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11.
二烯丙基二甲基氯化铵—丙烯酰胺反相乳液聚合的动力学特征研究 总被引:17,自引:1,他引:17
采用油酸失水山梨醇酯(SPAN)-壬基酚聚氧化乙烯醚(OP)复合乳化剂与K2S2O8-Na2SO3氧化还原引发剂,进行二烯丙基二甲基氯化铵-丙烯酰胺反相乳液共聚合,测得单体的竞聚率为γDADMAC=0.14±0.11,γAM=5.05±0.66;在单体浓度为25─45%,引发剂浓度0.06—0.1%,乳化剂浓度为5—9%,聚合温度303K条件下,得到了共聚反应动力学方程:Rp=k[M]0.68[I]1.31[E]0.73,文中对上述结果做了解释. 相似文献
12.
流动注射在线分离富集-火焰原子吸收光谱法测定环境水样中Cr(Ⅲ)和Cr(Ⅵ)的形态 总被引:9,自引:0,他引:9
采用单阀阴离子和阳离子交换树脂微柱并联 ,两柱交替采样逆向洗脱流动注射在线分离富集环境水样中Cr(Ⅲ )和Cr(Ⅵ ) ,分别用 15 %HNO3和 8%NH4 NO3洗脱 ,火焰原子吸收光谱法直接检测。富集 1min时Cr(Ⅲ )和Cr(Ⅵ )的特征浓度分别为 :1 5 0 μg·L- 1 和 1 39μg·L- 1 ,Cr(Ⅲ )和Cr(Ⅵ )检出限 (3σ)分别为 1 0 3μg·L- 1 和 0 5 4 μg·L- 1 ;相对标准偏差 (10 μg·L- 1 )分别为 :3 4 1%和 1 80 % ,分析样品加标回收率在 93 5 %~ 10 7 5 %之间。 相似文献
13.
L E Humes D D Dirks T S Bell G E Kincaid 《The Journal of the Acoustical Society of America》1987,81(3):765-773
In the present study, speech-recognition performance was measured in four hearing-impaired subjects and twelve normal hearers. The normal hearers were divided into four groups of three subjects each. Speech-recognition testing for the normal hearers was accomplished in a background of spectrally shaped noise in which the noise was shaped to produce masked thresholds identical to the quiet thresholds of one of the hearing-impaired subjects. The question addressed in this study is whether normal hearers with a hearing loss simulated through a shaped masking noise demonstrate speech-recognition difficulties similar to those of listeners with actual hearing impairment. Regarding overall percent-correct scores, the results indicated that two of the four hearing-impaired subjects performed better than their corresponding subgroup of noise-masked normal hearers, whereas the other two impaired listeners performed like the noise-masked normal listeners. A gross analysis of the types of errors made suggested that subjects with actual and simulated losses frequently made different types of errors. 相似文献
14.
JEONG-HAN KANG SEUNG-YEAL HA KYUNGKEUN KANG EUNHEE JEONG 《The Journal of mathematical sociology》2014,38(1):47-71
When cultural tastes are not neutral but hierarchically matched to social status, people assimilate themselves to higher status by consuming cultural goods while distinguishing themselves from lower status by developing new tastes. Extending the Cucker-Smale model for mutual influence among agents, we examine when and how many cultural classes emerge from continuous distributions of tastes and what conditions those classes satisfy, through the assimilation-distinction mechanism. We simulate the models with different initial distributions of tastes (uniform, normal, and chi-square), given various ranges of 2 parameters: (a) the strength and (b) the range of distinction relative to assimilation. Tastes are flocking and cultural classes emerge when the range of assimilation is much larger than that of distinction. The number of classes increases with the strength of distinction, whereas the distance between classes equals the range of distinction. Some properties of emergent classes are mathematically proved. First, in a two-class system, the stronger distinction, the larger the upper class. Second, in a three-class system, the middle class is necessarily larger than the lower class and likely larger than the upper class. Third, a 3-class system cannot emerge if distinction is weaker than assimilation. These properties are universal and do not depend on the initial distribution of cultural tastes. This independence predicts homogeneous cultural classes emerging across different social conditions. Also, the cultural middle class as the largest group may explain why subjective class consciousness is often higher than objective position. Unless assimilating efforts can reach an infinite range, there emerges a cultural outcast at the lowest end of the cultural hierarchy. 相似文献
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17.
大视角两步彩虹全息术 总被引:4,自引:1,他引:3
本文巧妙地运用了全息图的光路可逆性,采用两面反射镜与小面积全息图相结合,制得了视场角接近180°的大视角彩虹全息图.整个过程分两步完成,无需任何特殊的光学元件.文中给出了实验结果,并进行了讨论. 相似文献
18.
通过高速撞击实验,探讨了采用小尺寸防护板的可行性。实验中采用的Whipple结构由尺寸变化的1 mm厚防护板(前板)和尺寸固定的3 mm厚舱壁板(后板)组成,防护板与舱壁板间隔10 cm。防护板为边长分别为8、12、16和20 cm的方形2A12铝合金板,舱壁板为边长为20 cm的方形5A06铝合金板。实验过程中均采用直径为4 mm的铝合金球形弹丸,撞击速度为1.45~1.71 km/s。实验结果表明:Whipple防护结构在舱壁板被击穿的概率大于0.8的条件下和击穿概率为0的条件下的极限速度以及舱壁板临界击穿条件下的速度都与防护板尺寸无关;并且,防护板前后表面击穿孔的直径及击穿孔侧壁的倾斜角也与防护板尺寸无关;但是,在速度相同的条件下随着板尺寸的增大,防护板板面的最大挠度增大,而且,防护板挠曲面的凸凹方向也由单一的凹向变成凸凹方向交替出现;随着速度的增加和板尺寸的增大,防护板最大挠度的增量减小。 相似文献
19.
A new theoretical approach to describe pre-hydrodynamic stages of evolution in nonequilibrium fluids is presented. The local density, velocity, and temperature fields are expressed as integrals over Green's functions that depend on initial-state ensemble averages of dynamical quantities. For systems in which the initial states are nonuniform in only one spatial direction, explicit expressions for the Green's functions are derived in terms of initial-state ensemble averages of moments of particle displacements and products of particle velocities and particle displacements. 相似文献
20.
David R. Kincaid 《Numerische Mathematik》1972,20(5):392-408
A new class of norms which generalize norms previously investigated by Young [9, 14], Sheldon [4, 5], Golub [1], Golub and Varga [2], Varga [6], Wachspress [7], Young and Kincaid [12], Young [14], and Kincaid [3] is introduced. Expressions for these norms applied to the matrices associated with various iterative methods are developed.Work on this paper was sponsored by NSF Grant GP-8442 and Army Grant DA-ARO(D)-31-124-G1050 at The University of Texas at Austin. 相似文献