ICP光源中载气压力对等离子体辐射强度的影响

为了提高ICP光源等离子体的辐射强度,利用常规同心气动雾化器,增大载气压力,提高样品溶液的雾化效率,并且通过释放掉部分气溶胶的方法,以合适的流速将样品送入等离子体焰。经过测量水样品中元素Ca,Si,Sr和Zn的谱线强度表明,在常规条件下载气压力为0.05 MPa时有谱线峰值强度;当释放掉部分气溶胶以后,在0.07 MPa的载气压力下测得的峰值强度分别提高了38%,79%,45%和70%。另外,使用较高的载气压力并不影响等离子体辐射的稳定性。     

Quantum states of hydrogen transfer and vibration in malonaldehyde

New ab initio results on the 21D potential energy surface of malonaldehyde and a quantum mechanical treatment of the hydrogen transfer motion and its interaction with all vibrations are presented. An explicit approximate reaction path, close to the minimum energy path but matching the reactive normal mode near equilibrium, allows one to predict the ground state tunnelling frequency even when using small basis sets. With a barrier of 1144 cm^?1 (3.27kcal mol-¹) the tunnelling splitting is predicted to be 22.0cm^?1 for the parent species and 3.8 cm^?1 for the species deuterated in the hydrogen bond, in good agreement with the observed values 21.6 and 2.9 cm^?1, respectively. Predicted energy levels for excited states of the hydrogen transfer motion and for the non-reactive vibrations suggest a re-examination of the vibrational spectra and an extension of the number of vibrational factors in the basis set to improve the results for the vibrationally excited states.     

铝合金弹丸超高速撞击玄武岩纤维布剩余速度分析

 采用高强纤维作为防护材料,是航天器空间碎片超高速撞击防护结构发展的趋势之一。超高速撞击损伤分析是空间碎片防护结构研究开发设计的重要环节,也是高压极端加载条件下材料动态响应分析的重要内容。玄武岩纤维是近年来受到人们关注的一种高强度、高模量陶瓷纤维。利用二级轻气炮进行了铝合金弹丸超高速撞击玄武岩纤维编织布时的超高速撞击实验,根据弹丸碎片的闪光X射线阴影照片,分析了铝合金弹丸超高速撞击玄武岩纤维编织布的撞击速度损失规律,根据实验结果拟合得到了铝合金弹丸的剩余速度方程,为分析玄武岩纤维材料对弹丸的撞击能量消耗提供了参考依据。     

Microwave spectra and structure of an isoxazole-water complex

The rotational spectrum of a hydrogen-bonded isoxazole-water complex has been measured between 6–18 GHz with a pulsed nozzle Fourier transform microwave spectrometer. In addition to isoxazole-H₂O, the complexes with HDO and D₂O as well as isoxazole-¹⁵ N-H₂O have been investigated in order to determine the structure of the complex. Rotational constants, quartic centrifugal distortion constants and quadrupole coupling constants, where applicable, have been fitted to the measured transition frequencies of the isotopomers. Structural data, which have been deduced from the planar moments of inertia and the quadrupole coupling constants of the isotopomers, have established conclusively that water binds to nitrogen in the ring plane of isoxazole. Ab initio calculations have revealed that complexes with a hydrogen-bond to nitrogen or to oxygen are both stable. The complex with water attached to nitrogen has been found to be more strongly bound than that with water attached to oxygen. Small splittings of the rotational transitions of the two complexes with H₂O have been interpreted as being the result of an internal rotation of water with respect to isoxazole.     

The Solution of Dynamical Equation of Motion of IBM-Ⅱ in Continuous Variable Representation

In this article the solution of dynamical equation of motion of IBM-Ⅱ in continuous variable representation is discussed.With appropriate transformation and approximation,the on-phase part of system manifests the vibration-rotation mode and the off-phase part the 'scissor mode',ect.In the last section the energy spectrum of ¹⁵⁶Gd is calculated.The result can well reproduce the algebraic result of IBM-Ⅱ.     

压力及屏蔽对无限深量子阱中施主结合能的影响

对GaAs/Al_xGa_1-xAs和GaN/Al_xGa_1-xN无限深量子阱系统,考虑压力及屏蔽效应,利用变分方法数值计算这两种系统中的杂质态结合能。给出了结合能随阱宽和压力的变化关系,同时讨论了有无屏蔽时的区别。结果表明,结合能随压力增大而增大,随阱宽增大而减小;屏蔽效应随着压力的增加而增加,并且显著降低了杂质态的结合能。     

Nonlinear Local Lyapunov Exponent and Quantification of Local Predictability

Nonlinear local Lyapunov exponent （NLLE） is applied to quantitatively determine the local predictability limit of chaotic systems. As an example, we find that the local predictability limit of Henon attractor varies considerably with time, and some underlying phase-spatial structure does not appear. The local predictability limit of initially adjacent points in phase space may be completely different. This will cause difficulties in making the long-time analogue forecast.     

低能Cl-离子在绝缘纳米微孔膜中的传输过程

理论模拟结合实验研究了16-keV Cl-离子穿越不同厚度(7和12 μm)的Al₂O₃微孔膜的物理过程,发现负离子传输中并不存在与正离子传输类似的明显的导向现象。在只考虑散射过程的情况下,模拟出的穿透粒子角分布及电荷态分布与实验结果符合很好,出射的Cl-离子沿初束方向分布;Cl0、Cl+离子沿微孔轴向分布。仔细分析了不同出射粒子的角分布,发现出射的Cl+在微孔轴向与初束方向之间分布;经单次散射出射的Cl0沿微孔轴向分布,而经多次散射出射的Cl0向初束方向移动。发现了Cl-离子穿越不同厚度的具有相同微孔直径的Al₂O₃微孔时,较厚的膜出射的Cl+/Cl0比例低。理论分析显示,这是由散射过程的特性造成的,随着微孔膜厚度的增加,出射的Cl0中经单次碰撞的比例变小,而多次散射出射的比例增加,从而导致Cl+离子转化为Cl0的几率要远大于Cl0转化为Cl+离子的几率,使得长的微孔出射的粒子中Cl+/Cl0比例低。     

含N、O和S的Schiff碱配体与铜(Ⅱ)、锌(Ⅱ)配合物的合成及红外光谱研究

本文在40℃条件下制得了5-氯水杨醛,使其与硫脲缩合合成出了一种含N、O、S的新型Schiff碱配体,该配体与铜(Ⅱ)、锌(Ⅱ)能形成稳定的配合物,其组成、结构已由元素分析和红外光谱所表征.     

用于多组分同时测定的流动注射-CCD阵列探测分光光度装置研究

使用流动注射进样、多色仪分光、ＣＣＤ阵列探测器以及微机处理机等,建立了用于多组分同时测定的流动注射－ＣＣＤ阵列探测器联用分光光度装置。完成以ｍｅｓｏ－四（４－三甲铵苯基）卟啉为显色剂时铅和镉的同时测量,铅的检出限为０．０１４μｍ／ｍＬ,镉为０．０１５μｇ／ｍＬ。