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221.
The variety of known very stable PF(3) metal derivatives analogous to metal carbonyls suggests the synthesis of SF(3) metal derivatives analogous to metal nitrosyls. However, the only known SF(3) metal complex is the structurally uncharacterized (Et(3)P)(2)Ir(CO)(Cl)(F)(SF(3)) synthesized by Cockman, Ebsworth, and Holloway in 1987 and suggested by electron counting to have a one-electron donor SF(3) group rather than a three-electron donor SF(3) group. In this connection, the possibility of synthesizing SF(3) metal derivatives analogous to metal nitrosyls has been investigated using density functional theory. The [M]SF(3) derivatives with [M] = V(CO)(5), Mn(CO)(4), Co(CO)(3), Ir(CO)(3), (C(5)H(5))Cr(CO)(2), (C(5)H(5))Fe(CO), and (C(5)H(5))Ni analogous to known metal nitrosyl derivatives are all predicted to be thermodynamically disfavored with respect to the corresponding [M](SF(2))(F) derivatives by energies ranging from 19.5 kcal/mol for Mn(SF(3))(CO)(4) to 5.4 kcal/mol for Co(SF(3))(CO)(3). By contrast, the isoelectronic [M]PF(3) derivatives with [M] = Cr(CO)(5), Fe(CO)(4), Ni(CO)(3), (C(5)H(5))Mn(CO)(2), (C(5)H(5))Co(CO), and (C(5)H(5))Cu are all very strongly thermodynamically favored with respect to the corresponding [M](PF(2))(F) derivatives by energies ranging from 64.3 kcal/mol for Cr(PF(3))(CO)(5) to 31.6 kcal/mol for (C(5)H(5))Co(PF(3))(CO). The known six-coordinate (Et(3)P)(2)Ir(CO)(Cl)(F)(SF(3)) is also predicted to be stable relative to the seven-coordinate (Et(3)P)(2)Ir(CO)(Cl)(F)(2)(SF(2)). Most of the metal SF(3) complexes found in this work are singlet structures containing three-electron donor SF(3) ligands with tetrahedral sulfur coordination. However, two examples of triplet spin state metal SF(3) complexes, namely, the lowest energy (C(5)H(5))Fe(SF(3))(CO) structure and a higher energy Co(SF(3))(CO)(3) structure, are found containing one-electron donor SF(3) ligands with pseudo square pyramidal sulfur coordination with a stereochemically active lone electron pair. 相似文献
222.
Relative partial ionization cross sections (PICS) for the formation of fragment ions following electron ionization of SiCl(4), in the electron energy range 30-200 eV, have been determined using time-of-flight mass spectrometry coupled with an ion coincidence technique. By this method, the contributions to the yield of each fragment ion from dissociative single, double, and triple ionization, are distinguished. These yields are quantified in the form of relative precursor-specific PICS, which are reported here for the first time for SiCl(4). For the formation of singly charged ionic fragments, the low-energy maxima appearing in the PICS curves are due to contributions from single ionization involving predominantly indirect ionization processes, while contributions to the yields of these ions at higher electron energies are often dominated by dissociative double ionization. Our data, in the reduced form of relative PICS, are shown to be in good agreement with a previous determination of the PICS of SiCl(4). Only for the formation of doubly charged fragment ions are the current relative PICS values lower than those measured in a previous study, although both datasets agree within combined error limits. The relative PICS data presented here include the first quantitative measurements of the formation of Cl(2) (+) fragment ions and of the formation of ion pairs via dissociative double ionization. The peaks appearing in the 2D ion coincidence data are analyzed to provide further information concerning the mechanism and energetics of the charge-separating dissociations of SiCl(4) (2+). The lowest energy dicationic precursor state, leading to SiCl(3) (+) + Cl(+) formation, lies 27.4 ± 0.3 eV above the ground state of SiCl(4) and is in close agreement with a calculated value of the adiabatic double ionization energy (27.3 eV). 相似文献
223.
Methylborole iron tricarbonyl, (η(5)-C(4)H(4)BCH(3))Fe(CO)(3), is known experimentally and is a potential source of binuclear (C(4)H(4)BCH(3))(2)Fe(2)(CO)(n) (n = 5, 4, 3, 2, 1) derivatives through reactions such as photolysis. In this connection the lowest energy (C(4)H(4)BCH(3))(2)Fe(2)(CO)(5) structures are predicted theoretically to have a single bridging carbonyl group and Fe-Fe distances consistent with formal single bonds. The lowest energy (C(4)H(4)BCH(3))(2)Fe(2)(CO)(4) structures have two bridging carbonyl groups and Fe═Fe distances suggesting formal double bonds. Analogously, the lowest energy (C(4)H(4)BCH(3))(2)Fe(2)(CO)(3) structures have three bridging carbonyl groups and very short Fe≡Fe distances suggesting formal triple bonds. The tetracarbonyl (C(4)H(4)BCH(3))(2)Fe(2)(CO)(4) is predicted to be thermodynamically unstable toward disproportionation into (C(4)H(4)BCH(3))(2)Fe(2)(CO)(5) + (C(4)H(4)BCH(3))(2)Fe(2)(CO)(3), whereas the tricarbonyl is thermodynamically viable toward analogous disproportionation. The lowest energy structures of the more highly unsaturated methylborole iron carbonyls (C(4)H(4)BCH(3))(2)Fe(2)(CO)(n) (n = 2, 1) have hydrogen atoms bridging an iron-carbon bond. In addition, the lowest energy (C(4)H(4)BCH(3))(2)Fe(2)(CO) structures are "slipped perpendicular" structures with bridging methylborole ligands, a terminal carbonyl group, and agostic CH(3)→Fe interactions involving the methyl hydrogens. Thus, in these highly unsaturated systems the methyl substituent in the methylborole ligand chosen in this work is not an "innocent bystander" but instead participates in the metal-ligand bonding. 相似文献
224.
