall motion after nucleation: dependence on the wall energy

The dynamics of magnetic domain wall motion in the FeNi layer of a FeNi/Al2O3/Co trilayer has been investigated by a combination of x-ray magnetic circular dichroism, photoelectron emission microscopy, and a stroboscopic pump-probe technique. The nucleation of domains and subsequent expansion by domain wall motion in the FeNi layer during nanosecond-long magnetic field pulses was observed in the viscous regime up to the Walker limit field. We attribute an observed delay of domain expansion to the influence of the domain wall energy that acts against the domain expansion and that plays an important role when domains are small.     

A convenient HPLC assay for the determination of fructosamine-3-kinase activity in erythrocytes

Fructosamine-3-kinase (FN3K) mediates the regeneration of lysine from fructosamines formed on proteins as a result of the ‘early’ Maillard reaction. As fructosamines and advanced glycation endproducts derived therefrom are supposed to play an adverse role in the development of diabetic complications, FN3K is discussed as a protein-repairing enzyme. In this study, a method for the determination of FN3K activity in erythrocyte lysate is described which overcomes the complexity of currently known assays. The assay is based on the FN3K-dependent conversion of the synthetic UV-active fructosamine N ^α-hippuryl-N ^ε-(1-deoxy-D-fructosyl)lysine (BzGFruK) to N ^α-hippuryl-N ^ε-(phosphofructosyl)lysine (BzGpFruK). The FN3K activity was quantified by measuring the formation of BzGpFruK using RP-HPLC with UV detection. Identification of the metabolite BzGpFruK was achieved by means of UV and mass spectroscopy. The results are related to the content of haemoglobin for standardisation. First activity measurements with a chosen number of normoglycaemic subjects confirmed the convenient applicability of the method and showed distinctly different individual activities, as already discovered recently. The new established assay needs only the equipment of a routine laboratory with HPLC instrumentation. This should facilitate further studies about a possible relationship between the FN3K activity and the development of diabetic complications.     

Do hydroxyl radical-water clusters, OH(H2O)n, n = 1-5, exist in the atmosphere?

It has been speculated that the presence of OH(H2O)n clusters in the troposphere could have significant effects on the solar absorption balance and the reactivity of the hydroxyl radical. We have used the G3 and G3B3 model chemistries to model the structures and predict the frequencies of hydroxyl radical/water clusters containing one to five water molecules. The reaction between hydroxyl radical clusters and methane was examined as a function of water cluster size to gain an understanding of how cluster size affects the hydroxyl radical reactivity.     

Ortho effect in the Bergman cyclization: electronic and steric effects in hydrogen abstraction by 1-substituted naphthalene 5,8-diradicals

We present a detailed theoretical study of geometries, electronic structure, and energies of transition states and intermediates completing the full Bergman cycloaromatization pathway of ortho-substituted enediynes with a focus on polar and steric contributions to the kinetics and thermodynamics of hydrogen abstraction. This study provides a rare unambiguous example of remote substitution that affects reactivity of a neutral reactive intermediate through an sigma framework.     

Generation of hard X-ray radiation using the triboelectric effect by peeling adhesive tape

The triboelectric effect describes electrical charging when bringing different materials into contact. We report on the generation of hard X-ray radiation by peeling various adhesive tapes under medium vacuum conditions. Beside vacuum housing and pumps as instrumentation only an electric motor, two rolls and a metal foil as target material are necessary. The spectral distribution of generated X-rays was analyzed using an energy-dispersive detector. Depending on peeling speed, pressure and choice of material combination, electrons with energies sufficient to excite emission in the hard X-ray region are produced. The results are discussed in terms of triboelectric separation of charge carriers.     

Synthesis and catalytic properties of microemulsion-derived cerium oxide nanoparticles

The synthesis of cerium dioxide nanoparticles using an inverse microemulsion technique and precipitation method was investigated. Cerium hydroxide nanoparticles were synthesized by adding diluted ammonia to n-heptane–surfactant–cerium nitrate system. The micelle and particle size in the range of 5–12 nm were controlled by varying the molar water to surfactant ratio and analyzed by dynamic light scattering (DLS), small angle X-ray scattering (SAXS) and high-resolution transmission electron microscopy (HRTEM). Cerium hydroxide nanoparticles were isolated and subsequently treated at 100–600 °C to obtain nanoscale ceria. Crystallite sizes of cerium dioxide in the range of 6–16 nm were estimated by Scherrer analysis by X-ray diffraction (XRD) and HRTEM. The catalytic activity of particles annealed at 400 and 600 °C in soot combustion reactions was characterized by temperature-programmed oxidation (TPO) indicating a size-dependant activity. Crystallite sizes and catalytic stability of elevated ceria systems were tested in second combustion cycles.