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961.
Copper‐Catalyzed Regioselective Cascade Alkylation and Cyclocondensation of Quinoline N‐Oxides with Diazo Esters: Direct Access to Conjugated π‐Systems 下载免费PDF全文
Aniruddha Biswas Ujjwal Karmakar Arun Pal Dr. Rajarshi Samanta 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(39):13826-13830
An inexpensive copper‐catalyzed cascade regioselective alkylation, followed by cyclocondensation of quinoline N‐oxides with α‐diazo esters has been achieved successfully to provide heteroarene‐containing conjugated π‐systems. The developed method is simple, straightforward, and economical with a broad range of substrate scope. The dual role of copper catalyst in the C?H bond functionalization and in Lewis acid‐promoted cyclization was explored. 相似文献
962.
963.
Abstract The experimental data for the spectral distribution of light scattered from methyl fluoride in the critical region are collected and analysed for different polarization directions by means of a Fabry-Pérot etalon. The analysis reveals the presence of an unshifted Rayleigh line and two frequency shifted Brilllouin lines for polarized and depolarized intensities. The intensity ratio of these lines - the so-called Landau-Placzek ratio - is determined along the critical isochore and its divergence near the critical point is described by a power law expression. 相似文献
964.
965.
Anubha Yadav Soumen Biswas Shaikh M. Mobin Sampak Samanta 《Tetrahedron letters》2017,58(37):3634-3639
An efficient, solvent-free, environmentally benign, Cu(OTf)2-catalyzed and microwave-assisted fast synthesis of a fascinating class of a number of angularly fused chromenopyridinones having a carboxylate group at C-2 position on the pyridine ring via a one-pot [3+3] annulation reaction of several aminocoumarins/cyclic β-enaminones with different kinds of γ-aryl/styryl/heteroaryl-substituted-β,γ-unsaturated α-ketoesters as Michael acceptors under open atmosphere. This eco-friendly method delivers good to excellent yields of pyridine-fused-heterocycles within (15–40 min) without using any traditional oxidants and allows several important functionalities. Furthermore, by this method, stereoselective synthesis of trans-7,8-diaryl-8.9-dihydrochromeno[4,3-b]cyclopenta[e]pyridine-6,10-diones were obtained in an excellent diastereoselective manner (dr ≤ 99:1). 相似文献
966.
Nelson J. Castellanos Fernando Martínez Frédéric Lynen Shyam Biswas Pascal Van Der Voort Henri Arzoumanian 《Transition Metal Chemistry》2013,38(2):119-127
A dioxomolybdenum(VI) complex has been covalently anchored onto mesoporous titania by a silicon-assisted transesterification route. The grafting of the complex to the mesoporous structure was confirmed by diffuse reflectance infrared Fourier transform, Raman and UV–Vis spectroscopy and by nitrogen sorption experiments. The ability of the grafted complex to activate molecular oxygen (O2) has been evaluated in the photooxidation of diphenylmethane to produce benzophenone. The photooxidation of diphenylmethane was monitored continuously by in situ dispersive Raman spectroscopy. A scheme for the activation of molecular oxygen under very mild conditions is proposed. A comparison with the same complex anchored onto commercial titanium P-25 and silica gel revealed both the beneficial effect of the mesoporous structure and the existence of a synergistic effect between MoO/TiO2/O2/light entities, which promotes the photooxidation process under green chemistry conditions. Finally, the heterogeneous catalyst is sustainable; it can be recycled and reused without significant loss in activity or selectivity. 相似文献
967.
o-Isopropenyl phenoxyactic acids 1 and 8 on treatment with thionyl chloride followed by aqueous workup furnished the acylated products 4 and 9 in moderate yields. The corresponding acid chlorides could also be cyclised with stannic chloride. The acid chlorides from 10 and 11 however did not undergo cyclisation. 相似文献
968.
Patra A Bandyopadhyay D Tomar G Sharma A Biswas G 《The Journal of chemical physics》2011,134(6):064705
Instability and dewetting engendered by the van der Waals force in soft thin (<100 nm) linear viscoelastic solid (e.g., elastomeric gel) films on uniform and patterned surfaces are explored. Linear stability analysis shows that, although the elasticity of the film controls the onset of instability and the corresponding critical wavelength, the dominant length-scale remains invariant with the elastic modulus of the film. The unstable modes are found to be long-wave, for which a nonlinear long-wave analysis and simulations are performed to uncover the dynamics and morphology of dewetting. The stored elastic energy slows down the temporal growth of instability significantly. The simulations also show that a thermodynamically stable film with zero-frequency elasticity can be made unstable in the presence of physico-chemical defects on the substrate and can follow an entirely different pathway with far fewer holes as compared to the viscous films. Further, the elastic restoring force can retard the growth of a depression adjacent to the hole-rim and thus suppress the formation of satellite holes bordering the primary holes. These findings are in contrast to the dewetting of viscoelastic liquid films where nonzero frequency elasticity accelerates the film rupture and promotes the secondary instabilities. Thus, the zero-frequency elasticity can play a major role in imposing a better-defined long-range order to the dewetted structures by arresting the secondary instabilities. 相似文献
969.
We report here a robust automated active site detection, docking, and scoring (AADS) protocol for proteins with known structures. The active site finder identifies all cavities in a protein and scores them based on the physicochemical properties of functional groups lining the cavities in the protein. The accuracy realized on 620 proteins with sizes ranging from 100 to 600 amino acids with known drug active sites is 100% when the top ten cavity points are considered. These top ten cavity points identified are then submitted for an automated docking of an input ligand/candidate molecule. The docking protocol uses an all atom energy based Monte Carlo method. Eight low energy docked structures corresponding to different locations and orientations of the candidate molecule are stored at each cavity point giving 80 docked structures overall which are then ranked using an effective free energy function and top five structures are selected. The predicted structure and energetics of the complexes agree quite well with experiment when tested on a data set of 170 protein-ligand complexes with known structures and binding affinities. The AADS methodology is implemented on an 80 processor cluster and presented as a freely accessible, easy to use tool at http://www.scfbio-iitd.res.in/dock/ActiveSite_new.jsp . 相似文献
970.
An iron-catalyzed intramolecular alkyne-aldehyde metathesis strategy of the alkynyl ether of salicylaldehyde derivatives has been developed which works under mild reaction conditions to produce the functionalized 2H-chromene derivatives. This protocol is compatible toward a wide range of functional groups, such as methoxy, fluoro, chloro, bromo, and phenyl groups. This method provides an atom-economical and environmentally friendly approach for the synthesis of a series of substituted 2H-chromenes. 相似文献