Aspinall HC Bacsa J Jones AC Wrench JS Black K Chalker PR King PJ Marshall P Werner M Davies HO Odedra R 《Inorganic chemistry》2011,50(22):11644-11652
Thin films of ceria (CeO(2)) have many applications, and their synthesis by liquid-injection MOCVD (metal-organic chemical vapor deposition) or ALD (atomic layer deposition) requires volatile precursor compounds. Here we report the synthesis of a series of homoleptic and heteroleptic Ce(IV) complexes with donor-functionalized alkoxide ligands mmp (1-methoxy-2-methylpropan-2-olate), dmap (1-(dimethylamino)propan-2-olate), and dmop (2-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)propan-2-olate) and their potential as precursors for MOCVD and ALD of CeO(2). New complexes were synthesized by alcohol exchange reactions with [Ce(OBu(t))(4)]. [Ce(mmp)(4)] and [Ce(dmap)(4)] were both found to be excellent precursors for liquid-injection MOCVD of CeO(2), depositing high purity thin films with very low carbon contamination, and both have a large temperature window for diffusion controlled growth (350-600 °C for [Ce(mmp)(4)]; 300-600 °C for [Ce(dmap)(4)]). [Ce(mmp)(4)] is also an excellent precursor for liquid-injection ALD of CeO(2) using H(2)O as oxygen source and demonstrates self-limiting growth from 150 to 350 °C. [Ce(dmap)(4)] has lower thermal stability than [Ce(mmp)(4)] and does not show self-limiting growth in ALD. Heteroleptic complexes show a tendency to undergo ligand redistribution reactions to form mixtures in solution and are unsuitable as precursors for liquid-injection CVD. 相似文献
225.
tert-Butyl perbenzoate is a substitute for benzoquinone for mild (room-temperature) Fujiwara-Moritani reactions between acetanilides and butyl acrylate under homogeneous conditions. The system was enhanced further by including Cu(OAc)(2) as a cocatalyst. Methyl methacrylate can be activated toward coupling under these conditions. 相似文献
226.
Cocrystallized adenine and thymine derivatives, along with the pure monomeric crystals, were investigated by terahertz spectroscopy and solid-state density functional theory (DFT). The methylated nucleobase derivatives crystallize in planar hydrogen-bonded adenine-thymine pairs similar to the manner found in DNA. The spectra obtained for 1-methylthymine, 9-methyladenine, and the 1:1 cocrystal in the range of 10-100 cm(-1) clearly demonstrate that absorptions in this spectral range originate from the uniquely ordered assembly and the intermolecular interactions found in each individual crystal system. The quality of spectral reproduction for the DFT simulations of each system was clearly improved by the inclusion of an empirical correction term for London-type dispersion forces to the calculations. Notably, it was found that these weak dispersion forces in the adenine-thymine cocrystal were necessary to produce a properly converged crystal structure and meaningful simulation of the terahertz vibrational spectrum. 相似文献
227.
Morra S Valetti F Sadeghi SJ King PW Meyer T Gilardi G 《Chemical communications (Cambridge, England)》2011,47(38):10566-10568
[FeFe]-hydrogenases are efficient natural catalysts that can be exploited for hydrogen production. Immobilization of the recombinant [FeFe]-hydrogenase CaHydA was achieved for the first time on an anatase TiO(2) electrode. The enzyme is able to interact and exchange electrons with the electrode and to catalyze hydrogen production with an efficiency of 70%. 相似文献
228.
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230.
H (Rydberg) atom photofragment translational spectroscopy (HRA-PTS) and complete active space with second order perturbation theory (CASPT2) methods have been used to explore the competing N-H and O-H bond dissociation pathways of 4- and 5-hydroxyindoles (HI) and methoxyindoles (MI). When 4-HI was excited to bound (1)L(b) levels, (λ(phot) ≤ 284.893 nm) O-H bond fission was demonstrated by assignment of the structure within the resulting total kinetic energy release (TKER) spectra. By analogy with phenol, dissociation was deduced to occur by H atom tunnelling under the barrier associated with the lower diabats of the (1)L(b)/(1)πσ*((OH)) conical intersection (CI). No evidence was found for a significant N-H bond dissociation yield at these or shorter excitation wavelengths (284.893 ≥ λ(phot) ≥ 193.3 nm). Companion studies of 4-MI revealed different reaction dynamics. In this case, N-H bond fission is deduced to occur at λ(phot) ≤ 271.104 nm, by direct excitation to the (1)πσ*((NH)) state. Analysis of the measured TKER spectra implies a mechanism wherein, as in pyrrole, the (1)πσ*((NH)) state gains oscillator strength by intensity borrowing from nearby bound states with higher oscillator strengths. HRA-PTS studies of 5-HI, in contrast, showed no evidence for O-H bond dissociation when excited on (1)L(b) levels. The present CASPT2 calculations assist in rationalizing this observation: the area underneath the (1)L(b)/(1)πσ* CI diabats in 5-HI is ~60% greater than the corresponding area in 4-HI and O-H bond dissociation by tunnelling is thus much less probable. Only by reducing the wavelength to ≤ 255 nm were signs of N-H and/or O-H bond dissociation identified. By comparison with companion 5-MI studies, we deduce little O-H bond fission in 5-HI at λ(phot) > 235 nm and that N-H bond fission is the dominant source of H atoms in the wavelength region 255 > λ(phot) > 235 nm. The very different dissociation dynamics of 4- and 5-HI are traced to the position of the -OH substituent, and its effect on the overall electronic structure. 相似文献